Citation: | XUE Zhonghua, DONG Lianping, FAN Minqiang, YANG Chongyi, WANG Jiancheng, BAO Weiren. Extraction of Carbon from Fine Coal Gasification Slag by Hydrophobic-hydrophilic Separation[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(3): 63-69. doi: 10.3969/j.issn.1000-6532.2024.03.010 |
This is an article in the field of mining engineering. Coal gasification slag is a type of solid waste generated during the coal gasification process. The presence of residual carbon significantly limits its potential for reuse and recycling. Therefore, the extraction of residual carbon from coal gasification slag is a pressing concern. In this research, the separation of residual carbon and inorganic minerals from gasification fine slag was studied by hydrophobic-hydrophilic separation technology. The effects of stirring speed, stirring time, hydrophobic liquid dosage, pulp concentration, pulp temperature, and hydrophobic liquid type on the separation effect of carbon/ ash were investigated. The hydrophobic-hydrophilic separation technology has excellent carbon extraction and ash reduction effect on coal gasification slag, and the ash content of its carbon product can be up to 30% or less, while that of the ash product can be up to 95% or more. The separation mechanism was revealed by the characterisation analysis, which showed that the adsorption strength of residual carbon on paraffin was much higher than that of ash, which made the kerosene-treated residual carbon hydrophobicity greatly increased and easy to be captured by the oil phase. This study can provide important guidance for the efficient carbon extraction and ash reduction of coal gasification fine residue, which can help to achieve the comprehensive utilisation of coal gasification solid waste.
[1] | 杨丹, 王海锋, 黄志刚, 等. 纳米煤制备及其改善煤泥浮选的机理研究[J]. 矿产综合利用, 2021(2):70-76.YANG D, WANG H F, HUANG Z G, et al. Preparation of nano coal and its mechanism of improvement on coal flotation[J]. Multipurpose Utilization of Mineral Resources, 2021(2):70-76. doi: 10.3969/j.issn.1000-6532.2021.02.014 YANG D, WANG H F, HUANG Z G, et al. Preparation of nano coal and its mechanism of improvement on coal flotation[J]. Multipurpose Utilization of Mineral Resources, 2021(2):70-76. doi: 10.3969/j.issn.1000-6532.2021.02.014 |
[2] | 史达, 张建波, 杨晨年, 等. 煤气化灰渣脱碳技术研究进展[J]. 洁净煤技术, 2020, 26(6):1-10.SHI D, ZHANG J B, YANG C N, et al. Progress of coal gasification ash decarbonization technology[J]. Clean Coal Technology, 2020, 26(6):1-10. SHI D, ZHANG J B, YANG C N, et al. Progress of coal gasification ash decarbonization technology[J]. Clean Coal Technology, 2020, 26(6):1-10. |
[3] | 史兆臣, 戴高峰, 王学斌, 等. 煤气化细渣的资源化综合利用技术研究进展[J]. 华电技术, 2020, 42(7):63-73.SHI Z C, DAI G F, WANG X B, et al. Research progress on resource utilization technology of coal gasification fine slag[J]. Huadian Technology, 2020, 42(7):63-73. SHI Z C, DAI G F, WANG X B, et al. Research progress on resource utilization technology of coal gasification fine slag[J]. Huadian Technology, 2020, 42(7):63-73. |
[4] | 刘淑琴, 牛茂斐, 齐凯丽, 等. 煤炭地下气化特征污染物迁移行为探测[J]. 煤炭学报, 2018, 43(9):2618-2624.LIU S Q, NIU M F, QI K L, et al. Detection of characteristic pollutant migration behavior in underground coal gasification[J]. Journal of China Coal Society, 2018, 43(9):2618-2624. LIU S Q, NIU M F, QI K L, et al. Detection of characteristic pollutant migration behavior in underground coal gasification[J]. Journal of China Coal Society, 2018, 43(9):2618-2624. |
[5] | 晁岳建, 王洪记. 循环流化床锅炉掺烧气化渣和煤泥的可行性研究[J]. 化肥工业, 2015(3):48-50.CHAO Y J, WANG H J. The feasibility study of mixing gasification slag and coal slime in a circulating fluidized bed boiler[J]. Chemical Fertilizer Industry, 2015(3):48-50. doi: 10.3969/j.issn.1006-7779.2015.03.015 CHAO Y J, WANG H J. The feasibility study of mixing gasification slag and coal slime in a circulating fluidized bed boiler[J]. Chemical Fertilizer Industry, 2015(3):48-50. doi: 10.3969/j.issn.1006-7779.2015.03.015 |
[6] | 董永波. 水煤浆气化细渣碳资源回收及循环利用[J]. 氮肥技术, 2018, 39(3):25-26.DONG Y B. Recovery and recycling of carbon resources from coal-water slurry gasification fine slag[J]. Nitrogenous Fertilizer Technology, 2018, 39(3):25-26. DONG Y B. Recovery and recycling of carbon resources from coal-water slurry gasification fine slag[J]. Nitrogenous Fertilizer Technology, 2018, 39(3):25-26. |
[7] | 宁永安, 段一航, 高宁博, 等. 煤气化渣组分回收与利用技术研究进展[J]. 洁净煤技术, 2020(S1): 14-19.NING Y A, DUAN Y H , GAO N B, et al. Research progress in the recovery and utilization of coal gasification slag components[J]. Clean Coal Technology, 2020(S1): 14-19. NING Y A, DUAN Y H , GAO N B, et al. Research progress in the recovery and utilization of coal gasification slag components[J]. Clean Coal Technology, 2020(S1): 14-19. |
[8] | 曲江山, 张建波, 孙志刚, 等. 煤气化渣综合利用研究进展[J]. 洁净煤技术, 2020, 26(1): 184-193.QU J S, ZHANG J B, SUN Z G , et al. Research progress in comprehensive utilization of coal gasification slag[J]. Clean Coal Technology, 2020, 26(1): 184-193. QU J S, ZHANG J B, SUN Z G , et al. Research progress in comprehensive utilization of coal gasification slag[J]. Clean Coal Technology, 2020, 26(1): 184-193. |
[9] | 胡文豪. 煤气化渣铝硅组分活化分离与资源化利用基础研究[D]. 北京: 中国科学院大学, 2019.HU W H. Basic research on activation separation and resource utilization of aluminum and silicon components of coal gasification slag[D]. Beijing: University of Chinese Academy of Sciences, 2019. HU W H. Basic research on activation separation and resource utilization of aluminum and silicon components of coal gasification slag[D]. Beijing: University of Chinese Academy of Sciences, 2019. |
[10] | 汤云. 利用气化炉渣和煤矸石制备Sialon基复相陶瓷[D]. 西安: 西安建筑科技大学, 2011.TANG Y. Preparation of Sialon-based multiphase ceramics using gasification slag and coal gangue[D]. Xi'an: Xi'an University of Architecture and Technology, 2011. TANG Y. Preparation of Sialon-based multiphase ceramics using gasification slag and coal gangue[D]. Xi'an: Xi'an University of Architecture and Technology, 2011. |
Effect of mixing speed on the HHS separation
Effect of mixing time on the HHS separation
Effect of hydrophobic liquid dosage on the HHS separation
Effect of slurry concentration on the HHS separation
Effect of slurry temperature on the HHS separation
XRD patterns of the sample and separation products
Residual carbon and high ash heat flow lines of the sample by adsorption / desorption processing
FTIR spectra of the kerosene
FTIR spectra of residual carbon and ash before and after kerosene treatment