Citation: | Liu Xingping, Zeng Muyuan, Chen Song, Bao Shenxu, Li Keyao, Yang Siyuan. Beneficiation Process of Low-Grade Manganese Carbonate Ore with High Phosphorus and Calcium in Hubei Province[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(5): 148-153. doi: 10.3969/j.issn.1000-6532.2023.05.025 |
This is an essay in the field of mineral processing engineering. The process mineralogy study of a manganese carbonate ore from Hubei Province shows that the main valuable minerals of this ore are kutnohorite, calcimangite and a small amount of pyrolusite with fine monomer dissociation, the gangue minerals are dolomite, quartz and mica. The present manganese carbonate ore belongs to refractory low-grade manganese carbonate ore with high calcium and phosphorus. There are few studies on this type of manganese ore, thereby the treatment process is complicated with the low product grade and the high cost. The mineral processing results of this study reveal that, under the condition of 90% of the products from stage grinding to -74 μm, manganese minerals were recovered by magnetic separation through the process of cleaning mixed concentrate with one roughing and one cleaning tailings, and further enriched by one-stage reverse flotation desilication. Finally, a manganese concentrate with Mn grade of 27.10%, P/Mn ratio of 0.009 and Mn recovery of 58.21% was obtained, which can be mixed with other low-phosphorus manganese concentrates as the metallurgical industrial raw material to meet the industrial requirements.
[1] | 邓文兵, 张彦文, 孔令湖, 等. 中国锰矿资源现状与国家级锰矿床实物地质资料筛选[J]. 中国矿业, 2019, 28(9):175-182. DENG W B, ZHANG Y W, KONG L H, et al. Current status of manganese ore resources in China and selecting for national physical geological data of manganese ore deposits[J]. China Mining Magazine, 2019, 28(9):175-182. DENG W B, ZHANG Y W, KONG L H, et al. Current status of manganese ore resources in China and selecting for national physical geological data of manganese ore deposits[J]. China Mining Magazine, 2019, 28(9): 175-182. |
[2] | 李勇, 罗星, 夏瑜. 广西某氧化锰矿选矿实验研究[J]. 矿产综合利用, 2020(5):58-62. LI Y, LUO X, XIA Y. Experimental research on mineral processing of a manganese oxide ore in Guangxi[J]. Multipurpose Utilization of Mineral Resources, 2020(5):58-62. LI Y, LUO X, XIA Y. Experimental research on mineral processing of a manganese oxide ore in Guangxi[J]. Multipurpose Utilization of Mineral Resources, 2020(5): 58-62. |
[3] | 代典, 梁欢, 何东升, 等. 湘西地区微细粒级难选菱锰矿浮选实验研究[J]. 矿产综合利用, 2020(4):76-81. DAI D, LIANG H, HE D S, et al. Experimental study on the flotation of a micro-grained refractory rhodochrosite in Western Hunan Area[J]. Multipurpose Utilization of Mineral Resources, 2020(4):76-81. doi: 10.3969/j.issn.1000-6532.2020.04.012 DAI D, LIANG H, HE D S, et al. Experimental study on the flotation of a micro-grained refractory rhodochrosite in Western Hunan Area[J]. Multipurpose Utilization of Mineral Resources, 2020(4): 76-81. doi: 10.3969/j.issn.1000-6532.2020.04.012 |
[4] | Singh V, Chakraborty T, Tripathy S K. A review of low grade manganese ore upgradation processes[J]. Mineral Processing and Extractive Metallurgy Review, 2019, 41(6):417-438. |
[5] | 林平, 陈方正. 我国锰矿资源的需求态势和利用策略[J]. 中国市场, 2007(40):20-22. LIN P, CHEN F Z. Demand situation and utilization strategy of manganese ore resources in China[J]. China Market, 2007(40):20-22. doi: 10.3969/j.issn.1005-6432.2007.40.010 LIN P, CHEN F Z. Demand situation and utilization strategy of manganese ore resources in China[J]. China Market, 2007(40): 20-22. doi: 10.3969/j.issn.1005-6432.2007.40.010 |
[6] | 杨茂春, 肖东升, 敖江, 等. 某低品位氧化锰矿磁选实验研究[J]. 矿冶工程, 2020, 40(1):73-76. YANG M C, XIAO D S, AO J, et al. Magnetic separation of a low-grade manganese oxide ore[J]. Mining and Metallurgical Engineering, 2020, 40(1):73-76. doi: 10.3969/j.issn.0253-6099.2020.01.017 YANG M C, XIAO D S, AO J , et al. Magnetic separation of a low⁃grade manganese oxide ore[J]. Mining and Metallurgical Engineering, 2020, 40(1): 73-76. doi: 10.3969/j.issn.0253-6099.2020.01.017 |
[7] | 贾宝亮, 孙亚峰, 王小钊, 等. 陕西镇安某高磷混合型铁锰矿选矿实验研究[J]. 矿产综合利用, 2021(1):83-87. JIA B L, SUN Y F, WANG X Z, et al. Experimental study on beneficiation of a high phosphorus mixed ferromanganese ore in Zhenan, Shaanxi Province[J]. Multipurpose Utilization of Mineral Resources, 2021(1):83-87. doi: 10.3969/j.issn.1000-6532.2021.01.013 JIA B L, SUN Y F, WANG X Z, et al. Experimental study on beneficiation of a high phosphorus mixed ferromanganese ore in Zhenan, Shaanxi Province [J]. Multipurpose Utilization of Mineral Resources, 2021(1): 83-87. doi: 10.3969/j.issn.1000-6532.2021.01.013 |
[8] | 付金涛, 胡生操. 某难选高铁高磷锰矿石同步还原分离实验研究[J]. 矿产综合利用, 2021(3):158-164. FU J T, HU S C. Experimental study on a refractory low-grade ferromanganese ore[J]. Multipurpose Utilization of Mineral Resources, 2021(3):158-164. doi: 10.3969/j.issn.1000-6532.2021.03.025 FU J T, HU S C. Experimental study on a refractory low-grade ferromanganese ore [J]. Multipurpose Utilization of Mineral Resources, 2021(3): 158-164. doi: 10.3969/j.issn.1000-6532.2021.03.025 |
[9] | Elliott R, Barati M. A review of the beneficiation of low-grade manganese ores by magnetic separation[J]. Canadian Metallurgical Quarterly, 2020, 59(1):1-16. doi: 10.1080/00084433.2020.1711654 |
[10] | Yuan S, Zhou W T, Han Y X, et al. Separation of manganese and iron for low-grade ferromanganese ore via fluidization magnetization roasting and magnetic separation technology[J]. Minerals Engineering, 2020, 152:1-14. |
[11] | 郭腾博, 李少平, 黄超军, 等. 碳酸锰矿选矿工艺研究现状与进展[J]. 金属矿山, 2019(12):118-123. GUO T B, LI S P, HUANG C J, et al. Research status and development of beneficiation process of manganese carbonate ore[J]. Metal Mine, 2019(12):118-123. doi: 10.19614/j.cnki.jsks.201912022 GUO T B, LI S P, HUANG C J, et al. Research status and development of beneficiation process of manganese carbonate ore[J]. Metal Mine, 2019(12): 118-123. doi: 10.19614/j.cnki.jsks.201912022 |
[12] | 张周位, 陈文祥, 黄苑龄, 等. 贵州某低品位碳酸锰矿工艺矿物学及选矿实验研究[J]. 矿产综合利用, 2018(3):66-69. ZHANG Z W, CHEN W X, HUANG Y L, et al. Experimental study on process mineralogy and mineral processing of a low-grade manganese carbonate ore in Guizhou[J]. Multipurpose Utilization of Mineral Resources, 2018(3):66-69. doi: 10.3969/j.issn.1000-6532.2018.03.013 ZHANG Z W, CHEN W X, HUANG Y L, et al. Experimental study on process mineralogy and mineral processing of a low-grade manganese carbonate ore in Guizhou [J]. Multipurpose Utilization of Mineral Resources, 2018(3): 66-69. doi: 10.3969/j.issn.1000-6532.2018.03.013 |
[13] | 张风平, 徐本军. 我国氧化锰矿石选矿工艺研究现状[J]. 湿法冶金, 2014(2):79-81. ZHANG F P, XU B J. Research status of beneficiation of manganese oxide ores[J]. Hydrometallurgy of China, 2014(2):79-81. doi: 10.13355/j.cnki.sfyj.2014.02.01 ZHANG F P, XU B J. Research status of beneficiation of manganese oxide ores[J]. Hydrometallurgy of China, 2014(2): 79-81. doi: 10.13355/j.cnki.sfyj.2014.02.01 |
[14] | 黄斌, 李向益, 曾茂青, 等. 高碳酸盐型锰矿选矿试验[J]. 矿产综合利用, 2017(4):38-41. HUANG B, LI X Y, ZENG M Q, et al. Experimental research on benefication of high carbonate manganese ore[J]. Multipurpose Utilization of Mineral Resources, 2017(4):38-41. doi: 10.3969/j.issn.1000-6532.2017.04.008 HUANG B, LI X Y, ZENG M Q, et al. Experimental research on benefication of high carbonate manganese ore [J]. Multipurpose Utilization of Mineral Resources, 2017(4): 38-41. doi: 10.3969/j.issn.1000-6532.2017.04.008 |
[15] | Oladunni F O, Alabi O. Effect of sodium oleate concentration variations on froth flotation of manganese ore[J]. International Journal of Nonferrous Metallurgy, 2019(8):25-33. |
[16] | Sharath Kumar B. Influence of mineralogy on the dry magnetic separation of ferruginous manganese ore—a comparative study[J]. Minerals, 2021: 1-20 |
[17] | 戴思行, 王欠欠, 刘诚, 等. 淀粉类调整剂在矿物浮选中的研究进展[J]. 矿产综合利用, 2021(4):73-79. DAI S X, WANG Q Q, LIU C, et al. Research progress of starch-based regulators in mineral flotation[J]. Multipurpose Utilization of Mineral Resources, 2021(4):73-79. doi: 10.3969/j.issn.1000-6532.2021.04.011 DAI S X, WANG Q Q, LIU C, et al. Research progress of starch-based regulators in mineral flotation [J]. Multipurpose Utilization of Mineral Resources, 2021(4): 73-79. doi: 10.3969/j.issn.1000-6532.2021.04.011 |
[18] | 朱一民. 2020 年浮选药剂的进展[J]. 矿产综合利用, 2021(2):102-118. ZHU Y M. Development of flotation reagent in 2020[J]. Multipurpose Utilization of Mineral Resources, 2021(2):102-118. doi: 10.3969/j.issn.1000-6532.2021.02.019 ZHU Y M. Development of flotation reagent in 2020[J]. Multipurpose Utilization of Mineral Resources, 2021(2): 102-118. doi: 10.3969/j.issn.1000-6532.2021.02.019 |
[19] | 张萍萍, 田学达, 张小云, 等. 一种黑曲霉对高磷锰矿脱磷的研究[J]. 矿业研究与开发, 2006, 26(5):42-44. ZHANG P P, TIAN X D, ZHANG X Y, et al. Study on dephosphorization of phosphorus-rich manganese ore with an aspergillus niger[J]. Mining Research & Development, 2006, 26(5):42-44. doi: 10.3969/j.issn.1005-2763.2006.05.014 ZHANG P P, TIAN X D, ZHANG X Y, et al. Study on dephosphorization of phosphorus-rich manganese ore with an aspergillus niger[J]. Mining Research & Development, 2006, 26(5): 42-44. doi: 10.3969/j.issn.1005-2763.2006.05.014 |
XRD patterns of raw ore sample
EMPA testing energy spectrum
Manganese ore processing flow sheet
Effects of grinding fineness on the grade and recovery of magnetic separation concentrate
Effects of magnetic field intensities on the grade and recovery of magnetic separation concentrate
Magnetic separation-flotation flow sheet
Effect of starch dosages on the grade and recovery of flotation concentrate
Effect of dodecylamine dosages on the grade and recovery of flotation concentrate
Flowsheet of magnetic separation combined with reverse flotation