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2023 Vol. 46, No. 3
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ZHANG Zhuo, LIU Futian, CHEN Sheming. 2023. Review on the application of H, O, Sr, Ca, Li and B isotopes in the research of high-fluoride groundwater. North China Geology, 46(3): 49-56. doi: 10.19948/j.12-1471/P.2023.03.07
Citation: ZHANG Zhuo, LIU Futian, CHEN Sheming. 2023. Review on the application of H, O, Sr, Ca, Li and B isotopes in the research of high-fluoride groundwater. North China Geology, 46(3): 49-56. doi: 10.19948/j.12-1471/P.2023.03.07
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Review on the application of H, O, Sr, Ca, Li and B isotopes in the research of high-fluoride groundwater

  • 1. Tianjin Center, China Geological Survey (North China Center for Geoscience Innovation ), Tianjin 300170, China;

  • 2. Tianjin Key Laboratory of Coast Geological Processes and Environmental Safety, Tianjin 300170, China

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  • Corresponding author: LIU Futian  
Received Date:  06 July 2023
    Abstract
  • This article aims to explore the use of stable isotopic techniques in elucidating the origin, cycling and evolution processes of high fluoride groundwater. By collecting and synthesizing relevant research findings, a comprehensive review is conducted concerning the utilization of hydrogen and oxygen isotopes, strontiumcalcium isotopes, and lithium-boron isotopes in the investigation of high F- groundwater within subterranean environments.The research reveals that δ2H and δ18O values in groundwater can be utilized to identify the sources and mixing processes of water, thereby identifying potential sources of high fluoride groundwater. Of particular interest in the investigation of high fluoride groundwater is the use of strontium-calcium isotopes.By determining the 87Sr /86Sr ratio and δ44/40Ca in groundwater, hydrogeochemical processes such as mineral weathering dissolution, cation exchange, and secondary mineral precipitation can be elucidated, crucial for understanding the formation and evolution mechanisms of high fluoride groundwater.Additionally, lithium-boron isotopes serve as important tools in the study of high fluoride groundwater. Measurements of δ7Li and δ11B allow for the assessment of the influence of geothermal fluids on deep-seated high fluoride groundwater. In conclusion, stable isotopes hold immense potential in high fluoride groundwater research. By measuring deuterium-oxygen isotopes, strontium-calcium isotopes, and lithium-boron isotopes, we can gain profound insights into the origin, cycling, and evolution processes of high fluoride groundwater, thus providing a scientific basis for its management and water resource conservation. This research also offers crucial support for the development of appropriate prevention and control measures, ultimately safeguarding human health.
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