Citation: | WEI Qingcheng, WANG Haoxiang, SU Chao, LIU Dianwen, SHEN Peilun, WANG Han. Synthesis and Flotation Experimental Study of DX−2 Activator for a Refractory Oxidized Copper Mine[J]. Conservation and Utilization of Mineral Resources, 2023, 43(5): 25-31. doi: 10.13779/j.cnki.issn1001-0076.2023.07.007 |
Copper oxide ore is an important copper resource in China. In recent years, the easily treatable copper minerals have been decreasing annually. Therefore, the efficient enrichment of copper oxide ore is of great significance for copper resources. Due to the fine particle size and high mud content of existing copper oxide ores, it is difficult to separate from gangue minerals. Thus, it is unable to achieve beneficiation indicators using conventional activators for treatment. Based on 2,5−dithiophenol−1,3,4−thiodiazole, a new high−efficiency copper oxide mineral activator, DX−2, was synthesized through a one-pot method. Flotation test results showed that, for the refractory oxidized copper ore with a copper content of 1.23% and an oxidation rate of 90.24%, utilizing DX−2 as the activator, sodium sulfide as the sulfurizer, amyl xanthate and sodium alkyl hydroxamate as collectors, at pH 8, with terpineol as a frother, yielded a copper concentrate with a grade of 18.37% and a recovery rate of 82.59%. These experimental researches introduce a new technical approach for the efficient flotation of refractory copper oxide ores.
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Chemical reactions principles of DMTD synthesis
Isomer of DMTD
Polymerization and depolymerization reactions of DMTD
Infrared spectrometry of DX−2
Flow chart of activator type test
Effect of activator type on grade and recovery of concentrate
Test results of sodium sulfide dosage
Results of activator DX−2 dosage
Results of amyl xanthate dosage
Flow chart of open circuit
Flow chart of closed circuit test