Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2022 No. 1
Article Contents

Cheng Junwei, Huang Mingqin, Cai Shenwen. Research on Removal of Chromium (VI) from Waste water on Fly Ash Modified with Alkali Washing and Calcium Oxide Calcining Method[J]. Multipurpose Utilization of Mineral Resources, 2022, (1): 184-189, 199. doi: 10.3969/j.issn.1000-6532.2022.01.026
Citation: Cheng Junwei, Huang Mingqin, Cai Shenwen. Research on Removal of Chromium (VI) from Waste water on Fly Ash Modified with Alkali Washing and Calcium Oxide Calcining Method[J]. Multipurpose Utilization of Mineral Resources, 2022, (1): 184-189, 199. doi: 10.3969/j.issn.1000-6532.2022.01.026

Research on Removal of Chromium (VI) from Waste water on Fly Ash Modified with Alkali Washing and Calcium Oxide Calcining Method

  • Fly ash was modified by the alkali washing and calcium oxide calcining method The infrared spectrometer and scanning electron microscopy were used to characterize the bond groups and morphology before and after modification fly ash. The dosage, pH, calcined temperature and adsorption time were used as variable factors to adsorb Cr (VI)-containing waste water. The results showed that the removal rate of Cr(VI) can reach 96.38% under modified fly ash dosage at 6 g/L, initial pH value at 8, secondary calcination temperature at 800℃ and the ratio with calcium oxide at 3∶1. The adsorption capacity reached 16.06 mg/g. The kinetic fitting process shows that the adsorption of Cr (VI) by the modified fly ash conformed to the pseudo-second-order kinetic equation. This process was dominated by chemical adsorption and continuous.

  • 加载中
  • [1] Miretzky P, Cirelli A F. Cr(VI) and Cr(III) removal from aqueous solution by raw and modified lignocellulosic materials: a review[J]. Journal of Hazardous Materials, 2010, 180(1):1-19.

    Google Scholar

    [2] Leyva-ramos R, Jacobo-azuara A. Adsorption of chromium(VI) from an aqueous solution on a surfactant-modified zeolite[J]. Colloids & Surface A Physicochemical & Engineering Aspcets, 2008, 330(1):35-41.

    Google Scholar

    [3] 孙霞, 吴益梅, 王琪瑶. 碱溶粉煤灰对废水中六价铬的吸附试验研究[J]. 煤炭科学技术, 2010, 38(10):124-128.

    Google Scholar

    SUN X, WU Y M, WANG Q Y. Adsorption of hexavalent chromium from wastewater by alkali-dissolved fly ash[J]. Coal Science and Technology, 2010, 38(10):124-128.

    Google Scholar

    [4] 范力, 张建强, 程新, 等. 离子交换法及吸附法处理含铬废水的研究进展[J]. 水处理技术, 2009, 35(1):30-33.

    Google Scholar

    FAN L, ZHANG J Q, CHEN X, et al. Research progress in the treatment of chromium containing wastewater by ion exchange and adsorption[J]. Water Treatment Technology, 2009, 35(1):30-33.

    Google Scholar

    [5] Cheng Lang, Liu Hong, Wang Xi, et al. Preparation of CTMAB/attapulgite particles and their adsorption Cr(VI) performance[J]. Environmental science and technology, 2017, 40(10):77-81.

    Google Scholar

    [6] 欧阳平, 范洪勇. 粉煤灰吸附剂的研究现状[J]. 材料导报, 2013, 27(13):54-57.

    Google Scholar

    OU Y P, FAN H Y. Preparation and characterization of a novel adsorbent for coal fly ash[J]. Journal of Hazardous Materials, 2013, 27(13):54-57.

    Google Scholar

    [7] Blissett R S, Rowson N A. A review of the multi-component utilisation of coal fly ash[J]. Fuel, 2012, 97:1-23. doi: 10.1016/j.fuel.2012.03.024

    CrossRef Google Scholar

    [8] Deng Xin, Qi Liqiang, Zhang Yajuan. Experimental study on adsorption of hexavalent chromium with microwave-assisted alkali modified fly ash[J]. Water, Air and Soil Pollution, 2018, 229:18-23. doi: 10.1007/s11270-017-3679-8

    CrossRef Google Scholar

    [9] Li Beigang, Yin Haiyang. Preparation, characterization and adsorption application of cerium(III)/fly ash composite materials[J]. Journal of Agro-Environment Science, 2018, 37(9):2005-2013.

    Google Scholar

    [10] Xiyili H, Çetintaş S, Bingöl D. Removal of some heavy metals onto mechanically activated fly ash: Modeling approach for optimization, isotherms, kinetics and thermodynamics[J]. Process Safety and Environmental Protection, 2017, 109:288-300. doi: 10.1016/j.psep.2017.04.012

    CrossRef Google Scholar

    [11] 许效天, 霍林, 左叶颖, 等. 铝改性粉煤灰漂珠吸附水溶液中砷的性能研究[J]. 中国环境科学, 2011, 31(8):1300-1305.

    Google Scholar

    XU X T, HUO L, ZUO Y Y, et al. Removal of arsenic from aqueous solution by aluminum modified fly ash bleaching beads[J]. China Environmental Science, 2011, 31(8):1300-1305.

    Google Scholar

    [12] 柯昌君, 江盼, 吴维舟. 粉煤灰蒸压活性的红外光谱研究[J]. 武汉理工大学学报, 2009, 31(7):35-39. doi: 10.3963/j.issn.1671-4431.2009.07.010

    CrossRef Google Scholar

    KE C J, JIANG P, WEI W Z, et al. A study on the autoclaved activity of fly ash by infrared spectroscopy[J]. Journal of Wuhan University of Technology, 2009, 31(7):35-39. doi: 10.3963/j.issn.1671-4431.2009.07.010

    CrossRef Google Scholar

    [13] 曾丽, 白露, 向莹, 等. 碱性粉煤灰对废水中铬离子吸附性能的研究[J]. 成都大学学报(自然科学版), 2019, 38(2):210-213.

    Google Scholar

    ZENG L, BAI L, XIANG Y, et al. Removal of chromium ions from wastewater by coal fly ash[J]. Journal of Chengdu University (Natural Science Edition), 2019, 38(2):210-213.

    Google Scholar

    [14] 章晓彤, 李芳芹, 任建兴, 等. 钙基吸附剂的改性[J]. 上海电力学院学报, 2018, 34(4):391-394.

    Google Scholar

    ZHANG X T, LI F Q, REN J X, et al. Adsorbents for the removal of calcium from aqueous solution[J]. Journal of Shanghai University of Electric Power, 2018, 34(4):391-394.

    Google Scholar

    [15] 徐洁, 陈海燕, 王旋. 碱改性粉煤灰处理含铬废水[J]. 矿产综合利用, 2016(6):68-71. doi: 10.3969/j.issn.1000-6532.2016.06.016

    CrossRef Google Scholar

    XU J, CHEN H Y, WANG X, et al. Treatment of chromium containing wastewater by alkali modified fly ash[J]. Multipurpose Utilization of Mineral Resources, 2016(6):68-71. doi: 10.3969/j.issn.1000-6532.2016.06.016

    CrossRef Google Scholar

    [16] 贺龙强, 付克明, 胡鹏. 改性粉煤灰处理废水中铬(VI)的研究[J]. 煤炭技术, 2018, 37(7):324-326.

    Google Scholar

    HE L Q, FU K M, HU P, et al. Removal of chromium (VI) from wastewater by modified fly ash[J]. Coal Technology, 2018, 37(7):324-326.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(7)

Tables(2)

Article Metrics

Article views(1814) PDF downloads(411) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint