Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2022 No. 1
Article Contents

Zhang Wen, Tian Chengtao, Weng Xiaoqing, Li Hongqiang, He Dongsheng, Luo Huihua. Research on the Process Mineralogy of Phosphogypsum Using Mineral Liberation Analysis System[J]. Multipurpose Utilization of Mineral Resources, 2022, (1): 205-210. doi: 10.3969/j.issn.1000-6532.2022.01.030
Citation: Zhang Wen, Tian Chengtao, Weng Xiaoqing, Li Hongqiang, He Dongsheng, Luo Huihua. Research on the Process Mineralogy of Phosphogypsum Using Mineral Liberation Analysis System[J]. Multipurpose Utilization of Mineral Resources, 2022, (1): 205-210. doi: 10.3969/j.issn.1000-6532.2022.01.030

Research on the Process Mineralogy of Phosphogypsum Using Mineral Liberation Analysis System

More Information
  • Corresponding author: Li Hongqiang  
  • For the first time, process mineralogy including the chemical composition, mineral composition, main mineral particle morphology and embedded features, mineral dissociation analysis, and the occurrence status of harmful elements of an industrial phosphogypsum from Hubei provence was conducted using the mineral liberation analysis (MLA). The results provides a theoretical basis for the purification of phosphogypsum and impurity removal. It shows that the industrial phosphogypsum is mainly consist of oxygen, calcium, sulfur, and silicon. To improve the whiteness of the phosphogypsum, the coloring impurities elementsincluding iron, titaniumneed to be removed. The mineral composition of this phosphogypsum is relatively simple, and the content of gypsum mineral meets the standard of first-level phosphogypsum (≥85%) in GB/T 23456-2009 "Phosphogypsum", followed by a small amount of quartz, potassium feldspar, chlorite, iron-containing aluminosilicate, limonite and pyrite, etc. The impurity phosphorus in the phosphogypsum is mainly distributed in apatite and phosphorus pentoxide, and deep dephosphorization process requires water washing combined with pickling.

  • 加载中
  • [1] 赵红涛, 包炜军, 孙振华, 等. 磷石膏中杂质深度脱除技术[J]. 化工进展, 2017, 36(4):1240-1246.

    Google Scholar

    ZHAO H T, BAO W J, SUN Z H, et al. Removal of impurities from phosphogypsum[J]. Progress in Chemical Industry, 2017, 36(4):1240-1246.

    Google Scholar

    [2] 叶学东. 2018年我国磷石膏利用现状、问题及建议[J]. 磷肥与复肥, 2019, 34(7):1-4. doi: 10.3969/j.issn.1007-6220.2019.07.002

    CrossRef Google Scholar

    YE X D. Current situation, problems and suggestions of phosphogypsum utilization in China in 2018[J]. Phosphate Fertilizer & Compound Fertilizer, 2019, 34(7):1-4. doi: 10.3969/j.issn.1007-6220.2019.07.002

    CrossRef Google Scholar

    [3] 王圳, 张均, 陈芳, 等. 贵州省磷矿固体废弃物治理现状与建议[J]. 矿产综合利用, 2019(1):11-15. doi: 10.3969/j.issn.1000-6532.2019.01.003

    CrossRef Google Scholar

    WANG Z, ZHANG J, CHEN F, et al. Present situation and suggestion of management of phosphate rock solid waste[J]. Multipurpose Utilization of Mineral Resources, 2019(1):11-15. doi: 10.3969/j.issn.1000-6532.2019.01.003

    CrossRef Google Scholar

    [4] 唐湘平, 李超, 黄云阶, 等. 四川某地磷石膏开发利用试验研究[J]. 矿产综合利用, 2019(5):28-31. doi: 10.3969/j.issn.1000-6532.2019.05.006

    CrossRef Google Scholar

    TANG X P, LI C, HUANG Y J, et al. Experimental study on development and utilization of phosphogypsum in Sichuan[J]. Multipurpose Utilization of Mineral Resources, 2019(5):28-31. doi: 10.3969/j.issn.1000-6532.2019.05.006

    CrossRef Google Scholar

    [5] 张浩, 李辉. 用磷石膏制备贝利特-硫铝酸盐水泥[J]. 硅酸盐通报, 2014, 33(6):1567-1571.

    Google Scholar

    ZHANG H, LI H. Preparation of belite - sulphoaluminate cement by phosphogypsum[J]. Chinese Journal of Ceramics, 2014, 33(6):1567-1571.

    Google Scholar

    [6] 朱志伟, 何东升, 陈飞, 等. 磷石膏预处理与综合利用研究进展[J]. 矿产保护与利用, 2019, 39(4):19-25.

    Google Scholar

    ZHU Z W, HE D S, CHEN F, et al. Research progress on pretreatment and comprehensive utilization of phosphogypsum[J]. Conservation and Utilization of Mineral Resources, 2019, 39(4):19-25.

    Google Scholar

    [7] 杨斌. 水热法处理磷石膏过程研究[D]. 昆明: 昆明理工大学, 2006.

    Google Scholar

    YANG B. Study on the process of hydrothermal treatment of phosphogypsum [D]. Kunming: Kunming University of Science and Technology, 2006.

    Google Scholar

    [8] 白有仙. 磷石膏组成及脱磷脱硫方法的研究[D]. 贵阳: 贵州大学, 2009.

    Google Scholar

    BAI Y X. Study on the composition of phosphogypsum and the method of dephosphorization and desulfurization [D]. Guiyang: Guizhou University, 2009.

    Google Scholar

    [9] 陈嘉懿. 预处理工艺对磷石膏性能的影响及作用机理研究[D]. 武汉: 武汉理工大学, 2012.

    Google Scholar

    CHEN J Y. Study on the effect of pretreatment process on the properties of phosphogypsum and the mechanism of action [D]. Wuhan: Wuhan University of Technology, 2012.

    Google Scholar

    [10] 庞建涛, 肖喆, 王灿霞, 周建一. MLA系统在磷块岩工艺矿物学研究中的应用[J]. 化工矿物与加工, 2015, 44(10):19-21.

    Google Scholar

    PANG J T, XIAO Z, WANG C X, et al. Application of MLA system in process mineralogy research of phosphorite block[J]. Chemical Minerals and Processing, 2015, 44(10):19-21.

    Google Scholar

    [11] 苏庆东, 刘会忠, 刘会友, 等. NY/T1060-2006《水泥生产用磷石膏》[S]. 北京: 中国农业出版社, 2006.

    Google Scholar

    SU Q D, LIU H Z, LIU H Y, et al. NY/T1060-2006 Phosphogypsum for cement production [S]. Beijing: China Agriculture Press, 2006.

    Google Scholar

    [12] 郑建国, 王德伦, 袁运法, 等. GB/T 23456-2009《磷石膏》[S]. 北京: 中国标准出版社, 2010.

    Google Scholar

    ZHENG J G, WANG D L, YUAN Y F, et al. GB/T 23456-2009 Phosphogypsum [S]. Beijing: Standards Press of China, 2010.

    Google Scholar

    [13] 张欢. 磷石膏的质量影响因素及质量评价指标体系研究[D]. 重庆: 重庆大学, 2013.

    Google Scholar

    ZHANG H. Study on quality influencing factors and quality evaluation index system of phosphogypsum [D]. Chongqing: Chongqing University, 2013.

    Google Scholar

    [14] 胡敏, 彭丽, 郭娜, 等. 磷石膏- 炭化污泥胶凝材料力学性能试验研究[J]. 矿产综合利用, 2020(4):196-201. doi: 10.3969/j.issn.1000-6532.2020.04.034

    CrossRef Google Scholar

    HU M, PENG L, GUO N, et al. Study on mechanical properties of phosphogypsum-carbonized sludge composite cementitious materials[J]. Multipurpose Utilization of Mineral Resources, 2020(4):196-201. doi: 10.3969/j.issn.1000-6532.2020.04.034

    CrossRef Google Scholar

    [15] 李美. 磷石膏品质的影响因素及其建材资源化研究[D]. 重庆: 重庆大学, 2012.

    Google Scholar

    LI M. Study on the influencing factors of phosphogypsum quality and the resource utilization of building materials [D]. Chongqing: Chongqing University, 2012.

    Google Scholar

    [16] Ölmez H, Yilmaz V T. Infrared study on the refinement of phosphogypsum for cements[J]. Cement and Concrete Research, 1988, 18(3):449-454. doi: 10.1016/0008-8846(88)90079-8

    CrossRef Google Scholar

    [17] 彭家惠, 万体智, 汤玲, 等. 磷石膏中有机物、共晶磷及其对性能的影响[J]. 建筑材料学报, 2003, 6(3):221-226. doi: 10.3969/j.issn.1007-9629.2003.03.001

    CrossRef Google Scholar

    PENG J H, WAN T Z, TANG L, et al. Organic matter and eutectic phosphorus in phosphogypsum and their effects on properties[J]. Journal of Building Materials, 2003, 6(3):221-226. doi: 10.3969/j.issn.1007-9629.2003.03.001

    CrossRef Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(4)

Tables(7)

Article Metrics

Article views(1373) PDF downloads(572) Cited by(0)

Access History

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint