Citation: | LI Dewei, DAI Wenzhi, LI Jie, LI Jiaxin, NIE Guanghua. Flotation Test of Acid Leaching Tailings of Barium Slag in Guizhou[J]. Multipurpose Utilization of Mineral Resources, 2024, 45(1): 207-210. doi: 10.3969/j.issn.1000-6532.2024.01.028 |
This is an article in the field of mineral processing engineering. Barium slag is toxic solid waste, and a large amount of barium slag is piled up to seriously harm the environment and cause huge waste of national land resources. Acid-dissolving barium in acid leaching barium residue is one of the best ways to dispose of barium residue and recover barium. The paper adopts the flotation process to recover the barium sulfate in the acid leaching tailings of the enriched barium slag, in order to realize the comprehensive recovery of barium resources in the barium slag. The experimental research of the flotation recovery of barium residue acid leaching residue shows that. Under the condition that the amount of sodium carbonate is 2000 g/t, the amount of sodium silicate is 500 g/t and the amount of sodium oleate is 3000 g/t, through the flotation closed-circuit process of one roughing, four beneficiation, and two sweeping. Obtained the flotation index of 85.38% barite concentrate grade and 69.35% recovery rate. Concentrate products meet the barite standards used in the industrial production of barium carbonate.
[1] | Yang T, Wang N, Gu H, et al. Froth flotation separation of carbon from barium slag: Recycling of carbon and minimize the slag[J]. Waste Management, 2021, 120. |
[2] |
李祖荣. 钡渣淋溶实验研究及钡渣填埋场淋溶液处理工艺探讨[D]. 武汉: 武汉理工大学, 2017.LI Z R. Experimental study on barium slag leaching and discussion on the treatment process of barium slag landfill leaching solution [D]. Wuhan: Wuhan University of Technology, 2017.
|
[3] |
王海峰, 陈雁冰, 龙召凤, 等. 硫酸钠对钡渣的无害化效果研究[J]. 广州化工, 2020, 48(4):27-29,32.WANG H F, CHEN Y B, LONG Z F, et al. Research on the harmless effect of sodium sulfate on barium slag[J]. Guangzhou Chemical Industry, 2020, 48(4):27-29,32.
|
[4] |
袁志宇, 李祖荣, 夏静. 钡渣入场填埋前的预处理工艺条件研究[J]. 武汉理工大学学报, 2016, 38(9):67-71.YUAN Z Y, LI Z R, XIA J. Research on pretreatment process conditions of barium slag admission before landfill[J]. Journal of Wuhan University of Technology, 2016, 38(9):67-71.
|
[5] |
郭斌, 任爱玲, 吴根, 等. 钡渣中钡离子的淋溶释放规律[J]. 环境污染与防治, 2001, 23(3):98-100,104.GUO B, REN A L, WU G, et al. Release pattern of barium ions from barium slag by leaching[J]. Environmental Pollution and Prevention, 2001, 23(3):98-100,104.
|
[6] | Chen P, Ma B, Tan H, et al. Utilization of barium slag to improve chloride-binding ability of cement-based material[J]. Journal of Cleaner Production, 2021, 283. |
[7] |
甘四洋, 陈彦翠, 贾韶辉, 等. 工业固体废弃物钡渣的资源化综合利用研究[J]. 建材发展导向, 2015, 13(4):36-38.GAN S Y, CHEN Y C, JIA S H, et al. Research on resource utilization of industrial solid waste barium slag[J]. Building Materials Development Orientation, 2015, 13(4):36-38.
|
[8] |
刘一思. 钡渣的性能测试及应用研究[D]. 贵阳: 贵州大学, 2020.LIU Y S. Research on the performance test and application of barium slag [D]. Guiyang: Guizhou University, 2020.
|
[9] |
王湘徽, 颜湘华, 栗歆. 钡渣的污染特性与资源化利用风险研究[J]. 环境工程技术学报, 2016, 6(2):170-174.WANG X H, YAN X H, LI X. Research on the pollution characteristics and risk of resource utilization of barium slag[J]. Journal of Environmental Engineering Technology, 2016, 6(2):170-174.
|
[10] |
刘立柱, 贾韶辉, 王勇, 等. 钡渣在建材产品中的应用及其重金属固化效果研究[J]. 砖瓦, 2017(5):25-27.LIU L Z, JIA S H, WANG Y, et al. Research on the application of barium slag in building material products and its heavy metal curing effect[J]. Brick and Tile, 2017(5):25-27.
|
[11] |
陈英军. 含钡废渣制氯化钡的研究[J]. 无机盐工业, 2001(5):35-36.CHEN Y J. Study on the production of barium chloride from barium-containing waste slag[J]. Inorganic Salt Industry, 2001(5):35-36.
|
[12] |
刘攀, 张煜, 王艳书, 等. 盐酸浸取钡渣中钡离子工艺路线研究[J]. 广东化工, 2014, 41(22):12-13.LIU P, ZHANG Y, WANG Y S, et al. Research on the process route of barium ion extraction from barium slag by hydrochloric acid leaching[J]. Guangdong Chemical Industry, 2014, 41(22):12-13.
|
[13] |
童义隆, 付金涛, 舒超, 等. 贵州重晶石与方解石常温浮选分离试验研究[J]. 矿产综合利用, 2020(1):54-58.TONG Y L, FU J T, SHU C, et al. Research on flotation test of separation of barite and calcite from Guizhou at normal temperature[J]. Multipurpose Utilization of Mineral Resources, 2020(1):54-58.
|
Test procedure for rough selection of acid leaching residue
Effect of Na2CO3 dosage on the flotation index of acid leaching residue
Effect of the amount of sodium silicate on the flotation index of acid leaching residue
Effect of the amount of sodium oleate on the flotation index of acid leaching residue
Open-circuit test flow of barium slag leaching slag flotation