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2022 Vol. 42, No. 4
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Article navigation > Sedimentary Geology and Tethyan Geology > 2022 > 42(4): 542-555
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HU Zhizhong, YAN Xiong, DU Gu, WANG Guan, XU Guodong, HE Jiale, JIN Lu, LAN Mingguo, HE Xiuhui. 2022. The Calcite 811N, a potential isotope standard material for isotopic analyses of carbon, oxygen and strontium. Sedimentary Geology and Tethyan Geology, 42(4): 542-555. doi: 10.19826/j.cnki.1009-3850.2022.09004
Citation: HU Zhizhong, YAN Xiong, DU Gu, WANG Guan, XU Guodong, HE Jiale, JIN Lu, LAN Mingguo, HE Xiuhui. 2022. The Calcite 811N, a potential isotope standard material for isotopic analyses of carbon, oxygen and strontium. Sedimentary Geology and Tethyan Geology, 42(4): 542-555. doi: 10.19826/j.cnki.1009-3850.2022.09004
shu

The Calcite 811N, a potential isotope standard material for isotopic analyses of carbon, oxygen and strontium

  • 1. Chengdu Center, China Geological Survey, Chengdu 610081, China;

  • 2. Key Laboratory of Sedimentary Basin and Oil and Gas Resources, Ministry of Natural Resources, Chengdu 610081, China;

  • 3. Kunming Center of Natural Resource Comprehensive Survey, China Geological Survey, Kunming 650100, China

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  • Corresponding author: DU Gu  
Received Date:  22 November 2021
Revised Date:  11 March 2022
    Abstract
  • The isotope standard materials are important in analyzing isotopic compositions in a lab. The Calcite 811 has been a laboratory standard material for analyses of isotopic compositions of carbon and oxygen isotope of carbonate, but it was made a long time ago and its stock on hand is decreasing day by day, and its current quality situation is usually unclear. This study selects the un-used Calcite 811 as a research object, using a variety of analysis techniques such as the LA-(MC)-ICP-MS, laser Raman spectroscopy, XRD and EDX-SEM, to study its mineral, chemical, and isotopic compositions, in order to find a method for making a new isotope standard material, the Calcite 811N, to substitute the Calcite 811 in the future. The results show that the Calcite 811N is almost composed of calcite, containing few dolomite, needle-shaped iron ore, and clay minerals. Apart from its main chemical compositions of CaCO3, the Calcite 811N has trace amounts of elements such as Mg, Mn, Sr, Si, REE, U, and Th. As a whole, the contents of Mg, Mn, Sr are somewhat changeable, but they are relatively uniform in a small scope. The carbon isotopic and oxygen isotopic results are little different, the difference of which is consistent with the uniformity of distrubution of Mg，Mn,Sr. Isotopic compositions of carbon and oxygen are homogeneous in the main region of the Calcite 811N. The isotopic compositions of Sr have no significant differences in different parts. The δ13C and δ18O of Calcite 811N are changeable on the whole, but their differences are very small. So concluded that the Calcite 811N is a suitable isotopic standard material for situ and micro isotopic analyses of carbon, oxygen, and strontium of carbonate.
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