2019 Vol. 39, No. 4
Article Contents

SHA Zhibin, XU Zhenqiang, FU Shaoying, LIANG Jinqiang, ZHANG Wei, SU Pibo, LU Hongfeng, LU Jing'an. Gas sources and its implications for hydrate accumulation in the eastern Pearl River Mouth Basin[J]. Marine Geology & Quaternary Geology, 2019, 39(4): 116-125. doi: 10.16562/j.cnki.0256-1492.2019010902
Citation: SHA Zhibin, XU Zhenqiang, FU Shaoying, LIANG Jinqiang, ZHANG Wei, SU Pibo, LU Hongfeng, LU Jing'an. Gas sources and its implications for hydrate accumulation in the eastern Pearl River Mouth Basin[J]. Marine Geology & Quaternary Geology, 2019, 39(4): 116-125. doi: 10.16562/j.cnki.0256-1492.2019010902

Gas sources and its implications for hydrate accumulation in the eastern Pearl River Mouth Basin

  • Pressure cores and void gas samples are collected by drilling from target layers at five coring sites in the eastern Pearl River Mouth Basin. Dissociation gas is also sampled in thirteen layers, while headspace gas samples acquired at all the five sites. All gas samples have been tested for chemical and isotopic compositions. The gas is methane dominated, which is up to 96.5%~99.8% in concentration. Trace amount of ethane is also detected in concentration of (175~554)×10-6. No C2+ hydrocarbons have been found in all the gas samples. The isotopes of carbon and hydrogen of the methane suggest that δ13C1 is in the range of -68.4‰~-71.2‰, with δDC1 from -182‰ to -184‰, indicating a biogenic origin. The gas source of hydrate is not directly related to the occurrence of hydrate, while hydrate with multiple sources seems closely related to the evolution and morphological characteristics of reservoir. The main gas source area is located in the shallow strata less than 1000m in depth, suggesting that the hydrocarbon has migrated to the favorable stability zone to form gas hydrate accumulation by shallow lateral migration.

  • 加载中
  • [1] Ginsburgc G D, Soloviev V A. Methane migration within the submarine gas-hydrate stability zone under deep-water conditions[J]. Marine Geology, 1997, 137(1-2):49-57. doi: 10.1016/S0025-3227(96)00078-3

    CrossRef Google Scholar

    [2] Waseda A, Uchida T. Origin and migration of methane in gas hydrate-bearing sediments in the Nankai Trough[J]. The Geochemical Society Special Publications, 2004, 9: 377-387. doi: 10.1016/S1873-9881(04)80027-0

    CrossRef Google Scholar

    [3] Choi J, Kim J H, Torres M E, et al. Gas origin and migration in the Ulleung Basin, East Sea: Results from the Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2)[J]. Marine and Petroleum Geology, 2013, 47: 113-124. doi: 10.1016/j.marpetgeo.2013.05.022

    CrossRef Google Scholar

    [4] Sassen R, Joye S, Sweet S Y, et al. Thermogenic gas hydrates and hydrocarbon gases in complex chemosynthetic communities, Gulf of Mexico continental slope[J]. Organic Geochemistry, 1999, 30: 485-497. doi: 10.1016/S0146-6380(99)00050-9

    CrossRef Google Scholar

    [5] Smith A J, Mienert J, Bünz S, et al. Thermogenic methane injection via bubble transport into the upper Arctic Ocean from the hydrate-charged Vestnesa Ridge, Svalbard. Geochemistry. Geophysics[J]. Geosystems, 2014, 15(5): 1945-1959.

    Google Scholar

    [6] Lüdmann T, Wong H. Characteristics of gas hydrate occurrences associated with mud diapirism and gas escape structures in the northwestern Sea of Okhotsk[J]. Marine Geology, 2003, 201(4): 269-286. doi: 10.1016/S0025-3227(03)00224-X

    CrossRef Google Scholar

    [7] Pohlman J W, Canuel E A, Chapman N R, et al. The origin of thermogenic gas hydrates on the northern Cascadia Margin as inferred from isotope (13C/12C and D/H) and molecular composition of hydrate and vent gas[J]. Organic Geochemistry, 2005, 36: 703-716. doi: 10.1016/j.orggeochem.2005.01.011

    CrossRef Google Scholar

    [8] Vaular E N, Barth T, Haflidason H. The geochemical characteristics of the hydrate-bound gases from the Nyegga pockmark field, Norwegian Sea[J]. Organic Geochemistry, 2010, 41: 437-444. doi: 10.1016/j.orggeochem.2010.02.005

    CrossRef Google Scholar

    [9] Lorenson T D, Collett T S. National gas hydrate expedition 01 offshore India; gas hydrate systems as revealed by hydrocarbon gas geochemistry[J]. Marine and Petroleum Geology, 2018, 92: 477-492. doi: 10.1016/j.marpetgeo.2017.11.011

    CrossRef Google Scholar

    [10] Zhang W, Liang J Q, Lu J A, et al. Accumulation features and mechanisms of high saturation natural gas hydrate in Shenhu Area, northern South China Sea[J]. Petroleum Exploration and Development, 2017, 44(5): 708-719. doi: 10.1016/S1876-3804(17)30082-4

    CrossRef Google Scholar

    [11] Zhang G X, Liang J Q, Lu J A, et al., Geological features, controlling factors and potential prospects of the gas hydrate occurrence in the east part of the Pearl River Mouth Basin, South China Sea[J]. Marine and Petroleum Geology, 2015, 67: 356-367. doi: 10.1016/j.marpetgeo.2015.05.021

    CrossRef Google Scholar

    [12] Sha Z B, Liang J Q, Zhang G X, et al. Seepage gas hydrate system in northern South China Sea: Seismic and well log interpretations[J]. Marine Geology, 2015, 366:69-78. doi: 10.1016/j.margeo.2015.04.006

    CrossRef Google Scholar

    [13] 刘昌岭, 李彦龙, 孙建业, 等.天然气水合物试采:从实验模拟到现场实施[J].海洋地质与第四纪地质, 2017, 37(5):12-26.

    Google Scholar

    LIU Changling, LI Yanlong, SUN Jianye, et al.Gas hydrate production test: From experimental simulation to filed practice[J]. Marine Geology & Quaternary Geology, 2017, 37(5):12-26.

    Google Scholar

    [14] 王力峰, 尚久靖, 梁金强, 等.南海东北部陆坡水合物钻探区海底表层热导率分布特征[J].海洋地质与第四纪地质, 2016, 36(2):29-37.

    Google Scholar

    WANG Lifeng, SHANG Jiujing, LIANG Jinqiang, et al. Distribution pattern of seafloor thermal conductivities at the drilling area for gas hydrate on the northeastern slope of South China Sea[J]. Marine Geology & Quaternary Geology, 2016, 36(2):29-37.

    Google Scholar

    [15] 沙志彬, 梁金强, 苏丕波, 等.珠江口盆地东部海域天然气水合物钻探结果及其成藏要素研究[J].地学前缘, 2015, 22(6):125-135.

    Google Scholar

    SHA Zhibin, LIANG Jinqiang, SU Pibo, et al. Natural gas hydrate accumulation elements and drilling results analysis in the eastern part of the Pearl River Mouth Basin[J]. Earth Science Frontiers, 2015, 22(6):125-135.

    Google Scholar

    [16] 施和生, 何敏, 张丽丽, 等.珠江口盆地(东部)油气地质特征、成藏规律及下一步勘探策略[J].中国海上油气, 2014, 26 (3):11-22.

    Google Scholar

    SHI Hesheng, HE Min, ZHANG Lili, et al. Hydrocarbon geology, accumulation pattern and the next exploration strategy in the eastern Pearl River Mouth Basin[J]. China Offshore Oil and Gas, 2014, 26 (3):11-22.

    Google Scholar

    [17] 何家雄, 刘海龄, 姚永坚, 等.南海北部边缘盆地油气地质及资源前景[M].北京:石油工业出版社, 2008.

    Google Scholar

    HE Jiaxiong, LIU Hailing, YAO Yongjian, et al.The Petroleum Geology and the Resource Potential of the Marginal Basins in the Northern South China Sea[M]. Beijing: Petroleum Industry Press, 2008.

    Google Scholar

    [18] 梁金强, 付少英, 陈芳, 等.南海东北部陆坡海底甲烷渗漏及水合物成藏特征[J].天然气地球科学, 2017, 28(5):761-770.

    Google Scholar

    LIANG Jinqiang, FU Shaoying, CHEN Fang, et al. Characteristics of methane seepage and gas hydrate reservoir in the northeastern slope of South China Sea[J]. Natural Gas Geoscience, 2017, 28(5):761-770.

    Google Scholar

    [19] 王秀娟, 吴时国, 刘学伟, 等.东沙海域天然气水合物特征分析及饱和度估算[J].石油物探, 2009, 48 (5):445-452. doi: 10.3969/j.issn.1000-1441.2009.05.003

    CrossRef Google Scholar

    WANG Xiujuan, WU Shiguo, LIU Xuewei, et al. Characteristic analysis and saturation estimation of gas hydrate in Dongsha sea area[J]. Geophysical Prospecting for Petroleum, 2009, 48 (5):445-452. doi: 10.3969/j.issn.1000-1441.2009.05.003

    CrossRef Google Scholar

    [20] Youhai Z, Xia H, Shaoying F, et al. Gas sources of natural gas hydrates in the Shenhu Drilling Area, South China Sea: geochemical evidence and geological analysis[J]. Acta Geologica Sinica (English Edition), 2013, 87(3): 767-776. doi: 10.1111/1755-6724.12088

    CrossRef Google Scholar

    [21] 黄霞, 祝有海, 卢振权, 等.南海北部天然气水合物钻探区烃类气体成因类型研究[J].现代地质, 2010, 24(3):576-580. doi: 10.3969/j.issn.1000-8527.2010.03.023

    CrossRef Google Scholar

    HUANG Xia, ZHU Youhai, LU Zhenquan, et al. Study on genetic types of hydrocarbon gases from the gas hydrate drilling area, the northern South China Sea[J]. Geoscience, 2010, 24(3):576-580. doi: 10.3969/j.issn.1000-8527.2010.03.023

    CrossRef Google Scholar

    [22] 丛晓荣, 苏明, 吴能友, 等.富生烃凹陷背景下热成因气对水合物成藏贡献的探讨[J].地质学报, 2018, 92(1):170-183. doi: 10.3969/j.issn.0001-5717.2018.01.012

    CrossRef Google Scholar

    CONG Xiaorong, SU Ming, WU Nengyou, et al. Contribution of thermogenic gases to hydrate accumulation under the marine hydrocarbon-rich depression setting[J]. Acta Geologica Sinica, 2018, 92(1):170-183. doi: 10.3969/j.issn.0001-5717.2018.01.012

    CrossRef Google Scholar

    [23] Whiticar M J, Faber E, Schoell M. Biogenic methane formation in marine and freshwater environments: CO2 reduction VS. acetate fermentation-isotope evidence[J]. Geochimica et Cosmochimica Acta, 1986, 50: 693-709. doi: 10.1016/0016-7037(86)90346-7

    CrossRef Google Scholar

    [24] 李先奇, 张水昌, 朱光有, 等.中国生物成因气的类型划分与研究方向[J].天然气地球科学, 2005, 16(4):477-484. doi: 10.3969/j.issn.1672-1926.2005.04.015

    CrossRef Google Scholar

    LI Xianqi, ZHANG Shuichang, ZHU Guangyou, et al. Types and research direction of biogenic gas in China[J]. Natural Gas Geoscience, 2005, 16(4):477-484. doi: 10.3969/j.issn.1672-1926.2005.04.015

    CrossRef Google Scholar

    [25] 张水昌, 赵文智, 李先奇, 等.生物气研究新进展与勘探策略[J].石油勘探与开发, 2005, 32 (4):90-96. doi: 10.3321/j.issn:1000-0747.2005.04.015

    CrossRef Google Scholar

    ZHANG Shuichang, ZHAO Wenzhi, LI Xianqi, et al. Advances in biogenic gas studies and play strategies[J]. Petroleum Exploration and Development, 2005, 32 (4):90-96. doi: 10.3321/j.issn:1000-0747.2005.04.015

    CrossRef Google Scholar

    [26] Bernard B, Brooks J M, Sackett W M. A geochemical model for characterization of hydrocarbon gas sources in marine sediments[C]//Offshore Technology Conference. 1977.

    Google Scholar

    [27] Whiticar M J. Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane[J]. Chemical Geology, 1999, 161(1-3): 291-314. doi: 10.1016/S0009-2541(99)00092-3

    CrossRef Google Scholar

    [28] Matsumoto R, Takashi U, Waseda A, et al. Occurrence, structure, and composition of natural gas hydrate recovered from the Blake Ridge, Northwest Atlantic[R]//Proceedings of the Ocean Drilling Program Scientific Results. 2000, 164: 13-28.

    Google Scholar

    [29] 毕海波, 马立杰, 黄海军, 等.台西南盆地天然气水合物甲烷量估算[J].海洋地质与第四纪地质, 2010, 30(4):179-186.

    Google Scholar

    BI Haibo, MA Lijie, HUANG Haijun, et al. Estimation of methane amount contained in gas hydrate in Taixi'nan Basin based on GIS[J]. Marine Geology & Quaternary Geology, 2010, 30(4):179-186.

    Google Scholar

    [30] Ye J L, Qin X W, Qiu H J, et al. Data Report: Molecular and Isotopic composition of the extracted gas from China's first offshore national gas hydrate production test in South China Sea[J]. Energies, 2018, 11(10): 2793. doi: 10.3390/en11102793

    CrossRef Google Scholar

    [31] 毕海波.台西南海域天然气水合物含量估算及地球化学特征分析[D].中国科学院海洋研究所, 2010.http://cdmd.cnki.com.cn/article/cdmd-80068-2010147972.htm

    Google Scholar

    BI Haibo. Amount estimation and geochemical analysis of gas hydrate of Tai Xi Nan Basin[D]. Institute of Oceanology, Chinese Academy of Sciences, 2010.

    Google Scholar

    [32] 何家雄, 颜文, 祝有海, 等.全球天然气水合物成矿气体成因类型及气源构成与主控因素[J].海洋地质与第四纪地质, 2013, 33(2):121-128.

    Google Scholar

    HE Jiaxiong, YAN Wen, ZHU Youhai, et al. Genetic types of gas hydrate in the word and their main controlling factors[J]. Marine Geology & Quaternary Geology, 2013, 33(2):121-128.

    Google Scholar

    [33] 邬黛黛.南海天然气水合物的早期成岩作用和地球化学特性研究[D].浙江大学, 2008.http://cdmd.cnki.com.cn/Article/CDMD-10335-2009024630.htm

    Google Scholar

    WU Daidai. Early diagenesis records and geochemical characteritics of gas hydrate in the South China Sea[D]. Zhejiang University, 2008.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(6)

Tables(1)

Article Metrics

Article views(2439) PDF downloads(123) Cited by(0)

Access History

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint