Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2024 No. 3
Article Contents

CAO Huan, JIN Jianping, ZHAO Xiaoyi, LIANG Xiao, NING Xinxia. Low Temperature Sulfuric Acid Ripening-water Leaching for Vanadium Extraction from Stone Coal Vanadium Ore[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(3): 75-80. doi: 10.3969/j.issn.1000-6532.2024.03.012
Citation: CAO Huan, JIN Jianping, ZHAO Xiaoyi, LIANG Xiao, NING Xinxia. Low Temperature Sulfuric Acid Ripening-water Leaching for Vanadium Extraction from Stone Coal Vanadium Ore[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(3): 75-80. doi: 10.3969/j.issn.1000-6532.2024.03.012

Low Temperature Sulfuric Acid Ripening-water Leaching for Vanadium Extraction from Stone Coal Vanadium Ore

  • This is an article in the field of metallurgical engineering. The vanadium ore with vanadium containing sericite and illite in Shaanxi province was taken as the research object, low-temperature sulfuric acid ripening-water leaching process was used to extract vanadium. The effects of ripening temperature, ripening time, sulfuric acid dosage, sodium chloride dosage, leaching temperature, leaching time and liquid-solid ratio on vanadium leaching rate were investigated. The results show when 25% sulfuric acid and 0.8% sodium chloride are added to the stone coal vanadium ore, the sample is aged at 130 ℃ for 8 h, and the sample is leached at 55 ℃ for 2 h under the conditions of liquid-solid ratio of 1.5∶1, the vanadium leaching rate can reach more than 89%. This indicates that it is feasible to adopt low temperature sulfuric acid ripening and water leaching process to extract stone coal type vanadium ore.

  • 加载中
  • [1] 严伟平, 曾小波. 攀西地区钒钛磁铁矿资源开发利用水平评估方法研究[J]. 矿产综合利用, 2020(6):79-83.YAN W P, ZENG X B. Study on the evaluation method of development and utilization level of vanadium-titanium magnetite mine in Panxi district[J]. Multipurpose Utilization of Mineral Resources, 2020(6):79-83. doi: 10.3969/j.issn.1000-6532.2020.06.014

    CrossRef Google Scholar

    YAN W P, ZENG X B. Study on the evaluation method of development and utilization level of vanadium-titanium magnetite mine in Panxi district[J]. Multipurpose Utilization of Mineral Resources, 2020(6):79-83. doi: 10.3969/j.issn.1000-6532.2020.06.014

    CrossRef Google Scholar

    [2] 史政良, 严海军, 周玉娟. 甘肃某石煤钒矿焙烧灰渣综合利用工艺研究[J]. 矿产综合利用, 2020(3):158-163.SHI Z L, YAN H J, ZHOU Y J. Study on comprehensive utilization technology of sulphate roasting ash and slag of vanadium ore from stone coal in Gansu Province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):158-163. doi: 10.3969/j.issn.1000-6532.2020.03.027

    CrossRef Google Scholar

    SHI Z L, YAN H J, ZHOU Y J. Study on comprehensive utilization technology of sulphate roasting ash and slag of vanadium ore from stone coal in Gansu Province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):158-163. doi: 10.3969/j.issn.1000-6532.2020.03.027

    CrossRef Google Scholar

    [3] 王明, 程倩, 齐建云, 等. 石煤钒矿硫酸低温熟化—柱浸提钒工艺[J]. 矿冶, 2020, 29(3):62-67.WANG M, CHENG Q, QI J Y, et al. Sulfuric acid low-temperature maturation of stone coal vanadium ore-column leaching vanadium extraction process[J]. Mining and Metallurgy, 2020, 29(3):62-67. doi: 10.3969/j.issn.1005-7854.2020.03.013

    CrossRef Google Scholar

    WANG M, CHENG Q, QI J Y, et al. Sulfuric acid low-temperature maturation of stone coal vanadium ore-column leaching vanadium extraction process[J]. Mining and Metallurgy, 2020, 29(3):62-67. doi: 10.3969/j.issn.1005-7854.2020.03.013

    CrossRef Google Scholar

    [4] 赵玉卿, 王守敬, 田滔, 等. MLA在青海某石煤钒矿钒的赋存状态研究中的应用[J]. 矿产综合利用, 2020(1):89-93.ZHAO Y Q, WANG S J, TIAN T, et al. Application of MLA in the study of the occurrence state of vanadium in a rock coal vanadium ore in Qinghai[J]. Multipurpose Utilization of Mineral Resources, 2020(1):89-93. doi: 10.3969/j.issn.1000-6532.2020.01.018

    CrossRef Google Scholar

    ZHAO Y Q, WANG S J, TIAN T, et al. Application of MLA in the study of the occurrence state of vanadium in a rock coal vanadium ore in Qinghai[J]. Multipurpose Utilization of Mineral Resources, 2020(1):89-93. doi: 10.3969/j.issn.1000-6532.2020.01.018

    CrossRef Google Scholar

    [5] ZHANG Y M, BAO S X, LIU T, et al. The technology of extracting vanadium from stone coal in China: History, current status and future prospects[J]. Hydrometallurgy, 2011, 109(1/2):116-124.

    Google Scholar

    [6] 邢学永. 石煤钒矿低温碱性焙烧—水浸钒试验研究[J]. 湿法冶金, 2015, 34(4):275-278.XING X Y. Low-temperature alkaline roasting of stone coal vanadium ore—experimental research on water leaching vanadium[J]. Hydrometallurgy, 2015, 34(4):275-278.

    Google Scholar

    XING X Y. Low-temperature alkaline roasting of stone coal vanadium ore—experimental research on water leaching vanadium[J]. Hydrometallurgy, 2015, 34(4):275-278.

    Google Scholar

    [7] 贾秀敏, 李培佑, 黄永, 等. 陕西某钒矿石钙化焙烧-酸浸工艺研究[J]. 湿法冶金, 2015, 34(3):182-185+196.JIA X M, LI P Y, HUANG Y, et al. Study on the calcification roasting-acid leaching process of a vanadium ore in Shaanxi[J]. Hydrometallurgy, 2015, 34(3):182-185+196.

    Google Scholar

    JIA X M, LI P Y, HUANG Y, et al. Study on the calcification roasting-acid leaching process of a vanadium ore in Shaanxi[J]. Hydrometallurgy, 2015, 34(3):182-185+196.

    Google Scholar

    [8] 成宝海, 张廷安. 高温高压石煤提钒实验研究[J]. 长春师范大学学报, 2018, 37(12):73-74+96.CHENG B H, ZHANG T A. Experimental study on extracting vanadium from stone coal at high temperature and high pressure[J]. Journal of Changchun Normal University, 2018, 37(12):73-74+96.

    Google Scholar

    CHENG B H, ZHANG T A. Experimental study on extracting vanadium from stone coal at high temperature and high pressure[J]. Journal of Changchun Normal University, 2018, 37(12):73-74+96.

    Google Scholar

    [9] 张成强, 孙传尧, 印万忠, 等. 以氟化钙为助浸剂的某伊利石型含钒石煤提钒工艺[J]. 矿产综合利用, 2019(5):42-47.ZHANG C Q, SUN C Y, YIN W Z, et al. Acid leaching of vanadium from an illite-type vanadium- containing stone using calcium fluoride as aid-leaching reagent[J]. Multipurpose Utilization of Mineral Resources, 2019(5):42-47. doi: 10.3969/j.issn.1000-6532.2019.05.009

    CrossRef Google Scholar

    ZHANG C Q, SUN C Y, YIN W Z, et al. Acid leaching of vanadium from an illite-type vanadium- containing stone using calcium fluoride as aid-leaching reagent[J]. Multipurpose Utilization of Mineral Resources, 2019(5):42-47. doi: 10.3969/j.issn.1000-6532.2019.05.009

    CrossRef Google Scholar

    [10] 伍永国, 颜文斌, 蔡俊, 等. 复合添加剂对石煤中钒浸出率的影响[J]. 矿冶工程, 2019, 39(5):84-86+91.WU Y G, YAN W B, CAI J, et al. The effect of compound additives on the leaching rate of vanadium in stone coal[J]. Mining and Metallurgical Engineering, 2019, 39(5):84-86+91. doi: 10.3969/j.issn.0253-6099.2019.05.022

    CrossRef Google Scholar

    WU Y G, YAN W B, CAI J, et al. The effect of compound additives on the leaching rate of vanadium in stone coal[J]. Mining and Metallurgical Engineering, 2019, 39(5):84-86+91. doi: 10.3969/j.issn.0253-6099.2019.05.022

    CrossRef Google Scholar

    [11] 李丽洁, 石美莲, 华骏, 等. 二氧化锰氧化浸出石煤钒矿动力学研究[J]. 稀有金属与硬质合金, 2020, 48(6):24-29.LI L J, SHI M L, HUA J, et al. Study on the kinetics of manganese dioxide oxidation leaching stone coal Vanadium ore[J]. Rare Metals and Cemented Carbides, 2020, 48(6):24-29.

    Google Scholar

    LI L J, SHI M L, HUA J, et al. Study on the kinetics of manganese dioxide oxidation leaching stone coal Vanadium ore[J]. Rare Metals and Cemented Carbides, 2020, 48(6):24-29.

    Google Scholar

    [12] 王学文, 王明玉, 李青刚, 等. 一种石煤提钒矿石分解方法[P]. 中国: ZL 200810031050. 0, 2009.WANG X W, WANG M Y, LI Q G et al. A method for decomposing vanadium ore from stone coal[P]. China: ZL 200810031050. 0, 2009.

    Google Scholar

    WANG X W, WANG M Y, LI Q G et al. A method for decomposing vanadium ore from stone coal[P]. China: ZL 200810031050. 0, 2009.

    Google Scholar

    [13] 杨德芹, 梁晓峰, 郭学, 等. 含钒石煤硫酸化焙烧-超声浸出试验[J]. 金属矿山, 2014(7): 101-105.YANG D Q, LIANG X F, GUO X , et al. Sulfated roasting of vanadium-bearing stone coal-ultrasonic leaching test[J]. Metal Mine, 2014(7): 101-105.

    Google Scholar

    YANG D Q, LIANG X F, GUO X , et al. Sulfated roasting of vanadium-bearing stone coal-ultrasonic leaching test[J]. Metal Mine, 2014(7): 101-105.

    Google Scholar

    [14] 叶国华, 谢禹, 胡艺博, 等. 低品位石煤钒矿低温硫酸化焙烧-水浸提钒研究[J]. 稀有金属, 2020, 44(7):753-761.YE G H, XIE Y, HU Y B, et al. Study on Low-temperature Sulfated Roasting-Water Leaching Vanadium Extraction from Low-grade Stone Coal Vanadium Ore[J]. Rare Metals, 2020, 44(7):753-761.

    Google Scholar

    YE G H, XIE Y, HU Y B, et al. Study on Low-temperature Sulfated Roasting-Water Leaching Vanadium Extraction from Low-grade Stone Coal Vanadium Ore[J]. Rare Metals, 2020, 44(7):753-761.

    Google Scholar

    [15] 杨鑫龙, 冯雅丽, 李浩然. Na2CO3促进某硅质页岩中低价钒的钠化氧化作用研究[J]. 金属矿山, 2019(3):105-110.YANG X L, FENG Y L, LI H R. Research on Na2CO3 promoting sodium oxidation of low valence vanadium in a siliceous shale[J]. Metal Mine, 2019(3):105-110.

    Google Scholar

    YANG X L, FENG Y L, LI H R. Research on Na2CO3 promoting sodium oxidation of low valence vanadium in a siliceous shale[J]. Metal Mine, 2019(3):105-110.

    Google Scholar

    [16] 朱军, 康敏, 李维亮, 等. 粘土钒矿钡盐焙烧-酸浸提钒工艺研究[J]. 材料导报, 2020, 34(24):24061-24067.ZHU J, KANG M, LI W L et al. Study on the technology of extracting vanadium from clay vanadium ore by roasting and acid leaching[J]. Materials Review, 2020, 34(24):24061-24067. doi: 10.11896/cldb.19100158

    CrossRef Google Scholar

    ZHU J, KANG M, LI W L et al. Study on the technology of extracting vanadium from clay vanadium ore by roasting and acid leaching[J]. Materials Review, 2020, 34(24):24061-24067. doi: 10.11896/cldb.19100158

    CrossRef Google Scholar

    [17] 吕昌晓, 张廷安, 张莹, 等. 从钙化焙烧-酸浸尾渣中综合回收钒的研究[J]. 稀有金属, 2020, 44(11):1208-1214.LYU C X, ZHANG T A, ZHANG Y, et al. Comprehensive recovery of vanadium from calcification roasting-acid leaching tailings[J]. Rare Metals, 2020, 44(11):1208-1214.

    Google Scholar

    LYU C X, ZHANG T A, ZHANG Y, et al. Comprehensive recovery of vanadium from calcification roasting-acid leaching tailings[J]. Rare Metals, 2020, 44(11):1208-1214.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(9)

Tables(4)

Article Metrics

Article views(1142) PDF downloads(188) Cited by(0)

Access History

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint