Citation: | CHEN Yinsheng, LUO Guoping, HAO Shuai, REN Jie, AN Shengli, CHAI Yifan. Effect of Special Components in Blast Furnace Slag of Baotou Iron and Steel Company on Self-pulverization Behavior of Steel Slags[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(4): 168-174. doi: 10.3969/j.issn.1000-6532.2024.04.025 |
This is an article in the field of metallurgical engineering, which proposed a new idea of mixing molten blast furnace slag with steel slag to achieve self-pulverization of steel slag, and systematically studied the influence mechanism of special components of CaF2 and CeO2 in blast furnace slag of Baotou Iron and Steel Company on the self-pulverization of steel slags. Using analytically pure CaO, SiO2, CaF2 and CeO2 as starting materials, pure C2S specimens were prepared with n ( CaO ) : n ( SiO2 ) = 2 : 1, then different mass fractions of CaF2 and CeO2 were added, respectively. The effect of CaF2 and CeO2 on the self-pulverization behavior of C2S was investigated by calcining the specimen at 1 450 °C for 1 h and cooling with the furnace. The results showed when CaF2 was incorporated into C2S and the content of CaF2 was less than 2.5%, it had little effect on the self-pulverization of C2S. However, when the content of CaF2 was more than 2.5%, the specimen had different degrees of agglomeration, which affected the self-pulverization of C2S. Considering that excessive CaF2 would affect the environment, the content of CaF2 should be controlled below 2.5%. When CeO2 incorporated into C2S and the content was 0.25%, C2S could still be completely self-pulverized, but when the CeO2 content was more than 0.5%, C2S no longer self-pulverized.Therefore, the CeO2 content must be less than 0.25 %, and the self-pulverization effect of C2S was relatively good.
[1] | 高洋. 高钛高炉渣综合利用现状及展望[J]. 矿产综合利用, 2019(1):6-10.GAO Y. Present situation and prospect of comprehensive utilization of high titanium blast furnace slag[J]. Multipurpose Utilization of Mineral Resources, 2019(1):6-10. doi: 10.3969/j.issn.1000-6532.2019.01.002 GAO Y. Present situation and prospect of comprehensive utilization of high titanium blast furnace slag[J]. Multipurpose Utilization of Mineral Resources, 2019(1):6-10. doi: 10.3969/j.issn.1000-6532.2019.01.002 |
[2] | 邓志豪, 王珏, 周云. 转炉渣系矿物相研究[J]. 安徽工业大学学报(自然科学版), 2011, 28(3):201-204.DENG Z H, WANG J, ZHOU Y. Study on mineral phase of converter slag system[J]. Journal of Anhui University of Technology (Natural Science Edition), 2011, 28(3):201-204. DENG Z H, WANG J, ZHOU Y. Study on mineral phase of converter slag system[J]. Journal of Anhui University of Technology (Natural Science Edition), 2011, 28(3):201-204. |
[3] | 闫英师, 李玉凤, 赵礼兵. 改性钢渣吸附重金属离子的研究现状[J]. 矿产综合利用, 2021(1):8-13.YAN Y S, LI Y F, ZHAO L B. Research status of heavy metal ions adsorption by modified steel slag[J]. Multipurpose Utilization of Mineral Resources, 2021(1):8-13. doi: 10.3969/j.issn.1000-6532.2021.01.002 YAN Y S, LI Y F, ZHAO L B. Research status of heavy metal ions adsorption by modified steel slag[J]. Multipurpose Utilization of Mineral Resources, 2021(1):8-13. doi: 10.3969/j.issn.1000-6532.2021.01.002 |
[4] | 刘洋, 张春霞. 钢铁渣的综合利用现状及发展趋势[J]. 矿产综合利用, 2019(2):21-25.LIU Y, ZHANG C X. Comprehensive utilization situation and development trend of iron and steel slag in China and abroad[J]. Multipurpose Utilization of Mineral Resources, 2019(2):21-25. doi: 10.3969/j.issn.1000-6532.2019.02.004 LIU Y, ZHANG C X. Comprehensive utilization situation and development trend of iron and steel slag in China and abroad[J]. Multipurpose Utilization of Mineral Resources, 2019(2):21-25. doi: 10.3969/j.issn.1000-6532.2019.02.004 |
[5] | Gencel Osman, Karadag Omer, Oren Osman Hulusi, et al. Steel slag and its applications in cement and concrete technology: A review[J]. Construction and Building Materials, 2021, 283. |
[6] | 张作良, 陈韧. 转炉钢渣物相组成及其显微形貌[J]. 材料与冶金学报, 2019, 18(1):37-40.ZHANG Z L, CHEN R. Physical phase composition of converter steel slag and its micro-morphology[J]. Journal of Materials and Metallurgy, 2019, 18(1):37-40. ZHANG Z L, CHEN R. Physical phase composition of converter steel slag and its micro-morphology[J]. Journal of Materials and Metallurgy, 2019, 18(1):37-40. |
[7] | 林超. 石煤改质转炉钢渣自粉化及提钒的基础研究[D]. 马鞍山: 安徽工业大学, 2018.LIN C. Basic research on self-powdering and vanadium extraction from stone-coal modified converter steel slag [D]. Maanshan: Anhui University of Technology, 2018. LIN C. Basic research on self-powdering and vanadium extraction from stone-coal modified converter steel slag [D]. Maanshan: Anhui University of Technology, 2018. |
[8] | 林超, 高卫, 钟娜娜, 等. SiO2改质对转炉钢渣中C2S相优势析出及钢渣自粉化的影响[J]. 冶金工程, 2018, 5(2):77-84.LIN C, GAO W, ZHONG N N, et al. Effect of SiO2 modification on the dominant precipitation of C2S phase in converter steel slag and self-powdering of steel slag[J]. Metallurgical Engineering, 2018, 5(2):77-84. doi: 10.12677/MEng.2018.52011 LIN C, GAO W, ZHONG N N, et al. Effect of SiO2 modification on the dominant precipitation of C2S phase in converter steel slag and self-powdering of steel slag[J]. Metallurgical Engineering, 2018, 5(2):77-84. doi: 10.12677/MEng.2018.52011 |
[9] | 冯修吉, 龙世宗. 微量离子对 $ \mathrm{\beta } $-C2S稳定性的影响及其机理研究[J]. 硅酸盐学报, 1985(4):424-432.FENG X J, LONG S Z. Effect of trace ions on the stability of -C2S and its mechanism[J]. Journal of Silicate, 1985(4):424-432. FENG X J, LONG S Z. Effect of trace ions on the stability of -C2S and its mechanism[J]. Journal of Silicate, 1985(4):424-432. |
[10] | 邹千, 马妍, 王玺堂, 等. Ba2+离子掺杂对C2S结构稳定性的影响[J]. 耐火材料, 2016, 50(4):265-268.ZOU Q, MA Y, WANG X T, et al. Effect of Ba2+ ion doping on the structural stability of C2S[J]. Refractory Materials, 2016, 50(4):265-268. doi: 10.3969/j.issn.1001-1935.2016.04.007 ZOU Q, MA Y, WANG X T, et al. Effect of Ba2+ ion doping on the structural stability of C2S[J]. Refractory Materials, 2016, 50(4):265-268. doi: 10.3969/j.issn.1001-1935.2016.04.007 |
[11] | 王莉. 冶金工业固体废物钢渣的综合利用探讨[J]. 冶金管理, 2020(5):197-199.WANG L. Discussion on comprehensive utilization of steel slag as solid waste in metallurgical industry[J]. Metallurgical Management, 2020(5):197-199. WANG L. Discussion on comprehensive utilization of steel slag as solid waste in metallurgical industry[J]. Metallurgical Management, 2020(5):197-199. |
[12] | 钟侚, 蹇守卫, 柯凯. V5+及Cr3+掺杂对C2S多晶型的影响机制[J]. 济南大学学报(自然科学版), 2011, 25(4):349-353.ZHONG X, JIAN S W, KE K. Mechanisms of the effects of V5+ and Cr3+ doping on the polycrystalline shape of C2S[J]. Journal of Jinan University (Natural Science Edition), 2011, 25(4):349-353. ZHONG X, JIAN S W, KE K. Mechanisms of the effects of V5+ and Cr3+ doping on the polycrystalline shape of C2S[J]. Journal of Jinan University (Natural Science Edition), 2011, 25(4):349-353. |
[13] | 许莹, 王巧玲, 胡晨光, 等. 氟化钙对重构钢渣胶凝活性和体积安定性的影响[J]. 钢铁钒钛, 2018, 39(5):86-92.XU Y, WANG Q L, HU C G, et al. Effect of calcium fluoride on the gelling activity and volume stability of reconstituted steel slag[J]. Iron and Steel Vanadium and Titanium, 2018, 39(5):86-92. XU Y, WANG Q L, HU C G, et al. Effect of calcium fluoride on the gelling activity and volume stability of reconstituted steel slag[J]. Iron and Steel Vanadium and Titanium, 2018, 39(5):86-92. |
[14] | 王达志, 包燕平, 王敏. CaF2和Na2O对钢渣含磷相析出过程的影响[A]. 中国金属学会. 第十二届中国钢铁年会论文集--2. 炼钢与连铸[C]. 中国金属学会: 中国金属学会, 2019: 7.WANG D Z, BAO Y P, WANG M. Effects of CaF2 and Na2O on the precipitation process of phosphorus-containing phases from steel slag[A]. Chinese Society for Metals. Proceedings of the 12th Annual Conference on Steel in China - 2. Steelmaking and Continuous Casting[C]. Chinese Society for Metals: Chinese Society for Metals, 2019: 7. WANG D Z, BAO Y P, WANG M. Effects of CaF2 and Na2O on the precipitation process of phosphorus-containing phases from steel slag[A]. Chinese Society for Metals. Proceedings of the 12th Annual Conference on Steel in China - 2. Steelmaking and Continuous Casting[C]. Chinese Society for Metals: Chinese Society for Metals, 2019: 7. |
XRD patterns of F-0 and C-0 calcined specimens
XRD patterns of specimens doped with CaF2
XRD patterns of specimens doped with CaF2
Microstructure and surface scans of F-7 calcined specimens and EDS energy spectrum of point 1
XRD patterns of C-0 and C-1 calcined specimens
XRD patterns of C-1~C-3 calcined specimens
XRD patterns of C-3~C-7 calcined specimens
Microstructure and surface scans of C-7 calcined specimens and EDS energy spectrum of point 2