Citation: | Li Na, Qin Yufang, Jin Hailong, Wang Qiwei. Occurrence of Rare Earth, Iron, Phosphorus and Calcium in High Grade Rare Earth Concentrate[J]. Multipurpose Utilization of Mineral Resources, 2022, 43(6): 193-200. doi: 10.3969/j.issn.1000-6532.2022.06.033 |
Rare earth grade of Bayan Obo mixed rare earth concentrate is 65.86%, and the contents of P2O5, CaO and TFe are 11.26%, 3.89% and 1.34%, respectively. Chemical analysis, automatic mineral analysis system, SEM and EDS were used to study the occurrence of rare earth and impurity elements in mixed rare earth concentrate. The results show that rare earth mainly exists in bastnaesite, monazite, parisite and huanghoite in the form of independent minerals, iron mainly exists in magnetite hematite and pyrite, phosphorus mainly exists in monazite and apatite, calcium mainly exists in fluorite, apatite, dolomite and calcite, which can provides mineralogical basis for further separation of bastnaesite and monazite concentrate and reduction of impurity elements in rare earth concentrate.
[1] | Tian L, Chang H Q, Tang P, et al. Rare earth elements occurrence and economical recovery strategy from shale gas wastewater in the Sichuan Basin, China[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(32):11914-11920. |
[2] | 张博, 宁阳坤, 曹飞, 等. 世界稀土资源现状[J]. 矿产综合利用, 2018(4):7-12. doi: 10.3969/j.issn.1000-6532.2018.04.002 ZHANG B, NING Y K, CAO F, et al. Current situation of worldwide rare earth resources[J]. Multipurpose Utilization of Mineral Resources, 2018(4):7-12. doi: 10.3969/j.issn.1000-6532.2018.04.002 |
[3] | Chen W X, Zhou F, Wang H Q, et al. The occurrence states of rare earth elements bearing phosphorite ores and rare earth enrichment through the selective reverse flotation[J]. 2019, 9(11): 698-707. |
[4] | 王建英, 文登学, 贾艳. 白云鄂博稀选尾矿中铌的回收试验[J]. 矿产综合利用, 2019(3):121-126. doi: 10.3969/j.issn.1000-6532.2019.03.027 WANG J Y, WEN D X, JIA Y. Experiment on recovery of niobium in the tailings of Bayan Obo[J]. Multipurpose Utilization of Mineral Resources, 2019(3):121-126. doi: 10.3969/j.issn.1000-6532.2019.03.027 |
[5] | Li J F, Li M, Zhang D L, et al. Clean production technology of Baiyun Obo rare earth concentrate decomposed by Al(OH)3-NaOH[J]. Chemical Engineering Journal, 2020:382. |
[6] | 金海龙, 李娜, 魏威, 等. 白云鄂博混合原矿中有害元素的赋存状态研究[J]. 矿产综合利用, 2020(6):201-205. JIN H L, LI N, WEI W, et al. Study on the occurrence state of harmful elements in the Bayan Obo mixed raw ore[J]. Multipurpose Utilization of Mineral Resources, 2020(6):201-205. |
[7] | 洪秋阳, 梁冬云, 李波, 等. 某复杂铌稀土矿石工艺矿物性质及可选性分析[J]. 矿产综合利用, 2021(1):171-178. doi: 10.3969/j.issn.1000-6532.2021.01.029 HONG Q Y, LIANG D Y, LI B, et al. Process mineralogy characteristics of a complex niobium-rare earth ore and implications for mineral processing[J]. Multipurpose Utilization of Mineral Resources, 2021(1):171-178. doi: 10.3969/j.issn.1000-6532.2021.01.029 |
[8] | 宋常青. 氟碳铈矿与独居石矿浮选分离的研究[J]. 有色金属(选矿部分), 1993(4):5-8. SONG C Q. Study on flotation separation of bastnaesite and monazite[J]. Nonferrous metals (mineral processing), 1993(4):5-8. |
[9] | 朱智慧. 氟碳铈矿与独居石浮选分离及机理研究[D]. 包头: 内蒙古科技大学, 2019. ZHU Z H. Study on flotation separation and mechanism of bastnaesite and monazite [D]. Baotou: Inner Mongolia University of science and technology, 2019. |
[10] | 朱智慧, 杨占峰, 王其伟, 等. 白云鄂博稀土精矿工艺矿物学研究[J]. 有色金属(选矿部分), 2019(6):1-4+22. ZHU Z H, YANG Z F, WANG Q W, et al. Study on technological mineralogy of rare earth concentrate in Bayan Obo[J]. Nonferrous Metals (Mineral Processing Section), 2019(6):1-4+22. |
XRD analysis of the sample
Energy spectrum analysis diagram of sample
Characteristics of rare earth minerals association in rare earth concentrate
Relationship between rare earth grade and impurity element content