Research Progress on Elemental Speciation Analysis by Inductively Coupled Plasma-Mass Spectrometry Hyphenated Techniques

LIU Wei; HU Jun-dong; YANG Hong-xia; CHEN Jun-liang

doi:10.15898/j.cnki.11-2131/td.202006110089

2021 Vol. 40, No. 3

Article Contents

Article navigation > Rock and Mineral Analysis > 2021 > 40(3): 327-339

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LIU Wei, HU Jun-dong, YANG Hong-xia, CHEN Jun-liang. Research Progress on Elemental Speciation Analysis by Inductively Coupled Plasma-Mass Spectrometry Hyphenated Techniques[J]. Rock and Mineral Analysis, 2021, 40(3): 327-339. doi: 10.15898/j.cnki.11-2131/td.202006110089

Citation:

LIU Wei, HU Jun-dong, YANG Hong-xia, CHEN Jun-liang. Research Progress on Elemental Speciation Analysis by Inductively Coupled Plasma-Mass Spectrometry Hyphenated Techniques[J]. Rock and Mineral Analysis, 2021, 40(3): 327-339. doi: 10.15898/j.cnki.11-2131/td.202006110089

Research Progress on Elemental Speciation Analysis by Inductively Coupled Plasma-Mass Spectrometry Hyphenated Techniques

1.
National Research Center for Geoanalysis, Key Laboratory of Element Microareas and Speciation Analysis, China Geological Survey, Beijing 100037, China
2.
China Geological Survey, Beijing 100037, China
3.
Institute of Nuclear Safety, China Institute of Atomic Energy, Beijing 102413, China

Received Date: 11 June 2020

Revised Date: 21 December 2020

Accepted Date: 29 March 2021

Publish Date: 28 May 2021

Abstract

Abstract

BACKGROUND
As a highly sensitive analytical technique, ICP-MS has been widely used in the analysis of trace inorganic elements. Combined with chromatographic separation technology, it provides a powerful detection tool for elemental speciation analysis.
OBJECTIVES
To summarize the research progress of elemental speciation analysis by inductively coupled plasma mass spectrometry hyphenated techniques.
METHODS
The main methods of elemental speciation analysis by ICP-MS hyphenated techniques were summarized and compared. The methods included: (1) Gas chromatography coupled with ICP-MS (GC-ICP-MS). (2) Capillary electrophoresis coupled with ICP-MS (CE-ICP-MS). (3) Ion chromatography coupled with ICP-MS (IC-ICP-MS). (4) High performance liquid chromatography coupled with ICP-MS (HPLC-ICP-MS). The main application fields of elemental speciation analysis in China were biomedical field, food and drug safety monitoring and ecoenvironmental geochemistry.
RESULTS
GC-ICP-MS has high sensitivity and is suitable for volatile samples, its application is thus limited. CE-ICP-MS has fast analysis and high separation efficiency, but the limitation of sample injection volume makes the method detection limitation high. IC-ICP-MS mainly analyzes anions, cations and small molecular polar compounds. It is a useful complement to HPLC, but the mobile phase containing inorganic salts may block the sampling cone. HPLC-ICP-MS has been the most widely used technology in speciation analysis because of its wide application fields and simple technology.
CONCLUSIONS
Sample preparation research for complex matrices, preparing standard materials, and developing simultaneous multi-element speciation analysis methods are the research direction of elemental speciation analysis.
- GC-ICP-MS /
- CE-ICP-MS /
- IC-ICP-MS /
- HPLC-ICP-MS /
- hyphenated technique /
- elemental speciation

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References

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