Citation: | A Danchun, Xiao Xueying, Wen Jing, Dong Jinmei, Zheng Weixin, Chang Chenggong. Study on the Technology of Preparing Active MgO and MOC from Magnesium Hydroxide[J]. Multipurpose Utilization of Mineral Resources, 2022, 43(3): 17-26, 57. doi: 10.3969/j.issn.1000-6532.2022.03.004 |
The salt lakes in Qaidam area are rich in magnesium resources. Along with the development and utilization of lithium and potassium resources a large amount of magnesium-rich by-products will be produced as by-products. In order to improve the utilization rate of magnesium resources, this article uses Mg (OH)2 prepared from calcium carbide slag and MgCl2 as raw materials to study the effect of the calcination process on the particle size, specific surface area, reactive MgO content and setting time of the calcined product. MOC specimens were prepared from the calcined products. The effects of calcining temperature and raw material ratio on the MOC specimens were studied. The results of the study show that the specific surface area of the calcined product decreases gradually with the increase of the calcination temperature and the extension of the holding time, and the particle size tends to decrease first and then increase. With the increase of calcination temperature and the extension of holding time, the reactive MgO content in the calcined product and the setting time of the calcined product increases gradually. When the calcination temperature of the raw material is 600℃, the molar ratio of reactive MgO to MgCl2 is 6, and the Baume degree of the MgCl2 solution is 27, the compressive strength of the MOC specimen is high, and the compressive strength gradually increases with age.
[1] | Yunsong J. Study of the new type of light magnesium cement foamed material[J]. Mater Lett, 2001, 50(1):28-31. doi: 10.1016/S0167-577X(00)00407-9 |
[2] | Misra A, Mathur R. Magnesium oxychloride cement concrete[J]. Bull Mater, 2007, 30(3):239-246. doi: 10.1007/s12034-007-0043-4 |
[3] | Xu B W, Ma H Y, Hu C L, et al. Influence of cenospheres on properties of magnesium oxychloride cement-base composites[J]. Mater Struct, 2016, 49(4):1319-1326. doi: 10.1617/s11527-015-0578-6 |
[4] | 张骋, 张展鹏, 张荣娟, 等. 高致密氧化镁陶瓷制备工艺优化[J]. 稀有金属材料与工程, 2011, 40(S1):227-230. ZHANG P, ZHANG Z P, ZHANG R J, et al. Preparation process optimization of high-density magnesia ceramics[J]. Rare Metal Materials and Engineering, 2011, 40(S1):227-230. |
[5] | Qianqian Ye, Yufei Han, Shifeng Zhang, et al. Bioinspired and biomineralized magnesium oxychloride cement with enhanced compressive strength and water resistance[J]. Journal of Hazardous Materials. 2020. |
[6] | 王兆敏. 中国菱镁矿现状与发展趋势[J]. 中国非金属矿工业导刊, 2006(5):6-8+23. doi: 10.3969/j.issn.1007-9386.2006.05.002 WANG Z M. Present situation and development trend of magnesite in China[J]. China Nonmetallic Mineral Industry Guide, 2006(5):6-8+23. doi: 10.3969/j.issn.1007-9386.2006.05.002 |
[7] | 董金美, 余红发, 张立明. 水合法测定活性MgO含量的试验条件研究[J]. 盐湖研究, 2010, 18(1):38-41. DONG J M, YU H F, ZHANG L M. Study on the experimental conditions for the determination of active MgO content by water method[J]. Salt Lake Research, 2010, 18(1):38-41. |
[8] | 张旭, 冯雅静, 王志, 等. 氢氧化钠制备氢氧化镁阻燃热解特性研究[J]. 消防科学与技术, 2018, 37(3):379-380+413. doi: 10.3969/j.issn.1009-0029.2018.03.029 ZHANG X, FENG Y J, WANG Z, et al. Study on flame retardant pyrolysis characteristics of magnesium hydroxide prepared from sodium hydroxide[J]. Fire Science and Technology, 2018, 37(3):379-380+413. doi: 10.3969/j.issn.1009-0029.2018.03.029 |
[9] | 李维翰, 尚红霞, 李盛栋. 轻烧氧化镁粉活性的研究[J]. 武汉钢铁学院学报, 1992(1):30-37. LI W H, SHANG H X, LI S D. Study on activity of light-fired magnesium oxide powder[J]. Journal of Wuhan Iron and Steel Institute, 1992(1):30-37. |
[10] | 刘涛, 马鹏程, 于景坤, 等. 氢氧化镁热分解法制备活性氧化镁(英文)[J]. 硅酸盐学报, 2010(7):193-196. LIU T, MA P C, YU J K, et al. Preparation of active magnesium oxide by thermal decomposition of magnesium hydroxide[J]. Journal of the Chinese Ceramic Society, 2010(7):193-196. |
[11] | 崔鑫, 邓敏. 煅烧制度对MgO活性的影响[J]. 南京工业大学学报(自然科学版), 2008, 30(4):52-55. CUI X, DENG M. Effect of calcination system on MgO activity[J]. Journal of Nanjing University of Technology (Natural Science Edition), 2008, 30(4):52-55. |
[12] | Abdel-Gawwad HA, Khalil KA. Preparation and characterization of one-part magnesium oxychloride cement[J]. Construction and Building Materials, 2018, 189(20):745-750. |
Effect of calcining process on MgO specific surface area
Effect of calcining temperature on particle size
Effect of holding time on particle size
Effect of holding time on activity MgO
Effect of holding temperature and time on setting time
Compressive strength of MOC specimens prepared from different calcined products
XRD patterns of 28 day age of MOC specimens prepared from different calcinations
SEM morphology of 28 day age of MOC specimens prepared from different calcinations
Compressive strength of MOC specimens prepared from different MgO and MgCl2 molar ratios
XRD patterns of 28 day age of MOC specimens prepared from different molar ratios between MgO and MgCl2
SEM morphology of 28 day age of MOC specimens prepared from different molar ratios between MgO and MgCl2
Comparison of the compressive strength of MOC specimens prepared from MgCl2 solution with different baume degrees
XRD patterns of 28 day age of MOC specimens prepared from MgCl2 solution with different baume degrees
SEM morphology of 28 day age of MOC specimens prepared from MgCl2 solution with different baume degrees