Research Status of Resource Utilization of Graphite Tailings

WANG Tao; HAN Shibin; JU Cheng

doi:10.3969/j.issn.1000-6532.2024.02.018

2024 No. 2

Article Contents

Article navigation > Multipurpose Utilization of Mineral Resources > 2024 > 45(2): 111-117

Next Article Previous Article

WANG Tao, HAN Shibin, JU Cheng. Research Status of Resource Utilization of Graphite Tailings[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 111-117. doi: 10.3969/j.issn.1000-6532.2024.02.018

Citation:

WANG Tao, HAN Shibin, JU Cheng. Research Status of Resource Utilization of Graphite Tailings[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 111-117. doi: 10.3969/j.issn.1000-6532.2024.02.018

Research Status of Resource Utilization of Graphite Tailings

School of Materials Science and Engineering, Jiamusi University, Jiamusi 154007, Heilongjiang, China

Received Date: 16 March 2023

Publish Date: 25 April 2024

Abstract

Abstract

This is an article in the field of mining engineering. Graphite is an inorganic nonmetallic material widely used in China, and it also plays an important role in chemical industry, electrical industry, national defense and high-tech fields. Graphite mining will produce a large number of tailings, it not only occupies a lot of land but also causes serious pollution to the ecological environment. By consulting a large number of documents, the current research status of graphite tailings resource utilization is summarized in this paper, and the problem of massive accumulation of graphite tailings is discussed, and some suggestions are put forward to help its resource utilization.
- Mining engineering /
- Graphite tailings /
- Resource utilization /
- Research status

FullText(HTML)

References

[1]	汤优优, 喻连香, 陈雄. 重介质选矿技术在处理有色金属矿和非金属矿的研究现状及展望[J]. 矿产综合利用, 2021(4):118-124.TANG Y Y, YU L X, CHEN X. Research status and prospects of heavy medium beneficiation technology in treating non-ferrous and non-metallic ores[J]. Multipurpose Utilization of Mineral Resources, 2021(4):118-124. Google Scholar TANG Y Y, YU L X, CHEN X. Research status and prospects of heavy medium beneficiation technology in treating non-ferrous and non-metallic ores[J]. Multipurpose Utilization of Mineral Resources, 2021(4):118-124. Google Scholar
[2]	黑龙江省萝北县石墨园区环境违法违规问题突出. 生态破坏严重[J]. 中国环境监察, 2021 (12): 25-26.Heilongjiang Province Luobei County graphite park environmental violations prominent problems[J]. China Environmental Supervision, 2021 (12): 25-26. Google Scholar Heilongjiang Province Luobei County graphite park environmental violations prominent problems[J]. China Environmental Supervision, 2021 (12): 25-26. Google Scholar
[3]	刘树永, 韩百岁, 陈中航, 等. 中低品位磷矿浮选药剂研究现状与展望[J]. 矿产综合利用, 2021(6):91-100.LIU S Y, HAN B S, CHEN Z H, et al. Current status and prospects of the research on flotation reagent for medium and low grade phosphorite ore[J]. Multipurpose Utilization of Mineral Resources, 2021(6):91-100. Google Scholar LIU S Y, HAN B S, CHEN Z H, et al. Current status and prospects of the research on flotation reagent for medium and low grade phosphorite ore[J]. Multipurpose Utilization of Mineral Resources, 2021(6):91-100. Google Scholar
[4]	李栋学, 张弛, 丛昕彧, 等. 高温活化石墨尾矿对水泥砂浆力学性能的影响[J]. 建设科技, 2020(23):93-97.LI D X, ZHANG C, CONG X Y, et al. Effect of high temperature activated graphite tailings on mechanical properties of cement mortar[J]. Construction Science and Technology, 2020(23):93-97. Google Scholar LI D X, ZHANG C, CONG X Y, et al. Effect of high temperature activated graphite tailings on mechanical properties of cement mortar[J]. Construction Science and Technology, 2020(23):93-97. Google Scholar
[5]	李磊, 魏旭, 遇祯, 等. 安徽省凤阳县焦台陈含金石墨矿物质组份研究[J]. 矿产综合利用, 2020(3):126-130.LI L, WEI X, YU Z, et al. Study on the mineral composition of gold-bearing graphite in Jiaotaichen, Fengyang county, Anhui province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):126-130. Google Scholar LI L, WEI X, YU Z, et al. Study on the mineral composition of gold-bearing graphite in Jiaotaichen, Fengyang county, Anhui province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):126-130. Google Scholar
[6]	Vasumathi N, Kumar T V V, Ratchambigai S, et al. Flotation studies on low grade graphite ore from eastern India[J]. International Journal of Mining Science and Technology, 2015, 25(3):415-420. doi: 10.1016/j.ijmst.2015.03.014 CrossRef Google Scholar
[7]	傅开彬, 徐信, 侯普尧, 等. 朝鲜某隐晶质石墨工艺矿物学及可浮性研究[J]. 金属矿山, 2021(3):148-152.FU K B, XU X, HOU P Y, et al. Study on process mineralogy and floatability of a cryptocrystalline graphite from DPR Korea[J]. Metal Mine, 2021(3):148-152. Google Scholar FU K B, XU X, HOU P Y, et al. Study on process mineralogy and floatability of a cryptocrystalline graphite from DPR Korea[J]. Metal Mine, 2021(3):148-152. Google Scholar
[8]	岑对对, 张韬, 于阳辉, 等. 黑龙江某石墨矿石大鳞片石墨回收及提纯实验研究[J]. 金属矿山, 2018(6):89-93.CEN D D, ZHANG T, YU Y H, et al. Experimental study on recovery and purification of large flake graphite from a graphite ore in Heilongjiang[J]. Metal Mine, 2018(6):89-93. Google Scholar CEN D D, ZHANG T, YU Y H, et al. Experimental study on recovery and purification of large flake graphite from a graphite ore in Heilongjiang[J]. Metal Mine, 2018(6):89-93. Google Scholar
[9]	张帅, 李亚, 牛艳萍, 等. 某片麻岩鳞片石墨矿浮选实验研究[J]. 矿产综合利用, 2022(2):111-115.ZHANG S, LI Y, NIU Y P, et al. Flotation test of a gneiss scale graphite ore[J]. Multipurpose Utilization of Mineral Resources, 2022(2):111-115. Google Scholar ZHANG S, LI Y, NIU Y P, et al. Flotation test of a gneiss scale graphite ore[J]. Multipurpose Utilization of Mineral Resources, 2022(2):111-115. Google Scholar
[10]	刘淑贤, 徐平安, 苏严, 等. 河北某地细粒石墨矿工艺矿物学及选矿工艺研究[J]. 矿产综合利用, 2021(1):157-165.LIU S X, XU P A, SU Y, et al. Study on process mineralogy and concentrating of the graphite ore in Heibei[J]. Multipurpose Utilization of Mineral Resources, 2021(1):157-165. Google Scholar LIU S X, XU P A, SU Y, et al. Study on process mineralogy and concentrating of the graphite ore in Heibei[J]. Multipurpose Utilization of Mineral Resources, 2021(1):157-165. Google Scholar
[11]	刘淑贤, 魏少波. 从石墨尾矿中回收绢云母的实验研究[J]. 中国矿业, 2013, 22(7):97-100.LIU S X, WEI S B. Experimental study on recovery of sericite from graphite tailings[J]. China Mining, 2013, 22(7):97-100. Google Scholar LIU S X, WEI S B. Experimental study on recovery of sericite from graphite tailings[J]. China Mining, 2013, 22(7):97-100. Google Scholar
[12]	李凤. 石墨尾矿中回收石墨和绢云母的选矿工艺研究[D]. 北京: 北京有色金属研究总院, 2014.LI F. Study on beneficiation technology of graphite and sericite recovered from graphite tailings [D]. Beijing: Beijing General Research Institute of Non-ferrous Metals, 2014. Google Scholar LI F. Study on beneficiation technology of graphite and sericite recovered from graphite tailings [D]. Beijing: Beijing General Research Institute of Non-ferrous Metals, 2014. Google Scholar
[13]	罗立群, 张晓雪, 林永峰, 等. 江西金尾矿资源的性质与绢云母提取研究[J]. 矿产综合利用, 2021(3):1-8.LUO L Q, ZHANG X X, LIN Y F, et al. Properties of gold tailing and sericite separation from gold tailing in Jiangxi Province[J]. Multipurpose Utilization of Mineral Resources, 2021(3):1-8. doi: 10.3969/j.issn.1000-6532.2021.03.001 CrossRef Google Scholar LUO L Q, ZHANG X X, LIN Y F, et al. Properties of gold tailing and sericite separation from gold tailing in Jiangxi Province[J]. Multipurpose Utilization of Mineral Resources, 2021(3):1-8. doi: 10.3969/j.issn.1000-6532.2021.03.001 CrossRef Google Scholar
[14]	徐正震, 梁精龙, 李慧, 等. 含钒废弃物中钒的回收研究现状及展望[J]. 矿产综合利用, 2020(3):8-13.XU Z Z, LIANG J L, LI H, et al. Research status and prospects of vanadium recovery in vanadium containing wastes[J]. Multipurpose Utilization of Mineral Resources, 2020(3):8-13. doi: 10.3969/j.issn.1000-6532.2020.03.002 CrossRef Google Scholar XU Z Z, LIANG J L, LI H, et al. Research status and prospects of vanadium recovery in vanadium containing wastes[J]. Multipurpose Utilization of Mineral Resources, 2020(3):8-13. doi: 10.3969/j.issn.1000-6532.2020.03.002 CrossRef Google Scholar
[15]	欧阳志军. 江西某石墨矿石综合回收石墨和钒实验研究[D]. 武汉: 武汉理工大学, 2016.OUYANG Z J. Experimental study on comprehensive recovery of graphite and vanadium from a graphite ore in Jiangxi [D]. Wuhan: Wuhan University of Technology, 2016. Google Scholar OUYANG Z J. Experimental study on comprehensive recovery of graphite and vanadium from a graphite ore in Jiangxi [D]. Wuhan: Wuhan University of Technology, 2016. Google Scholar
[16]	张曦月, 孙红娟, 彭同江, 等. 旺苍含钒石墨矿的工艺矿物学及钒的赋存状态研究[J]. 矿产综合利用, 2020(3):136-142.ZHANG X Y, SUN H J, PENG T J, et al. Study on the mineralogical study of graphite and the occurrence state of vanadium in Wangcang graphite in Sichuan province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):136-142. doi: 10.3969/j.issn.1000-6532.2020.03.023 CrossRef Google Scholar ZHANG X Y, SUN H J, PENG T J, et al. Study on the mineralogical study of graphite and the occurrence state of vanadium in Wangcang graphite in Sichuan province[J]. Multipurpose Utilization of Mineral Resources, 2020(3):136-142. doi: 10.3969/j.issn.1000-6532.2020.03.023 CrossRef Google Scholar
[17]	张莉莉, 李波, 李美荣, 等. 莫桑比克某含钒石墨矿工艺矿物学研究[J]. 矿产综合利用, 2020(5):110-114.ZHANG L L, LI B, LI M R, et al. Processing mineralogy of a vanadium-bearing graphite ore from Mozambique[J]. Multipurpose Utilization of Mineral Resources, 2020(5):110-114. doi: 10.3969/j.issn.1000-6532.2020.05.016 CrossRef Google Scholar ZHANG L L, LI B, LI M R, et al. Processing mineralogy of a vanadium-bearing graphite ore from Mozambique[J]. Multipurpose Utilization of Mineral Resources, 2020(5):110-114. doi: 10.3969/j.issn.1000-6532.2020.05.016 CrossRef Google Scholar
[18]	王文齐, 文贵强, 李玉峰, 等. 某石墨尾矿回收钒实验研究[J]. 中国非金属矿工业导刊, 2020(6):30-33.WANG W Q, WEN G Q, LI Y F, et al. Experimental study on recovery of vanadium from graphite tailings[J]. China Non-Metallic Ore Industry Guide, 2020(6):30-33. doi: 10.3969/j.issn.1007-9386.2020.06.008 CrossRef Google Scholar WANG W Q, WEN G Q, LI Y F, et al. Experimental study on recovery of vanadium from graphite tailings[J]. China Non-Metallic Ore Industry Guide, 2020(6):30-33. doi: 10.3969/j.issn.1007-9386.2020.06.008 CrossRef Google Scholar
[19]	陈宝海. 利用黑龙江萝北云山石墨尾矿制备烧结砖的工艺与机理研究[D]. 北京: 中国地质大学, 2012.CHEN B H. Study on technology and mechanism of sintering brick from Yunshan graphite tailings of Luobei, Heilongjiang [D]. Beijing: China University of Geosciences, 2012. Google Scholar CHEN B H. Study on technology and mechanism of sintering brick from Yunshan graphite tailings of Luobei, Heilongjiang [D]. Beijing: China University of Geosciences, 2012. Google Scholar
[20]	徐晓虹, 金昊, 吴建锋, 等. 一种利用石墨尾矿制备陶瓷仿古砖的方法: ZL201910042607.9[P]. 2019.04. 16.XU X H, JIN H, WU J F, et al. A method of preparing ceramic antique tiles using graphite tailings: ZL201910042607.9[P]. 2019.04. 16. Google Scholar XU X H, JIN H, WU J F, et al. A method of preparing ceramic antique tiles using graphite tailings: ZL201910042607.9[P]. 2019.04. 16. Google Scholar
[21]	程飞飞, 于阳辉, 张韬. 利用石墨尾矿制备陶瓷砖的实验研究[J]. 非金属矿, 2020, 43(4):62-64.CHENG F F, YU Y H, ZHANG T. Experimental study on preparation of ceramic bricks from graphite tailings[J]. Non-metallic Mines, 2020, 43(4):62-64. doi: 10.3969/j.issn.1000-8098.2020.04.017 CrossRef Google Scholar CHENG F F, YU Y H, ZHANG T. Experimental study on preparation of ceramic bricks from graphite tailings[J]. Non-metallic Mines, 2020, 43(4):62-64. doi: 10.3969/j.issn.1000-8098.2020.04.017 CrossRef Google Scholar
[22]	杨中喜, 岳云龙, 陶文宏, 等. 利用固化技术研制石墨尾矿墙体材料[J]. 河南建材, 2001, 3(2):13-14.YANG Z X, YUE Y L, TAO W H, et al. Development of graphite tailings wall material by solidification technology[J]. Henan Building Materials, 2001, 3(2):13-14. doi: 10.3969/j.issn.1008-9772.2001.02.005 CrossRef Google Scholar YANG Z X, YUE Y L, TAO W H, et al. Development of graphite tailings wall material by solidification technology[J]. Henan Building Materials, 2001, 3(2):13-14. doi: 10.3969/j.issn.1008-9772.2001.02.005 CrossRef Google Scholar
[23]	房建果, 姚占勇, 苏公灿, 等. 石墨尾矿用作高速公路底基层[J]. 山东大学学报, 2003(5):562-567.FANG J G, YAO Z Y, SU G C, et al. Graphite tailings used as expressway base[J]. Journal of Shandong University, 2003(5):562-567. Google Scholar FANG J G, YAO Z Y, SU G C, et al. Graphite tailings used as expressway base[J]. Journal of Shandong University, 2003(5):562-567. Google Scholar
[24]	毛洪录, 赵东江, 赵军, 等. 石墨矿渣在高速公路底基层中应用[J]. 辽宁工程技术大学学报, 2005(2):202-204.MAO H L, ZHAO D J, ZHAO J, et al. Application of graphite slag in expressway base[J]. Journal of Liaoning Technical University, 2005(2):202-204. Google Scholar MAO H L, ZHAO D J, ZHAO J, et al. Application of graphite slag in expressway base[J]. Journal of Liaoning Technical University, 2005(2):202-204. Google Scholar
[25]	王丽娜, 申保磊. 石墨矿尾矿制备路面砖面层的实验研究[J]. 中国非金属矿工业导刊, 2012(5):24-27.WANG L N, SHEN B L. Experimental study on preparation of pavement brick with graphite tailings[J]. China Non-Metallic Ore Industry Guide, 2012(5):24-27. doi: 10.3969/j.issn.1007-9386.2012.05.009 CrossRef Google Scholar WANG L N, SHEN B L. Experimental study on preparation of pavement brick with graphite tailings[J]. China Non-Metallic Ore Industry Guide, 2012(5):24-27. doi: 10.3969/j.issn.1007-9386.2012.05.009 CrossRef Google Scholar
[26]	高东, 赵海涛, 仲伟程. 大掺量石墨尾矿绿色泡沫混凝土的研究[J]. 散装水泥, 2022(3):181-184.GAO D, ZHAO H T, ZHONG W C. Study on green foamed concrete with large graphite tailings[J]. Bulk Cement, 2022(3):181-184. doi: 10.3969/j.issn.1007-3922.2022.03.061 CrossRef Google Scholar GAO D, ZHAO H T, ZHONG W C. Study on green foamed concrete with large graphite tailings[J]. Bulk Cement, 2022(3):181-184. doi: 10.3969/j.issn.1007-3922.2022.03.061 CrossRef Google Scholar
[27]	Peng Y, Liu Y, Zhan B, et al. Preparation of autoclaved aerated concrete by using graphite tailings as an alternative silica source[J]. Construction and Building Materials, 2021, 26(8):129-135. Google Scholar
[28]	Hongbo Liu, Kun Liu, Zhu Lan, et al. Mechanical and electrical characteristics of graphite tailing concrete[J]. Advances in Materials Science and Engineering, vol. 2018, 7(5): 120-129. Google Scholar
[29]	Liu H, Duan H, Gao H, et al. Graphite tailings’ effects on mechanical and physical properties of eco-efficient steel fiber-reinforced concrete[J]. Buildings, 2022, 12(5):509-516. doi: 10.3390/buildings12050509 CrossRef Google Scholar
[30]	Wang Z R , Li B , Liu H B , et al. Degradation characteristics of graphite tailings cement mortar subjected to freeze-thaw cycles[J]. Construction and Building Materials, 2020, 23(4): 117-125. Google Scholar
[31]	刘洪波, 李兴, 佟瑶, 等. 石墨尾矿碳纤维混凝土电阻率与力学参数的相关性研究[J]. 黑龙江大学工程学报, 2020, 11(2):11-15.LIU H B, LI X, TONG Y, et al. Study on the correlation between electrical resistivity and mechanical parameters of carbon fiber concrete with graphite tailings[J]. Journal of Engineering of Heilongjiang University, 2020, 11(2):11-15. Google Scholar LIU H B, LI X, TONG Y, et al. Study on the correlation between electrical resistivity and mechanical parameters of carbon fiber concrete with graphite tailings[J]. Journal of Engineering of Heilongjiang University, 2020, 11(2):11-15. Google Scholar
[32]	郭金秋. 微波养护对含石墨尾矿混凝土早期性能的影响[D]. 哈尔滨: 哈尔滨工业大学, 2020.GUO J Q. The effect of microwave curing on the early performance of graphite containing tailings concrete [D]. Harbin: Harbin University of Technology, 2020. Google Scholar GUO J Q. The effect of microwave curing on the early performance of graphite containing tailings concrete [D]. Harbin: Harbin University of Technology, 2020. Google Scholar
[33]	Xue J, Wang X, Wang Z, et al. Investigations on influencing factors of resistivity measurement for graphite tailings concrete[J]. Cement and Concrete Composites, 2021, 12(3):104-112. Google Scholar
[34]	冯博雅, 夏洪春, 朱训国, 等. 石墨尾矿砂混凝土梁抗弯性能实验研究[J]. 西安理工大学学报, 2022, 38(2):279-286.FENG B Y, XIA H C, ZHU X G, et al. Experimental study on flexural performance of graphite tailings concrete beams[J]. Journal of Xi'an University of Technology, 2022, 38(2):279-286. Google Scholar FENG B Y, XIA H C, ZHU X G, et al. Experimental study on flexural performance of graphite tailings concrete beams[J]. Journal of Xi'an University of Technology, 2022, 38(2):279-286. Google Scholar
[35]	陈真, 陈松, 刘猛锐, 等. 不同替代率石墨尾矿砂混凝土断裂实验[J]. 科学技术与工程, 2021, 21(22):9541-9548.CHEN Z, CHEN S, LIU M R, et al. Fracture test of concrete with different substitution rates of graphite tailings[J]. Science and Engineering, 2021, 21(22):9541-9548. doi: 10.3969/j.issn.1671-1815.2021.22.050 CrossRef Google Scholar CHEN Z, CHEN S, LIU M R, et al. Fracture test of concrete with different substitution rates of graphite tailings[J]. Science and Engineering, 2021, 21(22):9541-9548. doi: 10.3969/j.issn.1671-1815.2021.22.050 CrossRef Google Scholar
[36]	何善能, 秦毅. 石墨尾矿混凝土耐久性与抗氯离子侵蚀性研究[J]. 金属矿山, 2022(6):225-229.HE S N, QIN Y. Study on durability and chloride ion resistance of graphite tailings concrete[J]. Metal Mines, 2022(6):225-229. Google Scholar HE S N, QIN Y. Study on durability and chloride ion resistance of graphite tailings concrete[J]. Metal Mines, 2022(6):225-229. Google Scholar
[37]	王允威, 魏弦, 邹敏. 工业废渣制备透水材料工艺的研究[J]. 广东建材, 2017, 33(12):3-7.WANG Y W, WEI X, ZOU M. Research on the process of preparing permeable materials from industrial waste residue[J]. Guangdong Building Materials, 2017, 33(12):3-7. doi: 10.3969/j.issn.1009-4806.2017.12.002 CrossRef Google Scholar WANG Y W, WEI X, ZOU M. Research on the process of preparing permeable materials from industrial waste residue[J]. Guangdong Building Materials, 2017, 33(12):3-7. doi: 10.3969/j.issn.1009-4806.2017.12.002 CrossRef Google Scholar
[38]	王允威, 魏弦, 马光强. 工艺参数对石墨尾矿透水材料性能影响的研究[J]. 福建建材, 2018(1):5-7.WANG Y W, WEI X, MA G Q. Research on the influence of process parameters on the performance of graphite tailings permeable materials[J]. Fujian Building Materials, 2018(1):5-7. Google Scholar WANG Y W, WEI X, MA G Q. Research on the influence of process parameters on the performance of graphite tailings permeable materials[J]. Fujian Building Materials, 2018(1):5-7. Google Scholar
[39]	彭寿, 任东风, 文贵强, 等. 一种石墨尾矿的利用方法: ZL202011467108. 3[P]. 2021.03. 19.PENG S, REN D F, WEN G Q, et al. A method for utilizing graphite tailings: ZL202011467108 3[P]. 2021.03. 19. Google Scholar PENG S, REN D F, WEN G Q, et al. A method for utilizing graphite tailings: ZL202011467108 3[P]. 2021.03. 19. Google Scholar
[40]	王哲飞, 潘卫, 于阳辉, 等. 一种石墨尾矿基微波介质陶瓷材料及其制备方法: ZL202110436475. 5[P]. 2021.07. 16WANG Z F, PAN W, YU Y H, et al. A graphite tailings based microwave dielectric ceramic material and its preparation method: ZL202110436475 5[P]. 2021.07. 16. Google Scholar WANG Z F, PAN W, YU Y H, et al. A graphite tailings based microwave dielectric ceramic material and its preparation method: ZL202110436475 5[P]. 2021.07. 16. Google Scholar
[41]	海韵. 黑龙江萝北石墨尾矿的工艺矿物学研究及其在导电橡胶中的应用[D]. 北京: 中国地质大学, 2015.HAI Y. Study on process mineralogy of graphite tailings from Luobei, Heilongjiang Province and its application in conductive rubber [D]. Beijing: China University of Geosciences, 2015. Google Scholar HAI Y. Study on process mineralogy of graphite tailings from Luobei, Heilongjiang Province and its application in conductive rubber [D]. Beijing: China University of Geosciences, 2015. Google Scholar
[42]	Fu Y, Jin Y, Ma J, et al. Lithium-ion transfer strengthened by graphite tailings and coking coal for high-rate performance anode[J]. Chemical Engineering Journal, 2022, 22(5):136-145. Google Scholar