Professional Committee of Rock and Mineral Testing Technology of the Geological Society of China, National Geological Experiment and Testing CenterHost
2024 Vol. 43, No. 6
Article Contents

CUI Yurong, YANG Jun, TU Jiarun, XIAO Zhibin, ZHOU Hongying, YU Guangming, CUI Minli, LIU Jiufen. Cassiterite U-Pb Dating with LA-MC-ICP-MS of the Laozhailing Cu-Sn Deposit, Yongzhou City, Hunan Province[J]. Rock and Mineral Analysis, 2024, 43(6): 880-891. doi: 10.15898/j.ykcs.202402290025
Citation: CUI Yurong, YANG Jun, TU Jiarun, XIAO Zhibin, ZHOU Hongying, YU Guangming, CUI Minli, LIU Jiufen. Cassiterite U-Pb Dating with LA-MC-ICP-MS of the Laozhailing Cu-Sn Deposit, Yongzhou City, Hunan Province[J]. Rock and Mineral Analysis, 2024, 43(6): 880-891. doi: 10.15898/j.ykcs.202402290025

Cassiterite U-Pb Dating with LA-MC-ICP-MS of the Laozhailing Cu-Sn Deposit, Yongzhou City, Hunan Province

More Information
  • Cassiterite is an important ore mineral in tin polymetallic deposits. Using cassiterite for dating tin polymetallic deposits has become one of the most direct methods to obtain the mineralization age of the deposits. However, due to the low uranium content and high common lead characteristics of cassiterite, the main problems and technical difficulties of the in situ U-Pb dating method for cassiterite lie in the development of ideal standards and the accuracy of common lead correction. The mineralization age of the Laozhailing Cu-Sn deposit in Yongzhou City, Hunan Province is constrained here by optimizing the technology. The Laozhailing Cu-Sn deposit is a vein-type tin polymetallic deposit, which is mainly composed of tin-quartz veins, cataclastic greisenized granite, and greisen. Three samples, 16LZ01, 16LZ02, and 16LZ03, were obtained with Tera-Wasserburg U-Pb lower intersection ages of 222.0±1.5Ma (MSWD=1.6, n=37), 220.5±3.5Ma (MSWD=2.9, n=28), and 225.0±1.6Ma (MSWD=1.3, n=31), respectively. These results indicate mineralization in the late Indosinian period. The mineralization of the Laozhailing Cu-Sn deposit is closely related to the magmatic hydrothermal activity of the Yangmingshan complex granites. The results of this study provide important chronological evidence for the magmatic hydrothermal origin of the Laozhailing Cu-Sn deposit.

  • 加载中
  • [1] Gulson B L, Jones M T. Cassiterite: Potential for direct dating of mineral deposits and a precise age for the Bushveld complex granites[J]. Geology, 1992, 355-358.

    Google Scholar

    [2] Jiang S Y, Yu J M, Lu J J. Trace and rare-earth element geochemistry in tourmaline and cassiterite from the Yunlong tin deposit, Yunnan, China: Implication for migmatitic-hydrothermal fluid evolution and ore genesis[J]. Chemical Geology, 2004, 209: 193−213.

    Google Scholar

    [3] 李惠民, 郝爽, 耿建珍, 等. 用激光烧蚀多接收器等离子体质谱(LA-MC-ICPMS)直接原位测定锡多金属矿床中的锡石U-Pb同位素年龄[J]. 矿物学报, 2009, 29(S1): 313. doi: 10.3321/j.issn:1000-4734.2009.z1.163

    CrossRef Google Scholar

    Li H M, Hao S, Geng J Z, et al. Direct determination of cassiterite U-Pb isotope age in the tin polymentallic deposit by laser ablation multiple receivers plasma mass spectrometry (LA-MC-ICP-MS)[J]. Acta Mineralogica Sinica, 2009, 29(S1): 313. doi: 10.3321/j.issn:1000-4734.2009.z1.163

    CrossRef Google Scholar

    [4] Yuan S D, Peng J T, Hao S, et al. In situ LA-MC-ICP-MS and ID-TIMS U-Pb geochronology of cassiterite in the giant Furong tin deposit, Hunan Province, South China: New constraints on the timing of tin-polymetallic mineralization[J]. Ore Geology Reviews, 2011, 43: 235−242. doi: 10.1016/j.oregeorev.2011.08.002

    CrossRef Google Scholar

    [5] 马楠, 邓军, 王庆飞, 等. 云南腾冲大松坡锡矿成矿年代学研究: 锆石LA-ICP-MS U-Pb年龄和锡石LA-MC-ICP-MS U-Pb年龄证据[J]. 岩石学报, 2013, 29(4): 1223−1235.

    Google Scholar

    Ma N, Deng J, Wang Q F, et al. Geochronology of the Dasongpo tin deposit, Yunnan Province: Evidence from zircon LA-ICP-MS U-Pb ages and cassiterite LA-MC-ICP-MS U-Pb age[J]. Acta Petrologica Sinica, 2013, 29(4): 1223−1235.

    Google Scholar

    [6] 王小娟, 刘玉平, 缪应理, 等. 都龙锡锌多金属矿床LA-MC-ICPMS锡石U-Pb测年及其意义[J]. 岩石学报, 2014, 30(3): 867−876.

    Google Scholar

    Wang X J, Liu Y P, Miao Y L, et al. In situ LA-MC-ICP-MS cassiterite U-Pb dating of Dulong Sn-Zn polymetallic deposit and its significance[J]. Acta Petrologica Sinica, 2014, 30(3): 867−876.

    Google Scholar

    [7] 徐斌, 蒋少涌, 罗兰. 江西彭山锡多金属矿集区尖峰坡锡矿床LA-MC-ICP-MS锡石U-Pb测年及其地质意义[J]. 岩石学报, 2015, 31(3): 701−708.

    Google Scholar

    Xu B, Jiang S Y, Luo L. LA-MC-ICP-MS U-Pb dating of cassiterite from the Jianfengpo Sn deposit in the Pengshan Sn-polymetallic ore field, Jiangxi Province and its geological significance[J]. Acta Petrologica Sinica, 2015, 31(3): 701−708.

    Google Scholar

    [8] Zhang R Q, Lu J J, Wang R C, et al. Constraints of in situ zircon and cassiterite U-Pb, molybdenite Re-Os and muscovite 40Ar-39Ar ages on multiple generations of granitic magmatism and related W-Sn mineralization in the Wangxianling area, Nanling Range, South China [J]. Ore Geology Reviews, 2015, 65: 1021−1042.

    Google Scholar

    [9] 熊峥嵘, 李信念, 祁程, 等. 锡石年代学和黑钨矿微量元素对湘东鸡冠石钨矿床的成因约束[J]. 岩石学报, 2021, 37(3): 769−780.

    Google Scholar

    Xiong Z R, Li X N, Qi C, et al. Geochronology of cassiterite and trace element compositions of wolframite: Contraints to the ore genisis of Jiguanshi tungsten deposite, Eastern Hunan Province[J]. Acta Geologica Sinica, 2021, 37(3): 769−780.

    Google Scholar

    [10] Zhao Z, Yang X Y, Li W Y, et al. Petrogenesis of the granite related to the Baishaziling Sn deposit, Dayishan ore field, Southern China[J]. Geochemistry, 2022, 82: 125873. doi: 10.1016/j.chemer.2022.125873

    CrossRef Google Scholar

    [11] Du Y, Lu Y Y, Zhang Z Z, et al. Indosinian magmatism and mineralization in the Banjiaoyuan tin deposit, middle Nanling Range, South China: Constraints from zircon and cassiterite U-Pb ages, geochemistry and Sr-Nd-Hf isotopic compositions[J]. Ore Geology Reviews, 2022, 151: 105190. doi: 10.1016/j.oregeorev.2022.105190

    CrossRef Google Scholar

    [12] Liu L, Xu G F, Lu Y Y, et al. Muscovite 40Ar-39Ar and cassiterite U-Pb dating of the Indosinian Aotou quartz-vein type tin deposit, Southern China and its geological significance[J]. Ore Geology Reviews, 2023, 158: 105516.

    Google Scholar

    [13] Zhang T F, Hou Z Q, Pan X F, et al. Cassiterite geochemistry and U-Pb geochronology of the Shihuiyao Rb-(Nb-Ta-Be-Sn) deposit, Northeast China: Implication for ore-forming processes and mineral exploration[J]. Ore Geology Reviews, 2023, 156: 105393. doi: 10.1016/j.oregeorev.2023.105393

    CrossRef Google Scholar

    [14] 黄层, 袁顺达, 赵盼捞. 南岭地区双园冲锡矿成岩成矿时代及其对柿竹园—荷花坪地区锡钨找矿的指示[J]. 岩石学报, 2023, 39(6): 1717−1729. doi: 10.18654/1000-0569/2023.06.08

    CrossRef Google Scholar

    Huang C, Yuan S D, Zhao P L, et al. Geochronology of granite and associated Sn mineralization in the Shuangyuanchong Sn deposit and its implication for Sn-W prospecting potential in the Shizhuyuan—Hehuaping area, the Nanling region, South China[J]. Acta Geologica Sinica, 2023, 39(6): 1717−1729. doi: 10.18654/1000-0569/2023.06.08

    CrossRef Google Scholar

    [15] 周红英, 耿建珍, 崔玉荣, 等. 磷灰石微区原位LA-MC-ICP-MS U-Pb同位素定年[J]. 地球学报, 2012, 33(6): 857−864. doi: 10.3975/cagsb.2012.06.03

    CrossRef Google Scholar

    Zhou H Y, Geng J Z, Cui Y R, et al. In situ U-Pb dating of apatite using LA-MC-ICP-MS[J]. Acta Geoscientica Sinica, 2012, 33(6): 857−864. doi: 10.3975/cagsb.2012.06.03

    CrossRef Google Scholar

    [16] 崔玉荣, 涂家润, 陈枫, 等. LA-(MC)-ICP-MS锡石U-Pb定年研究进展[J]. 地质学报,2017, 91(6): 1386−1399.

    Google Scholar

    Cui Y R, Tu J R, Chen F, et al. The research advances in LA-(MC)-ICP-MS U-Pb dating of cassiterite[J]. Acta Geologica Sinica, 2017, 91(6): 1386−1399.

    Google Scholar

    [17] 崔玉荣, 肖志斌, 涂家润, 等. 氧化物型含铀矿物微区原位Hf 同位素分析技术研究进展[J]. 岩矿测试, 2022, 41(5): 691−703. doi: 10.15898/j.cnki.11-2131/td.202205180104

    CrossRef Google Scholar

    Cui Y R, Xiao Z B, Tu J R, et al. Processes in situ Hf isotopic analysis on oxide-type U-bearing accessory minerals[J]. Rock and Mineral Analysis, 2022, 41(5): 691−703. doi: 10.15898/j.cnki.11-2131/td.202205180104

    CrossRef Google Scholar

    [18] Tera F, Wasserburg G J. U-Th-Pb systematics in Three Apollo 14 basalts and the problem of initial Pb in Lunar rocks[J]. Earth and Planetary Science Letters, 1972, 14: 281−304. doi: 10.1016/0012-821X(72)90128-8

    CrossRef Google Scholar

    [19] Liu Y S, Gao S, Hu Z C, et al. Continental and oceanic crust recycling-induced melt-peridotite interactions in the Trans-North China Orogen: U-Pb dating, Hf isotopes and trace elements in zircons from mantle xenoliths[J]. Journal of Petrology, 2010, 51(1−2): 537−571. doi: 10.1093/petrology/egp082

    CrossRef Google Scholar

    [20] Vermeesch P. IsoplotR: A free and open toolbox for geochronology[J]. Geoscience Frontiers, 2018, 9(5): 1479−1493. doi: 10.1016/j.gsf.2018.04.001

    CrossRef Google Scholar

    [21] 张东亮, 彭建堂, 胡瑞忠, 等. 锡石U-Pb同位素体系的封闭性及其测年的可靠性分析[J]. 地质论评, 2011, 57(4): 549−554. doi: 10.16509/j.georeview.2011.04.014

    CrossRef Google Scholar

    Zhang D L, Peng J T, Hu R Z, et al. The closure of U-Pb isotope system in cassiterite and its reliability for dating[J]. Geological Reviews, 2011, 57(4): 549−554. doi: 10.16509/j.georeview.2011.04.014

    CrossRef Google Scholar

    [22] Carr P A, Norman M D, Bennett V C. Assessment of crystallographic orientation effects on secondary ion mass spectrometry (SIMS) analysis of cassiterite[J]. Chemical Geology, 2017, 467: 122−133. doi: 10.1016/j.chemgeo.2017.08.003

    CrossRef Google Scholar

    [23] Neymark L A, Holm-Denoma C S, Moscati R J, et al. In situ LA-ICPMS U-Pb dating of cassiterite without a known-age matrix matched reference material: Examples from worldwide tin deposits spanning the Proterozoic to the Tertiary[J]. Chemical Geology, 2018, 483: 410−425. doi: 10.1016/j.chemgeo.2018.03.008

    CrossRef Google Scholar

    [24] Nambaje C, Williams I S, Sajeev K. SHRIMP U-Pb dating of cassiterite: Insights into the timing of Rwandan tin mineralisation and associated tectonic processes[J]. Ore Geology Reviews, 2021, 135: 104185.

    Google Scholar

    [25] 朱艺婷, 李晓峰, 余勇, 等. 滇西松山锡矿锡石LA-SF-ICP-MS U-Pb 年代学及其对区域锡成矿作用的指示[J]. 岩石学报, 2021, 37(7): 2179−2188. doi: 10.18654/1000-0569/2021.07.12

    CrossRef Google Scholar

    Zhu Y T, Li X F, Yu Y, et al. LA-SF-ICP-MS U-Pb ages of cassiterite at the Songshan tin deposit and its implications for regional tin mineralisation, Western Yunnan[J]. Acta Petrologica Sinica, 2021, 37(7): 2179−2188. doi: 10.18654/1000-0569/2021.07.12

    CrossRef Google Scholar

    [26] Yang M, Romer R L, Yang Y H, et al. U-Pb isotopic dating of cassiterite: Development of reference materials and in situ applications by LA-SF-ICP-MS[J]. Chemical Geology, 2022, 593: 120754. doi: 10.1016/j.chemgeo.2022.120754

    CrossRef Google Scholar

    [27] 陈靖, 侯可军, 王倩, 等. 非基体匹配分馏校正的LA-ICP-MS锡石微区U-Pb定年方法研究[J]. 岩石学报, 2021, 37(3): 943−955. doi: 10.18654/1000-0569/2021.03.18

    CrossRef Google Scholar

    Chen J, Hou K J, Wang Q, et al. In situ U-Pb dating of cassiterite by LA-ICP-MS without a matrix-matched standard[J]. Acta Petrologica Sinica, 2021, 37(3): 943−955. doi: 10.18654/1000-0569/2021.03.18

    CrossRef Google Scholar

    [28] Tapster S, Bright J W G. High-precision ID-TIMS cassiterite U-Pb systematics using a low-contamination hydrothermal decomposition: Implications for LA-ICP-MS and ore deposit geochronology[J]. Geochronology, 2020, 2(2): 425−441. doi: 10.5194/gchron-2-425-2020

    CrossRef Google Scholar

    [29] Rizvanova N G, Kuznetsov A B. A new approach to ID-TIMS U-Pb dating of cassiterite by the example of the Pitkäranta tin deposit[J]. Doklady Earth Sciences, 2020, 491: 146−149. doi: 10.1134/S1028334X20030150

    CrossRef Google Scholar

    [30] 涂家润, 崔玉荣, 周红英, 等. 锡石U-Pb定年方法评述[J]. 地质调查与研究, 2019, 42(4): 245−253.

    Google Scholar

    Tu J R, Cui Y R, Zhou H Y, et al. Review of U-Pb dating methods for cassiterite[J]. Geological Survey and Research, 2019, 42(4): 245−253.

    Google Scholar

    [31] 涂家润, 周红英, 崔玉荣, 等. 磷灰石ID-TIMS高精度U-Pb定年方法[J]. 岩矿测试, 2024, 43(4): 533−545. doi: 10.15898/j.ykcs.202404170087

    CrossRef Google Scholar

    Tu J R, Zhou H Y, Cui Y R, et al. A high-precision ID-TIMS U-Pb dating method of apatite[J]. Rock and Mineral Analysis, 2024, 43(4): 533−545. doi: 10.15898/j.ykcs.202404170087

    CrossRef Google Scholar

    [32] 陈卫锋, 陈培荣, 周新民, 等. 湖南阳明山岩体的LA-ICP-MS锆石U-Pb定年及成因研究[J]. 地质学报, 2006, 80(7): 1065−1077. doi: 10.3321/j.issn:0001-5717.2006.07.013

    CrossRef Google Scholar

    Chen W F, Chen P R, Zhou X M, et al. Single-zircon LA-ICP-MS U-Pb dating of the Yangmingshan granitic pluton in Hunan, South China and its petrogenetic study[J]. Acta Geologica Sinica, 2006, 80(7): 1065−1077. doi: 10.3321/j.issn:0001-5717.2006.07.013

    CrossRef Google Scholar

    [33] 刘伟, 曾佐勋, 陈德立, 等. 湖南阳明山复式花岗岩的岩石成因: 锆石U-Pb年代学、地球化学及Hf同位素约束[J]. 岩石学报, 2014, 30(5): 1485−1504.

    Google Scholar

    Liu W, Zeng Z X, Chen D L, et al. Petrogenesis of the Yangmingshan composite granites in South Hunan Province: Contraints from geochemistry, zircon U-Pb geochronology and Hf isotope[J]. Acta Geologica Sinica, 2014, 30(5): 1485−1504.

    Google Scholar

    [34] 马丽艳, 刘树生, 付建明, 等. 湖南塔山、阳明山花岗岩的岩石成因: 来自锆石U-Pb年龄、地球化学及Sr-Nd同位素证据[J]. 地质学报, 2016, 90(2): 284−303. doi: 10.3969/j.issn.0001-5717.2016.02.007

    CrossRef Google Scholar

    Ma L Y, Liu S S, Fu J M, et al. Petrogenesis of the Tashan—Yangmingshan granitic batholiths: Constraint from zircon U-Pb age, geochemistry and Sr-Nd isotopes[J]. Acta Geologica Sinica, 2016, 90(2): 284−303. doi: 10.3969/j.issn.0001-5717.2016.02.007

    CrossRef Google Scholar

    [35] 李勇, 张岳桥, 苏金宝, 等. 湖南大义山、塔山岩体锆石U-Pb年龄及其构造意义[J]. 地球学报, 2015, 36(3): 303−312. doi: 10.3975/cagsb.2015.03.05

    CrossRef Google Scholar

    Li Y, Zhang Y Q, Su J B, et al. Zircon U-Pb dating of Dayishan and Tashan pluton in Hunan Province and its tectonic implications[J]. Acta Geoscientica Sinica, 2015, 36(3): 303−312. doi: 10.3975/cagsb.2015.03.05

    CrossRef Google Scholar

    [36] 郭爱民, 陈必河, 陈剑锋, 等. 湖南塔山花岗岩SHRIMP锆石U-Pb年龄及其地质意义[J]. 地质通报, 2017, 36(2/3): 459−465. doi: 10.3969/j.issn.1671-2552.2017.02.027

    CrossRef Google Scholar

    Guo A M, Chen B H, Chen J F, et al. SHRIMP zircon U-Pb age of Tashan granitic pluton from Hunan Province and its geological significance[J]. Geological Bulletin of China, 2017, 36(2/3): 459−465. doi: 10.3969/j.issn.1671-2552.2017.02.027

    CrossRef Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(3)

Tables(4)

Article Metrics

Article views(75) PDF downloads(7) Cited by(0)

Access History

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint