| Citation: | PANG Baobao, HU Yingmo, ZHANG Zhen, CUI Kui, WU Shasha, GUO Sufang. C-CNF Surface Modified Tourmaline and its Dispersion Stability[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(2): 100-104, 117. doi: 10.3969/j.issn.1000-6532.2024.02.016 | 
This is an article in the field of mineral processing engineering. Tourmaline has been widely used for its spontaneous polarity, pyroelectric effect, far-infrared radiation and negative-ion release effect. In order to increase its stability in water-based coatings and improve its performance in water-based coatings, in this work, the surface modification of tourmaline with carboxylated nanolocellulose (C-CNF) was studied and optimized. The test results show that the performance of modified tourmaline was optimal while the addition of C-CNF was 2 g, solid-to-liquid ratio 1:5, and reacted 2h at 50 ℃, its turbidity reached 1361 ntu, contact angle to 53o. It was found that C-CNF was successfully grafted to the tourmaline surface by means of characterization of the modified tourmaline, and the dispersion of the modified tourmaline in the aqueous medium was better improved.
		                | [1] | Fuat Yavuz. TOURMAL: software package for tourmaline, tourmaline-rich rocks and related ore deposits[J]. Computers and Geosciences, 1997, 23(9):947-959. doi: 10.1016/S0098-3004(97)00080-0 | 
| [2] | 杨进忠, 毛益林, 陈晓青, 等. 某尾矿资源化处置与综合利用[J]. 矿产综合利用, 2019(6):117-122.YANG J Z, MAO Y L, CHEN X Q, et al. Study on resource disposal and comprehensive utilization of tailings[J]. Multipurpose Utilization of Mineral Resources, 2019(6):117-122. YANG J Z, MAO Y L, CHEN X Q, et al. Study on resource disposal and comprehensive utilization of tailings[J]. Multipurpose Utilization of Mineral Resources, 2019(6):117-122. | 
| [3] | 邱明华, 李强, 念保义, 等. 白炭黑表面改性研究现状及进展[J]. 矿产综合利用, 2020(3):40-47.QIU M H, LI Q, NIAN B Y, et al. Research status and development of precipitated silica surface modification[J]. Multipurpose Utilization of Mineral Resources, 2020(3):40-47. QIU M H, LI Q, NIAN B Y, et al. Research status and development of precipitated silica surface modification[J]. Multipurpose Utilization of Mineral Resources, 2020(3):40-47. | 
| [4] | Kairen Chen, Xinghui Gai, Guojun Zhou, et al. Study on a new type of pyroelectric materials with structure of tourmaline[J]. Ceramics International, 2019, 45(8):10684-10690. doi: 10.1016/j.ceramint.2019.02.139 | 
| [5] | Liang Yafeng, Tang Xuejiao, Zhu Qing, et al. A review: Application of tourmaline in environmental fields[J]. Chemosphere, 2021, 281(11):130780. | 
| [6] | Xiaorui Zhang, Xingxing Zhou, Xinquan Xu, et al. Enhancing the functional and environmental properties of asphalt binders and asphalt mixtures using tourmaline anion powder modification[J]. Coatings, 2021, 11(5):550. doi: 10.3390/coatings11050550 | 
| [7] | Xiaoyu Han, Junping Meng, Jie Liu, et al. Enhanced far infrared radiation properties of functional ceramics derived from iron ore tailings incorporating tourmaline particles[J]. Ceramics International, 2020, 11:247. | 
| [8] | 胡应模, 安文峰, 张丹丹, 等. 含电气石的功能聚合物的合成及其功能纤维试制[J]. 功能材料, 2021, 52(2):2034-2038.HU Y M, AN W F, ZHANG D D, et al. Synthesis of functional polymers containing tourmaline and trial production of their functional fibers[J]. Functional Materials, 2021, 52(2):2034-2038. HU Y M, AN W F, ZHANG D D, et al. Synthesis of functional polymers containing tourmaline and trial production of their functional fibers[J]. Functional Materials, 2021, 52(2):2034-2038. | 
| [9] | 安文峰, 胡应模, 张丹丹, 等. 硅烷偶联剂KH570 对电气石表面改性条件优化与表征[J]. 矿产综合利用, 2021(1):193-198.AN W F, HU Y M, ZHANG D D, et al. Optimization and characterization of surface modification of tourmaline by silane coupling agent KH570[J]. Multipurpose Utilization of Mineral Resources, 2021(1):193-198. AN W F, HU Y M, ZHANG D D, et al. Optimization and characterization of surface modification of tourmaline by silane coupling agent KH570[J]. Multipurpose Utilization of Mineral Resources, 2021(1):193-198. | 
| [10] | 崔瑞, 王旭, 魏骞, 等. 湖北某重晶石-萤石型矿综合利用研究[J]. 矿产综合利用, 2019(2):70-74.CUI R, WANG X, WEI Q, et al. Study on comprehensive utilization of a barite-fluorite ore in Hubei province[J]. Multipurpose Utilization of Mineral Resources, 2019(2):70-74. CUI R, WANG X, WEI Q, et al. Study on comprehensive utilization of a barite-fluorite ore in Hubei province[J]. Multipurpose Utilization of Mineral Resources, 2019(2):70-74. | 
| [11] | 张峰, 王怀法. 乳化捕收剂稳定性的探索及应用[J]. 矿产综合利用, 2019(6):55-59.ZHANG F, WANG H F. Research and application of stability of emulsifying collector[J]. Multipurpose Utilization of Mineral Resources, 2019(6):55-59. ZHANG F, WANG H F. Research and application of stability of emulsifying collector[J]. Multipurpose Utilization of Mineral Resources, 2019(6):55-59. | 
| [12] | 纪莹蕾. 智能浊度传感器的研究与设计[D]. 合肥: 中国科学技术大学, 2014.JI Y L. Research and design of intelligent turbidity sensor [D]. Hefei: University of Science and Technology of China, 2014. JI Y L. Research and design of intelligent turbidity sensor [D]. Hefei: University of Science and Technology of China, 2014. | 
| [13] | 李贤勇. 接触角的测试方法及其在烟用接装纸原纸上的应用[J]. 中华纸业, 2019, 40(22):26-29.LI X Y. Test method for contact angle and its application to cigarette splicing paper base paper[J]. China Paper, 2019, 40(22):26-29. LI X Y. Test method for contact angle and its application to cigarette splicing paper base paper[J]. China Paper, 2019, 40(22):26-29. | 
| [14] | 李雯雯, 吴瑞华, 董颖. 电气石红外光谱和红外辐射特性的研究[J]. 高校地质学报, 2008(3):426-432.LI W W, WU R H, DONG Y. Study on infrared spectra and infrared radiation properties of tourmaline[J]. Journal of College Geology, 2008(3):426-432. LI W W, WU R H, DONG Y. Study on infrared spectra and infrared radiation properties of tourmaline[J]. Journal of College Geology, 2008(3):426-432. | 
			            
			            
			            
			        Effect of C-CNF dosage on the modification effect of tourmaline
Effect of the reaction temperature on the modification effect of the tourmaline
Effect of the reaction time on the modification effect of the tourmaline
Infrared spectroscopy of unmodified and modified tourmaline
XRD spectrum of unmodified (a) and modified tourmaline (b)
SEM of unmodified tourmaline (a) and modified tourmaline (b)
3.5 h settlement experiment unmodified (a) and modified (b) tourmaline