Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2024 No. 3
Article Contents

PAN Zhengxian, JIANG Jiaqi, CAO Xin, WEI Yanhong, HE Yazi. Comprehensive Utilization Technology of Laterite Nickel Ore Residue[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(3): 187-192. doi: 10.3969/j.issn.1000-6532.2024.03.029
Citation: PAN Zhengxian, JIANG Jiaqi, CAO Xin, WEI Yanhong, HE Yazi. Comprehensive Utilization Technology of Laterite Nickel Ore Residue[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(3): 187-192. doi: 10.3969/j.issn.1000-6532.2024.03.029

Comprehensive Utilization Technology of Laterite Nickel Ore Residue

  • This is an article in the field of ceramics and composites. In order to effectively treat and resource utilize lateritic nickel slag, this study used lateritic nickel slags as raw materials and measured the pH value of leaching solution, metal leaching concentration, material unconfined compressive strength, dry shrinkage, elastic modulus, permeability coefficient and other indexes of the cementing material formed by cement solidification, and analyzed the feasibility of using it as backfill material for construction land or highway construction engineering materials. The results show that the cementitious material is made of waste slag (dry basis) 92%, PO42.5 cement 5%, bentonite 3%, PAC 0.5% and water, the pH value of leaching solution is about 8.45, the concentration of leaching metal ions is less than 0.1 mg/L, the unconfined compressive strength is 1.47 MPa, the modulus of elasticity is 1196 MPa, the permeability coefficient is 8.77×10-7 cm/s, and the dry shrinkage resistance is good. It can be used as backfill material for construction land or highway construction engineering. The raw soil cementitious material made of 92% raw soil (dry basis), 5% PO42.5 cement, 3% bentonite, 0.02% additional CHF and 5%~8% water has better dry shrinkage resistance. It can be used as the surface layer of large volume cementitious material to resist dry shrinkage cracks caused by long-term contact with dry air, protect the waste slag cementitious material in the lower layer and ensure the overall stability of cementitious materials. The above research provides a new way for the comprehensive utilization of laterite nickel slags, and lays a theoretical foundation for the research and engineering practice of waste slag as backfill materials or highway building materials.

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  • [1] 张振芳, 陈秀法, 李仰春, 等. “双碳”目标下镍资源的综合利用发展趋势[J]. 矿产综合利用, 2022(2):31-39.ZHANG Z F, CHEN X F, LI Y C, et al. Multipurpose utilization trend of nickel mineral resources under the goal of carbon peaking and carbon neutrality[J]. Multipurpose Utilization of Mineral Resources, 2022(2):31-39. doi: 10.3969/j.issn.1000-6532.2022.02.006

    CrossRef Google Scholar

    ZHANG Z F, CHEN X F, LI Y C, et al. Multipurpose utilization trend of nickel mineral resources under the goal of carbon peaking and carbon neutrality[J]. Multipurpose Utilization of Mineral Resources, 2022(2):31-39. doi: 10.3969/j.issn.1000-6532.2022.02.006

    CrossRef Google Scholar

    [2] 武兵强, 齐渊洪, 周和敏, 等. 红土镍矿火法冶炼工艺现状及进展[J]. 矿产综合利用, 2020(3):78-83.WU B Q, QI Y H, ZHOU H M, et al. Status and progress in pyrometallurgy processes of a laterite nickel ore[J]. Multipurpose Utilization of Mineral Resources, 2020(3):78-83. doi: 10.3969/j.issn.1000-6532.2020.03.012

    CrossRef Google Scholar

    WU B Q, QI Y H, ZHOU H M, et al. Status and progress in pyrometallurgy processes of a laterite nickel ore[J]. Multipurpose Utilization of Mineral Resources, 2020(3):78-83. doi: 10.3969/j.issn.1000-6532.2020.03.012

    CrossRef Google Scholar

    [3] 李洋洋, 李金辉, 张云芳, 等. 红土镍矿的开发利用及相关研究现状[J]. 材料导报, 2015, 29(17):79-83.LI Y Y, LI J H, ZHANG Y F, et al. Development and utilization of nickel laterite ore and current status of related research[J]. Materials Herald, 2015, 29(17):79-83.

    Google Scholar

    LI Y Y, LI J H, ZHANG Y F, et al. Development and utilization of nickel laterite ore and current status of related research[J]. Materials Herald, 2015, 29(17):79-83.

    Google Scholar

    [4] 杨泽宇, 张文, 申亚芳, 等. 红土镍矿处理方法现状[J]. 中国有色冶金, 2020, 49(4):1-6.YANG Z Y, ZHANG W, SHEN Y F, et al. Current status of treatment methods for nickel laterite ores[J]. China Nonferrous Metallurgy, 2020, 49(4):1-6.

    Google Scholar

    YANG Z Y, ZHANG W, SHEN Y F, et al. Current status of treatment methods for nickel laterite ores[J]. China Nonferrous Metallurgy, 2020, 49(4):1-6.

    Google Scholar

    [5] 李洁, 徐玉君, 沈洪涛, 等. 红土镍矿焙烧熟料溶出过程中镍的行为研究[J]. 矿产综合利用, 2019(5):37-41.LI J, XU Y J, SHEN H T, et al. Reaction behaviour of Ni during leaching from roasting materials of laterite nickel ore and ammonium sulfate[J]. Multipurpose Utilization of Mineral Resources, 2019(5):37-41. doi: 10.3969/j.issn.1000-6532.2019.05.008

    CrossRef Google Scholar

    LI J, XU Y J, SHEN H T, et al. Reaction behaviour of Ni during leaching from roasting materials of laterite nickel ore and ammonium sulfate[J]. Multipurpose Utilization of Mineral Resources, 2019(5):37-41. doi: 10.3969/j.issn.1000-6532.2019.05.008

    CrossRef Google Scholar

    [6] Saeed F, Lev F, Daniel F. Pre-concentration of nickel in laterite ores using physical separation methods[J]. Minerals Engineering, 2019, 141.

    Google Scholar

    [7] 施引珍, 钱忠伟, 周婷婷. 镍铁冶炼废渣在混凝土中的应用研究[J]. 江西建材, 2015(12):14-19.SHI Y Z, QIAN Z W, ZHOU T T. Research on the application of ferronickel smelting slag in concrete[J]. Jiangxi Building Materials, 2015(12):14-19.

    Google Scholar

    SHI Y Z, QIAN Z W, ZHOU T T. Research on the application of ferronickel smelting slag in concrete[J]. Jiangxi Building Materials, 2015(12):14-19.

    Google Scholar

    [8] 殷素红, 马健, 颜波, 等. 三种不同镍渣混合生产复合掺合料的研究[J]. 矿产综合利用, 2021(4):131-138.YIN S H, MA J, YAN B, et al. Study on the performance of compound admixture produced by Mixed grinding three different nickel slag[J]. Multipurpose Utilization of Mineral Resources, 2021(4):131-138. doi: 10.3969/j.issn.1000-6532.2021.04.020

    CrossRef Google Scholar

    YIN S H, MA J, YAN B, et al. Study on the performance of compound admixture produced by Mixed grinding three different nickel slag[J]. Multipurpose Utilization of Mineral Resources, 2021(4):131-138. doi: 10.3969/j.issn.1000-6532.2021.04.020

    CrossRef Google Scholar

    [9] 吕文强, 郑水林, 孙志明, 等. 红土镍矿酸浸渣硫酸铵焙烧-超声分散-离心分离提纯增白效果与机理[J]. 矿业科学学报, 2019, 4(6):564-572.LYU W Q, ZHENG S L, SUN Z M, et al. Effect and mechanism of whitening by ammonium sulfate roasting-ultrasonic dispersion-centrifugal separation purification of nickel laterite ore acid leaching slag[J]. Journal of Mining Science, 2019, 4(6):564-572.

    Google Scholar

    LYU W Q, ZHENG S L, SUN Z M, et al. Effect and mechanism of whitening by ammonium sulfate roasting-ultrasonic dispersion-centrifugal separation purification of nickel laterite ore acid leaching slag[J]. Journal of Mining Science, 2019, 4(6):564-572.

    Google Scholar

    [10] Cao Z, Ma B, Jing Q, et al. Facile and inexpensive preparation method of iron phosphate from laterite residue[J]. Ceramics International, 2020(prepublish).

    Google Scholar

    [11] 孙英娟, 周旋, 岳丽娜, 等. 工业固废制备聚合氯化铝铁及其在煤泥废水处理中的应用[J]. 矿产综合利用, 2021(1):144-150.SUN Y J, ZHOU X, YUE L N, et al. Preparation of polyaluminium ferric chloride from industrial solid waste and its application in coal slurry wastewater treat ment[J]. Multipurpose Utilization of Mineral Resources, 2021(1):144-150. doi: 10.3969/j.issn.1000-6532.2021.01.025

    CrossRef Google Scholar

    SUN Y J, ZHOU X, YUE L N, et al. Preparation of polyaluminium ferric chloride from industrial solid waste and its application in coal slurry wastewater treat ment[J]. Multipurpose Utilization of Mineral Resources, 2021(1):144-150. doi: 10.3969/j.issn.1000-6532.2021.01.025

    CrossRef Google Scholar

    [12] 郭小艳. CHF土壤固化剂在公路工程中的应用[J]. 中国公路, 2015(21):132-133.GUO X Y. Application of CHF soil curing agent in highway engineering[J]. China Highway, 2015(21):132-133. doi: 10.3969/j.issn.1006-3897.2015.21.032

    CrossRef Google Scholar

    GUO X Y. Application of CHF soil curing agent in highway engineering[J]. China Highway, 2015(21):132-133. doi: 10.3969/j.issn.1006-3897.2015.21.032

    CrossRef Google Scholar

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