Citation: | Mei Yajun, Li Xiaoyu, Li Chengxiu, Liu Xing. Re-election of Spodumene from Lithium Processing Tailings in Keeryin, Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(4): 83-87, 94. doi: 10.3969/j.issn.1000-6532.2023.04.013 |
This is an essay in the field of mineral processing engineering. In order to comprehensively evaluate the feasibility of spodumene beneficiation of certain lithium tailings in Sichuan, the mineralogy study of the lithium tailings beneficiation process and the test study of the whole beneficiation process were carried out. Through MLA/AMICS automatic mineral analysis, LA-ICP-MS laser ablation in-situ analysis and other technical means, the mineral composition of the tailings sample and the occurrence state of lithium in the sample were found; On the basis of a series of exploratory tests, the lithium separation process of "grinding-desliming-floating" was determined. For the lithium tailings with a Li2O grade of 0.51%, the high-efficient spodumene collector EM-PN10 is used to obtain a flotation spodumene concentrate with a Li2O grade of 4.32% and a Li2O recovery of 60.23% through a closed flotation process of one roughing, one sweeping and four finishing. After the flotation lithium concentrate is subjected to high-intensity magnetic separation, a spodumene concentrate with a Li2O grade of 5.07% and a recovery of 59.21% (relative to the raw ore) is finally obtained. The recovery and utilization index of spodumene determined by the test can provide certain technical support for the utilization of this kind of spodumene tailings.
[1] | JI Z Y, JIAO P P, YUAN J S, et al. The exploitation and utilization of lithium resources and its development[J]. Light Metals, 2013(5):1-5. |
[2] | LEE J H. Novel state-of-charge estimation method for lithium polymer batteries using electrochemical impedance spectroscopy[J]. Journal of Power Electronics, 2011(2):237-243. |
[3] | 吴西顺, 孙艳, 王登红, 等. 国际锂矿开发技术现状、革新及展望[J]. 矿产综合利用, 2020(6):110-120. WU X S, SUN Y, WANG D H, et al. International lithium mine utilization technology: current status, innovation and prospects[J]. Multipurpose Utilization of Mineral Resources, 2020(6):110-120. doi: 10.3969/j.issn.1000-6532.2020.06.019 WU X S, SUN Y, WANG D H, et al. International lithium mine utilization technology: current status, innovation and prospects[J]. Multipurpose Utilization of Mineral Resources, 2020(6): 110-120. doi: 10.3969/j.issn.1000-6532.2020.06.019 |
[4] | 吴西顺, 王登红, 杨添天, 等. 碳中和目标下的锂矿产业创新及颠覆性技术[J]. 矿产综合利用, 2022(2):1-8. WU X S, WANG D H, YANG T T, et al. Lithium mining industry innovation and disruptive technology under the goal of carbon neutrality[J]. Multipurpose Utilization of Mineral Resources, 2022(2):1-8. doi: 10.3969/j.issn.1000-6532.2022.02.001 WU X S, WANG D H, YANG T T, et al. Lithium mining industry innovation and disruptive technology under the goal of carbon neutrality[J]. Multipurpose Utilization of Mineral Resources, 2022 (2): 1-8. doi: 10.3969/j.issn.1000-6532.2022.02.001 |
[5] | 伊新辉. 锂辉石低温浮选试验研究[J]. 中国矿山工程, 2011(6):20-22. YIN X H. Experimental study on spodumene flotation at low temperature[J]. China Mining Engineering, 2011(6):20-22. doi: 10.3969/j.issn.1672-609X.2011.06.007 YIN X H. Experimental study on spodumene flotation at low temperature [J]. China Mining Engineering, 2011(6): 20-22. doi: 10.3969/j.issn.1672-609X.2011.06.007 |
[6] | 李新冬, 黄万抚, 文金磊, 等. 锂辉石矿的工艺矿物学与选矿工艺研究[J]. 硅酸盐通报, 2014, 33(5):1207-1213. LI X D, HUANG W F, WEN J L, et al. Study on process mineralogy and mineral processing technology of spodumene ore in China Mining Engineering[J]. Bulletin of The Chinese Ceramic Society, 2014, 33(5):1207-1213. doi: 10.16552/j.cnki.issn1001-1625.2014.05.039 LI X D, HUANG W F, WEN J L, et al. Study on process mineralogy and mineral processing technology of spodumene ore in China Mining Engineering [J]. Bulletin of The Chinese Ceramic Society, 2014(5): 1207-1213. doi: 10.16552/j.cnki.issn1001-1625.2014.05.039 |
[7] | 朱一民, 周菁. 2018年浮选药剂的进展[J]. 矿产综合利用, 2019(4):1-10. ZHU Y M, ZHOU J. The development of flotation reagent in 2018[J]. Multipurpose Utilization of Mineral Resources, 2019(4):1-10. doi: 10.3969/j.issn.1000-6532.2019.04.001 ZHU Y M, ZHOU J. The development of flotation reagent in 2018[J]. Multipurpose Utilization of Mineral Resources, 2019(4): 1-10. doi: 10.3969/j.issn.1000-6532.2019.04.001 |
[8] | 李成秀, 程仁举, 刘星. 我国锂辉石选矿技术研究现状及展望[J]. 矿产综合利用, 2021(5):1-8. LI C X, CHENG R J, LIU X. Research status and prospects of spodumene ore beneficiation technology in China[J]. Multipurpose Utilization of Mineral Resources, 2021(5):1-8. doi: 10.3969/j.issn.1000-6532.2021.05.001 LI C X, CHENG R J, LIU X. Research status and prospects of spodumene ore beneficiation technology in China[J]. Multipurpose Utilization of Mineral Resources, 2021(5): 1-8. doi: 10.3969/j.issn.1000-6532.2021.05.001 |
[9] | 赖杨, 田恩源, 龚大兴, 等. 川西斯跃武锂-铌-钽稀有金属矿集区自然重砂异常特征及其找矿潜力[J]. 矿产综合利用, 2019(3):65-70. LAI Y, TIAN E Y, GONG D X, et al. Natural heavy mineral anomaly characteristics and ore potential analysis of the Siyuewu Li-Nb-Ta rare metals ore-concentrated area in western Sichuan Province[J]. Multipurpose Utilization of Mineral Resources, 2019(3):65-70. doi: 10.3969/j.issn.1000-6532.2019.03.015 LAI Y, TIAN E Y, GONG D X, et al. Natural heavy mineral anomaly characteristics and ore potential analysis of the Siyuewu Li-Nb-Ta rare metals ore-concentrated area in western Sichuan province [J]. Multipurpose Utilization of Mineral Resources, 2019(3): 65-70. doi: 10.3969/j.issn.1000-6532.2019.03.015 |
[10] | 陈超, 张裕书, 张少翔, 等. 川西九龙地区低品位锂辉石浮选实验研究[J]. 矿产综合利用, 2019(4):55-58. CHEN C, ZHANG Y S, ZHANG S X, et al. Flotation test of low-grade spodumene in the Jiulong area of West Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2019(4):55-58. doi: 10.3969/j.issn.1000-6532.2019.04.011 CHEN C , ZHANG Y S, ZHANG S X, et al. Flotation test of low-grade spodumene in the Jiulong area of West Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2019(4): 55-58. doi: 10.3969/j.issn.1000-6532.2019.04.011 |
Flowsheet of open-circuit flotation test
Flowsheet of closed-circuit flotation
Flowsheet of high intensity magnetic separation test