2021 Vol. 41, No. 3
Article Contents

XU Bo, ZENG Wenqian, DIAO Hui, TANG Rui, OU Ge. Trace rare earth elements in the Pinghu Formation of Xihu Sag and its implications for paleo-production environment[J]. Marine Geology & Quaternary Geology, 2021, 41(3): 72-84. doi: 10.16562/j.cnki.0256-1492.2020082402
Citation: XU Bo, ZENG Wenqian, DIAO Hui, TANG Rui, OU Ge. Trace rare earth elements in the Pinghu Formation of Xihu Sag and its implications for paleo-production environment[J]. Marine Geology & Quaternary Geology, 2021, 41(3): 72-84. doi: 10.16562/j.cnki.0256-1492.2020082402

Trace rare earth elements in the Pinghu Formation of Xihu Sag and its implications for paleo-production environment

  • The Xihu Sag has been proved as a hydrocarbon-rich basin in the East China Sea with the Pinghu Formation of Eocene as the main source rock. Based on the analysis data of 433 samples from 30 wells in the sag for geochemistry and micronutrients, the characteristics and vertical distribution patterns of organic carbon, micronutrients and rare earth elements are studied for the lower, middle and upper members of the Pinghu Formation respectively. The vertical patterns of palaeosalinities, palaeoclimate, palaeooxidation-reduction environment, palaeowater depth, palaeotemperature and palaeoproductivities of the Pinghu Formation suggest that Rb, Ba and Zr are enriched in micronutrients, shown as significant positive anomalies, while Co, Mo, Sc and Hf are deficient relatively. Sr/Ba、Sr/Cu、paleoclimate value C、V/Cr、Ni/Co、U/Th、V/(V+Ni)、V/Sc、Mn/Fe、Co、Sr、Sr/Cu、Baxs indicate that Pinghu Formation is formed in a terrestrial fresh water environment under warm, semi-arid to semi-humid climate with high paleoproductivity and high potential for hydrocarbon generation.

  • 加载中
  • [1] 朱光有, 金强, 张水昌, 等. 东营凹陷沙河街组湖相烃源岩的组合特征[J]. 地质学报, 2004, 78(3):416-427 doi: 10.3321/j.issn:0001-5717.2004.03.015

    CrossRef Google Scholar

    ZHU Guangyou, JIN Qiang, ZHANG Shuichang, et al. Combination characteristics of lake facies source rock in the Shahejie formation, Dongying depression [J]. Acta Geologica Sinica, 2004, 78(3): 416-427. doi: 10.3321/j.issn:0001-5717.2004.03.015

    CrossRef Google Scholar

    [2] Demaison G J, Moore G T. Anoxic environments and oil source bed genesis [J]. Organic Geochemistry, 1980, 2(1): 9-31. doi: 10.1016/0146-6380(80)90017-0

    CrossRef Google Scholar

    [3] Calvert S E, Fontugne M R. On the late pleistocene-holocene sapropel record of climatic and oceanographic variability in the eastern Mediterranea [J]. Paleoceanography and Paleoclimatology, 2001, 16(1): 78-94.

    Google Scholar

    [4] Rinna J, Warning B, Meyers P A, et al. Combined organic and inorganic geochemical reconstruction of paleodepositional conditions of a pliocene sapropel from the eastern Mediterranean sea [J]. Geochimica et Cosmochimica Acta, 2002, 66(11): 1969-1986. doi: 10.1016/S0016-7037(02)00826-8

    CrossRef Google Scholar

    [5] Sageman B B, Murphy A E, Werne J P, et al. A tale of shales: the relative roles of production, decomposition, and dilution in the accumulation of organic-rich Strata, middle-upper Devonian, Appalachian basin [J]. Chemical Geology, 2003, 195(1-4): 229-273. doi: 10.1016/S0009-2541(02)00397-2

    CrossRef Google Scholar

    [6] Mort H, Jacquat O, Adatte T, et al. The cenomanian/turonian anoxic event at the bonarelli level in Italy and Spain: enhanced productivity and/or better preservation? [J]. Cretaceous Research, 2007, 28(4): 597-612. doi: 10.1016/j.cretres.2006.09.003

    CrossRef Google Scholar

    [7] Wei H Y, Chen D Z, Wang J G, et al. Organic accumulation in the Lower Chihsia formation (Middle Permian) of South China: constraints from pyrite morphology and multiple geochemical proxies [J]. Palaeogeography, Palaeoclimatology, Palaeoecology, 2012, 353-355: 73-86. doi: 10.1016/j.palaeo.2012.07.005

    CrossRef Google Scholar

    [8] 李艳芳, 邵德勇, 吕海刚, 等. 四川盆地五峰组—龙马溪组海相页岩元素地球化学特征与有机质富集的关系[J]. 石油学报, 2015, 36(12):1470-1483 doi: 10.7623/syxb201512002

    CrossRef Google Scholar

    LI Yanfang, SHAO deyong, LV Haigang, et al. A relationship between elemental geochemical characteristics and organic matter enrichment in marine shale of Wufeng Formation—Longmaxi Formation, Sichuan basin [J]. Acta Petrolei Sinica, 2015, 36(12): 1470-1483. doi: 10.7623/syxb201512002

    CrossRef Google Scholar

    [9] Demaison GJ, Moore GT. Anixic environments and oil sourced genesis [J]. AAPG Bulletin, 1980, 64(8): 1179-1209.

    Google Scholar

    [10] Pedersen T F, Calver S E. Anoxia vs. productivity: what controls the formation of organic-carbon-rich sediments and sedimentary rocks [J]. AAPG Bulletin, 1990, 74(4): 454-466.

    Google Scholar

    [11] 张水昌, 张宝民, 边立曾, 等. 中国海相烃源岩发育控制因素[J]. 地学前缘, 2005, 12(3):39-48 doi: 10.3321/j.issn:1005-2321.2005.03.006

    CrossRef Google Scholar

    ZHANG Shuichang, ZHANG Baomin, BIAN Liceng, et al. Development constraints of marine source rocks in China [J]. Earth Science Frontiers, 2005, 12(3): 39-48. doi: 10.3321/j.issn:1005-2321.2005.03.006

    CrossRef Google Scholar

    [12] 常华进, 储雪蕾, 冯连君, 等. 氧化还原敏感微量元素对古海洋沉积环境的指示意义[J]. 地质论评, 2009, 55(1):91-99 doi: 10.3321/j.issn:0371-5736.2009.01.011

    CrossRef Google Scholar

    CHANG Huajin, CHU Xuelei, FENG Lianjun, et al. Redox sensitive trace elements as paleoenvironments proxies [J]. Geological Review, 2009, 55(1): 91-99. doi: 10.3321/j.issn:0371-5736.2009.01.011

    CrossRef Google Scholar

    [13] 李双建, 肖开华, 沃玉进, 等. 南方海相上奥陶统-下志留统优质烃源岩发育的控制因素[J]. 沉积学报, 2008, 26(5):872-880

    Google Scholar

    LI Shuangjian, XIAO Kaihua, WO Yujin, et al. Developmental controlling factors of Upper Ordovician-Lower Silurian high quality source rocks in marine sequence, South China [J]. Acta Sedimentologica Sinica, 2008, 26(5): 872-880.

    Google Scholar

    [14] 熊小辉, 肖加飞. 沉积环境的地球化学示踪[J]. 地球与环境, 2011, 39(3):405-414

    Google Scholar

    XIONG Xiaohui, XIAO Jiafei. Geochemical indicators of sedimentary environments-a summary [J]. Earth and Environment, 2011, 39(3): 405-414.

    Google Scholar

    [15] Tribovillard N, Algeo T J, Lyons T, et al. Trace metals as paleoredox and paleoproductivity proxies: an update [J]. Chemical Geology, 2006, 232(1-2): 12-32. doi: 10.1016/j.chemgeo.2006.02.012

    CrossRef Google Scholar

    [16] Tribovillard N, Algeo T J, Baudin F, et al. Analysis of marine environmental conditions based on molybdenum-uranium covariation-applications to Mesozoic Paleoceanography [J]. Chemical Geology, 2012, 324-325: 46-58. doi: 10.1016/j.chemgeo.2011.09.009

    CrossRef Google Scholar

    [17] 胡玮, 卢宗盛, 喻鹏. 陆相盆地古生产力研究现状[J]. 地质科技情报, 2010, 29(6):15-20 doi: 10.3969/j.issn.1000-7849.2010.06.003

    CrossRef Google Scholar

    HU Wei, LU Zongsheng, YU Peng. Current status of paleoproductivity research in continental basins [J]. Geological Science and Technology Information, 2010, 29(6): 15-20. doi: 10.3969/j.issn.1000-7849.2010.06.003

    CrossRef Google Scholar

    [18] Algeo T J, Maynard J B. Trace-element behavior and redox facies in core shales of Upper Pennsylvanian Kansas-type cyclothems [J]. Chemical Geology, 2004, 206(3-4): 289-318. doi: 10.1016/j.chemgeo.2003.12.009

    CrossRef Google Scholar

    [19] 叶加仁, 任建业, 吴景富, 等. 中国近海富烃凹陷特征及评价[M]. 北京: 科学出版社, 2016: 1-361.

    Google Scholar

    YE Jiaren, REN Jianye, WU Jingfu, et al. Characteristics and Evaluation of Hydrocarbon-Rich Depressions in Offshore China[M]. Beijing: Science Press, 2016: 1-361.

    Google Scholar

    [20] 卢双舫, 张敏. 油气地球化学[M]. 北京: 石油工业出版社, 2008: 1-273.

    Google Scholar

    LU Shuangfang, ZHANG Min. Organic Geochemistry of Petroleum[M]. Beijing: Petroleum Industry Press, 2008: 1-273.

    Google Scholar

    [21] 田正隆, 陈绍勇, 龙爱民. 以Ba为指标反演海洋古生产力的研究进展[J]. 热带海洋学报, 2004, 23(3):78-86 doi: 10.3969/j.issn.1009-5470.2004.03.012

    CrossRef Google Scholar

    TIAN Zhenglong, CHEN Shaoyong, LONG Aimin. A review on barium as a geochemical proxy to reconstruct paleoproductivity [J]. Journal of Tropical Oceanography, 2004, 23(3): 78-86. doi: 10.3969/j.issn.1009-5470.2004.03.012

    CrossRef Google Scholar

    [22] 薛罗. 恩平凹陷古近系烃源岩元素地球化学综合评价[D]. 中国地质大学(武汉)硕士学位论文, 2013.

    Google Scholar

    XUE Luo. Element geochemistry evaluation of paleogene source rocks in Enping depression[D]. Master Dissertation of China University of Geosciences (Wuhan), 2013.

    Google Scholar

    [23] Mason B. Meteorites[M]//Fleischerl M. Data of Geochemistry, Chap B, Part I, USGS Prof Paper 440 B-1, US Government Printing Office. 1979: 132.

    Google Scholar

    [24] 彭海艳, 陈洪德, 向芳, 等. 微量元素分析在沉积环境识别中的应用——以鄂尔多斯盆地东部二叠系山西组为例[J]. 新疆地质, 2006, 24(2):202-205 doi: 10.3969/j.issn.1000-8845.2006.02.022

    CrossRef Google Scholar

    PENG Haiyan, CHEN Hongde, XIANG Fang, et al. Application of trace elements analysis on sedimentary environment identification--an example from the Permian Shanxi formation in eastern ordos basin [J]. Xinjiang Geology, 2006, 24(2): 202-205. doi: 10.3969/j.issn.1000-8845.2006.02.022

    CrossRef Google Scholar

    [25] 关有志. 科尔沁沙地的元素、粘土矿物与沉积环境[J]. 中国沙漠, 1992, 12(1):9-15

    Google Scholar

    GUAN Youzhi. The element, clay mineral and depositional environment in Horqin sand land [J]. Journal of Desert Research, 1992, 12(1): 9-15.

    Google Scholar

    [26] Jones B, Manning D A C. Comparison of geochemical indices used for the interpretation of palaeoredox conditions in ancient mudstones [J]. Chemical Geology, 1994, 111(1-4): 111-129. doi: 10.1016/0009-2541(94)90085-X

    CrossRef Google Scholar

    [27] Nicholls G D. Trace elements in sediments: an assessment of their possible utility as depth indicators [J]. Marine Geology, 1967, 5(5-6): 539-555. doi: 10.1016/0025-3227(67)90059-X

    CrossRef Google Scholar

    [28] 吴智平, 周瑶琪. 一种计算沉积速率的新方法——宇宙尘埃特征元素法[J]. 沉积学报, 2000, 18(3):395-399 doi: 10.3969/j.issn.1000-0550.2000.03.012

    CrossRef Google Scholar

    WU Zhiping, ZHOU Yaoqi. Using the characteristic elements from meteoritic must in strata to calculate sedimentation rate [J]. Acta Sedimentologica Sinica, 2000, 18(3): 395-399. doi: 10.3969/j.issn.1000-0550.2000.03.012

    CrossRef Google Scholar

    [29] 周瑶琪, 吴智平. 地层间断面的时间结构研究[M]. 北京: 地质出版社, 2000.

    Google Scholar

    ZHOU Yaoqi, WU Zhiping. Study on the Time Compositional Units of Hiatus Surface[M]. Beijing: Geological Publishing House, 2000.

    Google Scholar

    [30] 周洪瑞, 王自强, 崔新省, 等. 华北地台南部中新元古界层序地层研究[M]. 北京: 地质出版社, 1999.

    Google Scholar

    ZHOU Hongrui, WANG Ziqiang, CUI Xinsheng, et al. Study of the Neoproterozoic Strata on the southern of the North China Platform[M]. Beijing: Geological Publishing House, 1999.

    Google Scholar

    [31] 张才利, 高阿龙, 刘哲, 等. 鄂尔多斯盆地长7油层组沉积水体及古气候特征研究[J]. 天然气地球科学, 2011, 22(4):582-587

    Google Scholar

    ZHANG Caili, GAO Along, LIU Zhe, et al. Study of character on sedimentary water and palaeoclimate for Chang 7 oil layer in Ordos basin [J]. Natural Gas Geoscience, 2011, 22(4): 582-587.

    Google Scholar

    [32] 周瑶琪, 吴智平. 中子活化技术在层序地层学中的应用[J]. 地学前缘, 5(1-2): 143-149.

    Google Scholar

    ZHOU Yaoqi, WU Zhiping. Applications of neutron activation analysis in sequence stratigraphy[J]. Earth Science Frontiers, 5(1-2): 143-149.

    Google Scholar

    [33] 刘福田, 李荣西, 赵帮胜, 等. 鄂尔多斯盆地西南缘蓟县系碳酸盐岩碳氧同位素特征及其地质意义[J]. 兰州大学学报(自然科学版), 2018, 54(4):597-603, 611

    Google Scholar

    LIU Futian, LI Rongxi, ZHAO Bangsheng, et al. Characteristics of carbon and oxygen isotopes of the Jixian System carbonate rocks in the southwestern margin of Ordos Basin and their implication [J]. Journal of Lanzhou University (Natural Sciences), 2018, 54(4): 597-603, 611.

    Google Scholar

    [34] Epstein S, Buchsbaum R, Lowenstam H A, et al. Revised carbonate-water isotopic temperature scale [J]. GSA Bulletin, 1953, 64(11): 1315-1326. doi: 10.1130/0016-7606(1953)64[1315:RCITS]2.0.CO;2

    CrossRef Google Scholar

    [35] 陈慧, 解习农, 李红敬, 等. 利用古氧相和古生产力替代指标评价四川上寺剖面二叠系海相烃源岩[J]. 古地理学报, 2010, 12(3):324-333 doi: 10.7605/gdlxb.2010.03.008

    CrossRef Google Scholar

    CHEN Hui, XIE Xinong, LI Hongjing, et al. Evaluation of the Permian marine hydrocarbon source rocks at Shangsi section in Sichuan Province using multi-proxies of paleoproductivity and paleoredox [J]. Journal of Palaeogeography, 2010, 12(3): 324-333. doi: 10.7605/gdlxb.2010.03.008

    CrossRef Google Scholar

    [36] 韦恒叶. 古海洋生产力与氧化还原指标——元素地球化学综述[J]. 沉积与特提斯地质, 2012, 32(2):76-88 doi: 10.3969/j.issn.1009-3850.2012.02.012

    CrossRef Google Scholar

    WEI Hengye. Productivity and redox proxies of palaeo-oceans: An overview of elementary geochemistry [J]. Sedimentary Geology and Tethyan Geology, 2012, 32(2): 76-88. doi: 10.3969/j.issn.1009-3850.2012.02.012

    CrossRef Google Scholar

    [37] Tatlor S R, McLennan S M. The continental Crust: its composition and evolution: an examination of the Geochemical record preserved in sedimentary rocks[M]. Oxford: Blackwell Scientific Publications, 1985: 312.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(13)

Tables(6)

Article Metrics

Article views(2014) PDF downloads(100) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint