Current Status and Development Trend of Vanadium Extraction by P204 Extraction

Hu Yujie; Ye Guohua; Tang Yue; Tao Yuanyuan

doi:10.3969/j.issn.1000-6532.2023.03.011

2023 No. 3

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Article navigation > Multipurpose Utilization of Mineral Resources > 2023 > 44(3): 63-69, 77

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Hu Yujie, Ye Guohua, Tang Yue, Tao Yuanyuan. Current Status and Development Trend of Vanadium Extraction by P204 Extraction[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(3): 63-69, 77. doi: 10.3969/j.issn.1000-6532.2023.03.011

Citation:

Hu Yujie, Ye Guohua, Tang Yue, Tao Yuanyuan. Current Status and Development Trend of Vanadium Extraction by P204 Extraction[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(3): 63-69, 77. doi: 10.3969/j.issn.1000-6532.2023.03.011

Current Status and Development Trend of Vanadium Extraction by P204 Extraction

Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming, Yunnan, China

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Corresponding author: Ye Guohua, ghye581@163.com

Received Date: 06 April 2020

Publish Date: 25 June 2023

Abstract

Abstract

This is a paper in the field of metallurgical engineering. Organophosphorus class extractant D2EHPA (P204) is very widely used in vanadium extraction. Firstly, the form of vanadium present in the leach solution affects the effect of extraction, V(IV) is mainly stable in solution in the form of VO²⁺ in a strongly acidic solution; when the pH value gradually increases, V(V) mostly exists in the form of H₂V₁₀O₂₈ ^4- and HV₁₀O₂₈ ^5-. Secondly, based on the research of organophosphorus extractant P204 in recent years, this paper analyzes the conformational relationship of organophosphorus extractant P204 and finds that the spatial site resistance effect is equally important as a secondary factor compared with the type of phosphoryl adjacent groups, based on the hydrogen bonding effect, the extractant molecules will produce dimers or even multimers between them, thus changing the structure and properties of the extractant molecules. Finally, the progress of the development and application of P204 extractive vanadium and the outlook on the future of the related fields are presented, pointing out the future research directions of P204 extractive agents.
- Metallurgical engineering /
- Vanadium extraction /
- P204 /
- Solvent extraction /
- Applications and advances

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References

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