Professional Committee of Rock and Mineral Testing Technology of the Geological Society of China, National Geological Experiment and Testing CenterHost
2018 Vol. 37, No. 3
Article Contents

Jin-mei FANG. Study on Pb Geochemical Characteristics of Soil and Rice in Longhai City, Fujian Province[J]. Rock and Mineral Analysis, 2018, 37(3): 327-335. doi: 10.15898/j.cnki.11-2131/td.201803070020
Citation: Jin-mei FANG. Study on Pb Geochemical Characteristics of Soil and Rice in Longhai City, Fujian Province[J]. Rock and Mineral Analysis, 2018, 37(3): 327-335. doi: 10.15898/j.cnki.11-2131/td.201803070020

Study on Pb Geochemical Characteristics of Soil and Rice in Longhai City, Fujian Province

  • BACKGROUND The distribution, migration and biological effects of lead in the red soil region of Southern China are still not clear. BAOBJECTIVES To study the soil and rice in Longhai city, Fujian Province, and systematically analyze the distribution characteristics, morphological composition, bioaccumulation ability and influencing mechanism of soil lead, and summarize the enrichment and distribution of lead in the parent rock-soil-rice migration process. METHODS The content of Pb in parent material and its speciation in top soil, as well as the content of Pb in rice was analyzed complying with a systemic sampling code for agro-ecology research. RESULTS The top soil in the central area of Longhai city has high lead content, and the remaining areas are relatively low. The 92.5% sample values range from 10 to 90 mg/kg, corresponding to a pH of 4.0 to 7.5, and the lead content in strongly acidic and alkaline soils is slightly lower. 4.1% of the rice lead (0.018-0.398 mg/kg) exceeded the standard, indicating that the rice has a weak soil lead enrichment capacity (enrichment coefficient 0.23%±0.16%). Therefore, rice in the study area may not necessarily exceed the standard when lead exceeds the standard. The main factors influencing soil lead are soil-forming parent rocks and soil types. The rules of soil lead content in different parent-rock areas are Quaternary marine sediments > Quaternary residual sediments > Granite and acid volcanic rocks > Fotan Formation basic basalt. The rules of lead content in different soil types were fluvo-aquic > coastal saline soil > paddy soil > red soil > red soil > coastal aeolian sandy soil. CONCLUSIONS The soil lead availability status (ion-exchange state, water-soluble state) accounted for only 4.95% of the total lead, and the strong organic state and residual state accounted for 94.99% of the total, indicating that soil lead exists mainly in a stable state and is difficult to be absorbed by plants. This provides investigation basis for reasonable interpretation of the phenomenon that the soil exceeds the standard lead and the rice does not exceed the standard. The study also showed that there is no significant correlation between rice lead and surface soil lead, and maintaining soil pH in the weakly acidic to weakly alkaline range can reduce soil lead activity.
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  • [1] 崔邢涛, 秦振宇, 栾文楼, 等.河北省保定市平原区土壤重金属污染及潜在生态危害评价[J].现代地质, 2014, 24(3):523-530.

    Google Scholar

    Cui X T, Qin Z Y, Luan W L, et al.Assessment of heavy metal pollution ecological hazard in soil of plain area of Baoding city of Hebei Province[J].Geoscience, 2014, 24(3):523-530.

    Google Scholar

    [2] 晏星, 罗娜娜, 赵文吉, 等.北京城区交通边缘带土壤重金属污染研究[J].环境科学与技术, 2013, 36(12):175-180.

    Google Scholar

    Yan X, Luo N N, Zhao W J, et al.Heavy metal pollution evaluation and spatial influence range analysis for main roads within the fifth ring road of Beijing urban[J].Environmental Science & Technology, 2013, 36(12):175-180.

    Google Scholar

    [3] 何剪太, 朱轩仪, 巫放明, 等.铅中毒和驱铅药物的研究进展[J].中国现代医学杂志, 2017, 27(14):53-57. doi: 10.3969/j.issn.1005-8982.2017.14.011

    CrossRef Google Scholar

    He J T, Zhu X Y, Wu F M, et al.Research progress on lead poisoning and development of deleading reagents[J].China Journal of Modern Medicine, 2017, 27(14):53-57. doi: 10.3969/j.issn.1005-8982.2017.14.011

    CrossRef Google Scholar

    [4] Tóth G, Hermann T, da Silva M R, et al.Heavy metals in agricultural soils of the European Union with implications for food safety open access[J].Environment International, 2016, 88:299-309. doi: 10.1016/j.envint.2015.12.017

    CrossRef Google Scholar

    [5] Parnia A, Chakravartty D, Wiseman C L S, et al.Environmental factors associated with blood lead among newcomer women from South and East Asia in the Greater Toronto Area[J].Science of the Total Environment, 2018, 624:558-566. doi: 10.1016/j.scitotenv.2017.11.336

    CrossRef Google Scholar

    [6] Specht A J, Lin Y F, Xu J, et al.Bone lead levels in an environmentally exposed elderly population in Shanghai, China short communication[J].Science of the Total Environment, 2018, 626:96-98. doi: 10.1016/j.scitotenv.2018.01.091

    CrossRef Google Scholar

    [7] 周国华.土壤重金属生物有效性研究进展[J].物探与化探, 2014, 38(6):1097-1106. doi: 10.11720/wtyht.2014.6.01

    CrossRef Google Scholar

    Zhou G H.Recent progress in the study of heavy metal bioavailability in soil[J].Geophysical and Geochemical Exploration, 2014, 38(6):1097-1106. doi: 10.11720/wtyht.2014.6.01

    CrossRef Google Scholar

    [8] 钟晓兰, 周生路, 黄明丽, 等.土壤重金属的形态分布特征及其影响因素[J].生态环境学报, 2009, 18(4):1266-1273.

    Google Scholar

    Zhong X L, Zhou S L, Huang M L, et al.Chemical form distribution characteristics of soil heavy metals and its influencing factors[J].Ecology and Environmental Sciences, 2009, 18(4):1266-1273.

    Google Scholar

    [9] 廉梅花, 孙丽娜, 王辉, 等.沈阳细河流域土壤和作物中汞的潜在生态危害及健康风险评价[J].生态毒理学报, 2014, 9(5):916-923.

    Google Scholar

    Lian M H, Sun L N, Wang H, et al.Assessment of potential ecological and health risk of mercury in soils and plants along Xi River watershed in Shenyang[J].Asian Journal of Ecotoxicology, 2014, 9(5):916-923.

    Google Scholar

    [10] 刘建国, 李坤权, 张祖建, 等.水稻不同品种对Pb的吸收分配的差异及机理[J].应用生态学报, 2004, 15(2):291-294.

    Google Scholar

    Liu J G, Li K Q, Zhang Z J, et al.Difference of lead uptake and distribution in rice cultivars and its mechanism[J].Chinese Journal of Applied Ecology, 2004, 15(2):291-294.

    Google Scholar

    [11] 邹紫今, 周航, 吴玉俊, 等.羟基磷灰石+沸石对稻田土壤中铅镉有效性及糙米中铅镉累积的影响[J].农业环境科学学报, 2016, 35(1):45-52. doi: 10.11654/jaes.2016.01.006

    CrossRef Google Scholar

    Zou Z J, Zhou H, Wu Y J, et al.Effects of hydroxyapatite plus zeolite on bioavailability and rice bioaccumulation of Pb and Cd in soils[J].Journal of Agro-Environment Science, 2016, 35(1):45-52. doi: 10.11654/jaes.2016.01.006

    CrossRef Google Scholar

    [12] 冯莲莲, 郭京霞, 黄梓璨, 等.水稻土中7个水稻品种对土壤Cd、Pb的富集与转运:田间研究[J].生态环境学报, 2017, 26(12):2146-2153.

    Google Scholar

    Feng L L, Guo J X, Huang Z C, et al.A field study on the accumulation and translocation of cadmium and lead from a contaminated paddy rice field by seven rice cultivars[J].Ecology and Environmental Sciences, 2017, 26(12):2146-2153.

    Google Scholar

    [13] Levonmäki M, Hartikainen H.Efficiency of liming in controlling the mobility of lead in shooting range soils as assessed by different experimental approaches[J].Science of the Total Environment, 2007, 388:1-7. doi: 10.1016/j.scitotenv.2007.07.055

    CrossRef Google Scholar

    [14] 成杭新, 赵传冬, 庄广民, 等.太湖流域土壤重金属元素污染历史的重建:以Pb、Cd为例[J].地学前缘, 2008, 15(5):167-178.

    Google Scholar

    Cheng H X, Zhao C D, Zhuang G M, et al.Reconstruction of the regional soil pollution history by heavy metals in Taihu Lake drainage area:Taking Pb and Cd as examples[J].Earth Science Frontiers, 2008, 15(5):167-178.

    Google Scholar

    [15] 蔡奎, 段亚敏, 栾文楼, 等.河北平原农田土壤重金属元素Pb、Hg地球化学行为的影响因素[J].中国地质, 2016, 43(4):1420-1428.

    Google Scholar

    Cai K, Duan Y M, Luan W L, et al.Geochemical behavior of heavy metals Pb and Hg in the farmland soil of Hebei Plain[J].Geology in China, 2016, 43(4):1420-1428.

    Google Scholar

    [16] 余涛, 杨忠芳, 钟坚, 等.土壤中重金属元素Pb、Cd地球化学行为影响因素研究[J].地学前缘, 2008, 15(5):67-73.

    Google Scholar

    Yu T, Yang Z F, Zhong J, et al.Factors affecting the geochemical behavior of heavy metal elements Pb and Cd in soil[J].Earth Science Frontiers, 2008, 15(5):67-73.

    Google Scholar

    [17] 赵庆令, 李清彩, 谢江坤, 等.应用富集系数法和地累积指数法研究济宁南部区域土壤重金属污染特征及生态风险评价[J].岩矿测试, 2015, 34(1):129-137.

    Google Scholar

    Zhao Q L, Li Q C, Xie J K, et al.Characteristics of soil heavy metal pollution and its ecological risk assessment in South Jining district using methods of enrichment factor and index of geoaccumulation[J].Rock and Mineral Analysis, 2015, 34(1):129-137.

    Google Scholar

    [18] Kushwaha A, Hans N, Kumar S, et al.A critical review on speciation, mobilization and toxicity of lead in soil-microbe-plant system and bioremediation strategies[J].Ecotoxicology and Environmental Safety, 2018, 147:1035-1045. doi: 10.1016/j.ecoenv.2017.09.049

    CrossRef Google Scholar

    [19] 王腾云, 周国华, 孙彬彬, 等.福建沿海地区土壤-稻谷重金属含量关系与影响因素研究[J].岩矿测试, 2016, 35(3):295-301.

    Google Scholar

    Wang T Y, Zhou G H, Sun B B, et al.The relationship between heavy metal contents of soils and rice in coastal areas, Fujian Province, including influencing factors[J].Rock and Mineral Analysis, 2016, 35(3):295-301.

    Google Scholar

    [20] Usiyama T, Fukushi K.Predictive model for Pb(Ⅱ) adsorption on soil minerals (oxides and low-crystalline aluminum silicate) consistent with spectroscopic evidence[J].Geochimica et Cosmochimica Acta, 2016, 190:134-155. doi: 10.1016/j.gca.2016.06.022

    CrossRef Google Scholar

    [21] 李艳艳, 王亚平, 周继华, 等.土壤中Pb离子地球化学——以山西的典型土壤为例[J].地质通报, 2008, 27(2):230-239.

    Google Scholar

    Li Y Y, Wang Y P, Zhou J H, et al.Simulation experiment of the geochemical behavior of Pb in soils-A case study of typical soils in Shanxi, China[J].Geological Bulletin of China, 2008, 27(2):230-239.

    Google Scholar

    [22] Veeresh H, Tripathy S, Chaudhuri D, et al.Sorption and distribution of adsorbed metals in three soils of India[J].Applied Geochemistry, 2003, 18:1723-1731. doi: 10.1016/S0883-2927(03)00080-5

    CrossRef Google Scholar

    [23] 杨海欧, 王长城, 李文杰, 等.基于微量元素比值分析方法研究川东南地区小河坝组沉积环境和古气候环境[J].岩矿测试, 2017, 36(3):289-296.

    Google Scholar

    Yang H O, Wang C C, Li W J, et al.Research on the sedimentary and paleoclimate environment of the Xiaoheba Formation in Southeastern Sichuan based on the trace elements ratio method[J]. Rock and Mineral Analysis, 2017, 36(3):289-296.

    Google Scholar

    [24] 蔡奎, 张蒨, 吴云霞, 等.河北平原农田土壤重金属形态分布特征及控制因素研究[J].生态毒理学报, 2017, 12(2):155-168. doi: 10.7524/AJE.1673-5897.20160321010

    CrossRef Google Scholar

    Cai K, Zhang Q, Wu Y X, et al.Speciation distribution and its influencing factors of Cd, Cr, Pb, As, Hg in farm land soil from Heibei Plain, China[J].Asian Journal of Ecotoxicology, 2017, 12(2):155-168. doi: 10.7524/AJE.1673-5897.20160321010

    CrossRef Google Scholar

    [25] 关天霞, 何红波, 张旭东, 等.土壤中重金属元素形态分析方法及形态分布的影响因素[J].土壤通报, 2011, 42(2):503-512.

    Google Scholar

    Guan T X, He H B, Zhang X D, et al.The methodology of fractionation analysis and the factors affecting the species of heavy metals in soil[J].Chinese Journal of Soil Science, 2011, 42(2):503-512.

    Google Scholar

    [26] 林琦, 陈怀满, 郑春荣, 等.根际环境中铅的形态转化[J].应用生态学报, 2002, 13(9):1145-1149.

    Google Scholar

    Lin Q, Chen H M, Zheng C R, et al.Conformation transformation of lead in rhizosphere[J].Chinese Journal of Applied Ecology, 2002, 13(9):1145-1149.

    Google Scholar

    [27] 李玉双, 孙丽娜, 王洪.农作物对污染土壤中及其植物有效性的影响[J].农业环境科学学报, 2006, 25(增刊):487-491.

    Google Scholar

    Li Y S, Sun L N, Wang H.Relativity between available and total Cu concentrations in soils under non-continuous spatial-temporally statistic conditions[J].Journal of Agro-Environment Science, 2006, 25(Supplement):487-491.

    Google Scholar

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