Simultaneous Determination of Silver, Boron, Tin, Molybdenum and Lead in Geological Samples by Atomic Emission Spectrometer with Full Spectrum

Hai-bo HUANG; Jia-lin SHEN; Yu CHEN; Jian-kun LIU

doi:10.15898/j.cnki.11-2131/td.201909230137

2020 Vol. 39, No. 4

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Hai-bo HUANG, Jia-lin SHEN, Yu CHEN, Jian-kun LIU. Simultaneous Determination of Silver, Boron, Tin, Molybdenum and Lead in Geological Samples by Atomic Emission Spectrometer with Full Spectrum[J]. Rock and Mineral Analysis, 2020, 39(4): 555-565. doi: 10.15898/j.cnki.11-2131/td.201909230137

Citation:

Hai-bo HUANG, Jia-lin SHEN, Yu CHEN, Jian-kun LIU. Simultaneous Determination of Silver, Boron, Tin, Molybdenum and Lead in Geological Samples by Atomic Emission Spectrometer with Full Spectrum[J]. Rock and Mineral Analysis, 2020, 39(4): 555-565. doi: 10.15898/j.cnki.11-2131/td.201909230137

Simultaneous Determination of Silver, Boron, Tin, Molybdenum and Lead in Geological Samples by Atomic Emission Spectrometer with Full Spectrum

Nanjing Center of Geological Survey, China Geological Survey, Nanjing 210016, China

Received Date: 23 September 2019

Revised Date: 18 January 2020

Accepted Date: 24 April 2020

Abstract

Abstract

BACKGROUNDThe contents of silver, tin, boron, molybdenum, and lead in geological samples are extremely important for studying the metallogenic regularity and for geochemical prospecting. Current analytical methods rarely determine silver, tin, boron, molybdenum, and lead simultaneously. OBJECTIVESTo establish a method to simultaneously determine silver, tin, boron, molybdenum and lead in geological samples. METHODSTo eliminate the matrix interference, first-class standard materials (rock, soil and water sediments) were used for linear fitting of the synthetic silicate standard materials curve. By setting analytical line conversion values, different analytical line can be used for samples with different contents. RESULTSThe detection limits of silver, tin, boron, molybdenum, and lead were 0.0077μg/g, 0.19μg/g, 0.68μg/g, 0.058μg/g, 0.49μg/g, respectively. The precisions of the method were 3.23%-9.39%. The measured value of national first class standard materials including soil, water sediments and rock by this method was in accordance with standard values, with an absolute value of △logC < 0.10. The qualified rates of actual sample were 92%-98%, and the qualified rate of the inspection sample was 100%. CONCLUSIONSThis method is easy to apply and can be used to analyze samples rapidly. It can also be used to avoid contamination during sample dilution. Compared with traditional atomic emission spectrometry that uses a single analytical spectrum line, this method can be used to obtain a value which is closer to the standard value of national standard materials. The detection limit of this method is much lower than the standard value of the specification of testing quality management for geological laboratories.
- geological sample /
- metal and non-metal elements /
- full spectrum /
- atomic emission spectrometry /
- second fitting /
- analytical line conversion values

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References

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