Citation: | Wang Wei, Liu Lin, Liu Hongzhao, Wang Hongliang, Cao Yaohua, Ma Chi. Selective Leaching Process of Waste Lithium Iron Phosphate Cathode Powder[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(5): 53-57. doi: 10.3969/j.issn.1000-6532.2023.05.010 |
This is an essay in the field of metallurgical engineering. Using waste lithium iron phosphate battery cathode powder as raw material, a study on lithium selective leaching with Na2S2O8 as oxidant and low concentration acetic acid as aleaching agent was carried out. The effects of Na2S2O8 addition, acetic acid concentration, leaching temperature, leaching liquid-solid ratio and leaching time on selective leaching of lithium were investigated. At the conditions of acetic acid concentration of 0.3 mol/L, Na2S2O8 addition of 1.1 times the theoretical amount, L/S ratio of 10 mL /g and room temperature leaching for 2 h, the leaching rates of lithium, iron and phosphorus were 98.05%, 4.49% and 2.46% respectively.
[1] | Castro F D, Vaccari M, Cutaia L. Valorization of resources from end-of-life lithium-ion batteries: A review[J]. Critical Reviews in Environmental Science and Technology, 2021, 1:1-44. |
[2] | 郑鸿帅. 废旧锂离子电池正极材料分离回收锂的研究[D]. 北京: 中国科学院大学, 2021. ZHENG H S. Study on separation and recovery of lithium from spent lithium-ion battery cathode materials[D]. Beijing: University of the Chinese Academy of Sciences, 2021. |
[3] | 李波, 张莉莉, 洪秋阳, 等. 废弃锂电池电极材料中有价金属的赋存状态[J]. 矿产综合利用, 2022(1):200-204. LI B, ZHANG L L, HONG Q Y, et al. Study on the occurrence state of valuable metals in waste lithium battery electrode material[J]. Multipurpose Utilization of Mineral Resources, 2022(1):200-204. LI B, ZHANG L L, HONG Q Y, et al. Study on the occurrence state of valuable metals in waste lithium battery electrode material[J]. Multipurpose Utilization of Mineral Resources, 2022 (1): 200-204. |
[4] | 杨芳, 吴正斌, 徐亚威, 等. 废旧动力磷酸铁锂电池资源化回收技术研究进展[J]. 有色金属(冶炼部分), 2017, 12(12):53-56. YANG F, WU Z B, XU Y W, et al. Progress of recycling of spent lithium iron phosphate batteries[J]. Nonferrous Metals (Extractive Metallurgy), 2017, 12(12):53-56. YANG F, WU Z B, XU Y W, et al. Progress of recycling of spent lithium iron phosphate batteries [J]. Nonferrous Metals (Extractive Metallurgy), 2017(12): 53-56. |
[5] | 郑莹, 刘禹, 董超, 等. 废旧磷酸铁锂电池回收研究进展[J]. 电源技术, 2014, 38(6):1172-1175. ZHENG Y, LIU Y, DONG C, et al. Research status of spent lithium iron phosphate battery recycling[J]. Chinese Journal of Power Sources, 2014, 38(6):1172-1175. ZHENG Y, LIU Y, DONG C, et al. Research status of spent lithium iron phosphate battery recycling[J]. Chinese Journal of Power Sources, 2014, 38(6): 1172-1175. |
[6] | 伍德佑, 刘志强, 饶帅, 等. 废旧磷酸铁锂电池正极材料回收利用技术的研究进展[J]. 有色金属(冶炼部分), 2020(10): 70-78. WU D Y, LIU Z Q, RAO S, et al. Research progress in recycling technology of cathode materialsfor spent lithium iron phosphate batteries [J]. Nonferrous Metals (Extractive Metallurgy), 2020(10): 70-78. |
[7] | ZHANG J L, HU J T, LIU Y B, et al. Sustainable and facile method for the selective recovery of lithium from cathode scrap of spent LiFePO4 batteries[J]. ACS Sustainable Chem. Eng. 2019, 7(6): 5626-5631. |
[8] | LI H Y, YE H, SUN M C, et al. Process for recycle of spent lithium iron phosphate battery via a selective leaching-precipitation method[J]. J. Cent. South Univ. 2020, 27: 3239−3248. |
[9] | YANG Y X, MENG X Q, CAO H B, et al. Selective recovery of lithium from spent lithium iron phosphate batteries: a sustainable process[J]. Green Chemistry, 2018, 20:3121-3133. doi: 10.1039/C7GC03376A |
[10] | 阿来拉姑, 张聪聪, 贺凯, 等. 机械化学活化对磷酸铁锂电池中锂选择性浸出特性的影响[J]. 环境工程学报, 2020, 41(11):3136-3146. ALAI L G, ZHANG C C, HE K, et al. Effect of mechanochemical activation on the selective leaching properties of lithium from LiFePO4 batteries[J]. Chinese Journal of Environmental Engineering, 2020, 41(11):3136-3146. ALAI L G, ZHANG C C, HE K, et al. Effect of mechanochemical activation on the selective leaching properties of lithium from LiFePO4 batteries [J]. Chinese Journal of Environmental Engineering, 2020, 41 (11): 3136-3146. |
[11] | 徐正震, 梁精龙, 李慧, 等. 废旧锂电池正极材料中有价金属的回收工艺研究进展[J]. 矿产综合利用, 2022(4):119-142. XU Z Z, LIANG J L, LI H, et al. Research progress of recovery process of valuable metals in cathode materials of waste lithium batteries[J]. Multipurpose Utilization of Mineral Resources, 2022(4):119-142. XU Z Z, LIANG J L, LI H, et al. Research progress of recovery process of valuable metals in cathode materials of waste lithium batteries[J]. Multipurpose Utilization of Mineral Resources, 2022(4): 119-142. |
XRD pattern of lithium iron phosphate cathode powder
Effect of sodium persulfate addition on leaching rate of lithium, iron and phosphorus
Effect of acetic acid addition on leaching rate of lithium, iron and phosphorus
Effect of leaching liquid solid ratio on leaching rate of lithium, iron and phosphorus
Effect of leaching time on leaching rate of lithium, iron and phosphorus
Effect of leaching temperature on leaching rate of lithium, iron and phosphorus