Research Progress on Activation Mechanism of Typical Metal Ions on Mineral Flotation

YU Anmei; DING Zhan; LI Jie; YUAN Jiaqiao; BAI Shaojun

doi:10.13779/j.cnki.issn1001-0076.2023.04.013

2023 Vol. 43, No. 4

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Article navigation > Conservation and Utilization of Mineral Resources > 2023 > 43(4): 114-122

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YU Anmei, DING Zhan, LI Jie, YUAN Jiaqiao, BAI Shaojun. Research Progress on Activation Mechanism of Typical Metal Ions on Mineral Flotation[J]. Conservation and Utilization of Mineral Resources, 2023, 43(4): 114-122. doi: 10.13779/j.cnki.issn1001-0076.2023.04.013

Citation:

YU Anmei, DING Zhan, LI Jie, YUAN Jiaqiao, BAI Shaojun. Research Progress on Activation Mechanism of Typical Metal Ions on Mineral Flotation[J]. Conservation and Utilization of Mineral Resources, 2023, 43(4): 114-122. doi: 10.13779/j.cnki.issn1001-0076.2023.04.013

Research Progress on Activation Mechanism of Typical Metal Ions on Mineral Flotation

1.
Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
2.
State Key Laboratory of Clean Utilization of Complex Nonferrous Metals, Yunnan Kunming 650093, Yunnan, China

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Corresponding author: BAI Shaojun, baishaojun830829@126.com

Received Date: 21 April 2023

Publish Date: 25 August 2023

Abstract

Abstract

This paper analyzes the effects of typical metal ions (Pb²⁺, Cu²⁺, Ca²⁺, Fe³⁺ and Al³⁺) on the flotation behaviors of minerals and corresponding mechanism. Meanwhile, the merits and demerits of these metal ions on the activation of minerals are reviewed in details. Besides, the activated ability of above-mentioned metal ions on minerals flotation behaviors is analyzed. It is advisable to strengthen the basic theory of the activation mechanism of metal ions and to develop new green activators of metal ions in the future research of this field. Thus, the present paper provides some references for the development of new activators for mineral flotation.
- metal ions /
- mineral flotation /
- activation mechanism /
- ability of activation

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References

[1]	WANG L, SUN W, HU Y H, et al. Adsorption mechanism of mixed anionic/cationic collectors in muscovite–quartz flotation system[J]. Minerals Engineering, 2014, 64: 44−50. doi: 10.1016/j.mineng.2014.03.021 CrossRef Google Scholar
[2]	KOU J, XU S, SUN T, et al. A study of sodium oleate adsorption on Ca²⁺ activated quartz surface using quartz crystal microbalance with dissipation[J]. International Journal of Mineral Processing, 2016, 154: 24−34. doi: 10.1016/j.minpro.2016.06.008 CrossRef Google Scholar
[3]	LIU B, WANG X M, H. DU H, et al. The surface features of lead activation in amyl xanthate flotation of quartz[J]. International Journal of Mineral Processing, 2016, 151: 33−39. doi: 10.1016/j.minpro.2016.04.004 CrossRef Google Scholar
[4]	FORNASIERO D, J. Ralston. Cu(Ⅱ) and Ni(Ⅱ) activation in the flotation of quartz, lizardite and chlorite[J]. International Journal of Mineral Processing, 2005, 76: 75−81. doi: 10.1016/j.minpro.2004.12.002 CrossRef Google Scholar
[5]	HUANG Y Q, YIN W Z, DENG R D, et al. Strengthening sulfidation flotation of hemimorphite via pretreatment with Pb²⁺[J]. Minerals, 2019, 9(8): 463. doi: 10.3390/min9080463 CrossRef Google Scholar
[6]	盛洁, 刘全军, 董敬申, 等. 典型金属离子对黄铜矿浮选效果的影响研究进展[J]. 应用化工, 2022, 51(2): 557−562. Google Scholar SHENG J, LIU Q J, DONG J S, et al. Research progress on the effect of typical metal ions on chalcopyrite flotation[J]. Applied Chemical Industry, 2022, 51(2): 557−562. Google Scholar
[7]	PENG H. Q, LUO W, BIE X X, et al. Study on the effect of Fe³⁺ on zircon flotation separation from cassiterite using sodium oleate as collector[J]. Minerals, 2017, 7: 18. Google Scholar
[8]	高跃升, 高志勇, 孙伟. 金属离子对矿物浮选行为的影响及机理研究进展[J]. 中国有色金属学报, 2017, 27(4): 859−868. Google Scholar GAO Y S, GAO Z Y, SUN W. Research progress of influence of metal ions on mineral flotation behavior and underlying mechanism[J]. The Chinese Journal of Nonferrous Metals, 2017, 27(4): 859−868. Google Scholar
[9]	周瑜林, 王毓华, 胡岳华, 等. 金属离子对一水硬铝石和高岭石浮选行为的影响[J]. 中南大学学报(自然科学版), 2009, 40(2): 268−274. Google Scholar ZHOU Y M, WANG Y H, HU Y H, et al. Influence of metal ions on floatability of diaspore and kaolinite[J]. Journal of Central South University (Science and Technology), 2009, 40(2): 268−274. Google Scholar
[10]	王亮, 李育彪, 李万青. 不同价态杂质离子对黄铜矿浮选的影响机理研究[J]. 金属矿山, 2018(12): 84−88. Google Scholar WANG L, LI Y B, LI W Q. Influencing mechanism of ions with different valence on chalcopyrite flotation[J]. Metal Mine, 2018(12): 84−88. Google Scholar
[11]	WANG B, PENG Y J. The interaction of clay minerals and saline water in coarse coal flotation[J]. Fuel, 2014, 134: 326−332. doi: 10.1016/j.fuel.2014.05.085 CrossRef Google Scholar
[12]	LI G S, DENG L J, CAO Y J, et al. Effect of sodium chloride on fine coal flotation and discussion based on froth stability and particle coagulation[J]. International Journal of Mineral Processing, 2017, 169: 47−52. doi: 10.1016/j.minpro.2017.10.008 CrossRef Google Scholar
[13]	LI Y B, LI W Q, XIAO Q, et al. The influence of common monovalent and divalent chlorides on chalcopyrite flotation[J]. Minerals, 2017, 7(7): 111−111. doi: 10.3390/min7070111 CrossRef Google Scholar
[14]	王淀佐, 胡岳华. 浮选溶液化学[M]. 长沙: 湖南科学技术出版社, 1988.35. WANG D Z, HU Y H. Flotation solution chemistry[M]. Changsha: Hunan Science and Technology Press, 1988.35. Google Scholar
[15]	王雪伟. 极硬水对煤泥浮选的影响研究[D]. 北京: 中国矿业大学, 2015 Google Scholar WANG X W. Research on the effect of extremely hard water on slime flotation[D]. Beijing: China University of Mining and Technology, 2015. Google Scholar
[16]	付鹏, 李解, 李保卫, 等. 某选矿厂工业回水中离子对黄铁矿浮选的影响机制[J]. 稀有金属, 2017, 41(7): 792−798. Google Scholar FU P, LI J, LI B W, et al. Influence mechanism of ions in industry backwater of concentrator on floatability of pyrite[J]. Chinese Journal of Rare Metals, 2017, 41(7): 792−798. Google Scholar
[17]	CASTRO S, MIRANDA CToledo P, et al. Effect of frothers on bubble coalescence and foaming in electrolyte solutions and seawater[J]. International Journal of Mineral Processing, 2013, 124: 8−14. doi: 10.1016/j.minpro.2013.07.002 CrossRef Google Scholar
[18]	SERGIO C, LASKOWSKI JS. Froth flotation in saline water[J]. KONA Powder and Particle Journal, 2011, 29: 4−15. doi: 10.14356/kona.2011005 CrossRef Google Scholar
[19]	ROWSON X. The effect of Pb(NO₃)₂ on ilmenite flotation[J]. Minerals Engineering, 2000(2): 205−215. Google Scholar
[20]	YU L, XIN Y, YUAN Z T, et al. Effect of lead ions on the selective flotation of ilmenite against titanaugite using octyl hydroxamic acid as collector[J]. Applied Surface Science, 2022, 603: 154458. Google Scholar
[21]	FENG Q C, WANG M L, ZHANG G, et al. Enhanced adsorption of sulfide and xanthate on smithsonite surfaces by lead activation and implications for flotation intensification[J]. Separation and Purification Technology, 2023, 307. Google Scholar
[22]	YAO W, LI M L, ZHANG M, et al. Effects of Pb²⁺ ions on the flotation behavior of scheelite, calcite, and fluorite in the presence of water glass[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 636: 127826. Google Scholar
[23]	LIU C, ZHANG C, SONG S X, et al. Study on the activation mechanism of lead ions in wolframite flotation using benzyl hydroxamic acid as the collector[J]. Minerals Engineering, 2019, 141: 105859. Google Scholar
[24]	FANG S, XU L H, WU H Q, et al. Adsorption of Pb(Ⅱ)/benzohydroxamic acid collector complexes for ilmenite flotation[J]. Minerals Engineering, 2018, 126: 16−23. Google Scholar
[25]	卫召, 韩海生, 胡岳华, 等. Pb-BHA配位捕收剂的黑白钨混合常温浮选研究[J]. 有色金属工程, 2017, 7(6): 70-75 Google Scholar WEI Z, HAN H S, HU Y H, et al. Flotation of wolframite and scheelite at the room temperature based on Pb-BHA coordination collector[J]. Nonferrous Metals Engineering, 2017, 7(6): 70-75. Google Scholar
[26]	黄伟生, 徐涛, 韩海生, 等. 苯甲羟肟酸铅体系与脂肪酸体系钨矿浮选原理及其应用[J]. 金属矿山, 2019(8): 63−70. Google Scholar HUANG W S, XU T, HAN H S, et al. Fatty acid flotation versus BHA flotation of tungsten minerals and their performance in flotation practice[J]. Metal Mine, 2019(8): 63−70. Google Scholar
[27]	LI H Q, MU S X, WENG X Q, et al. Rutile flotation with Pb²⁺ ions as activator: adsorption of Pb²⁺ at rutile/water interface[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 2016, 506: 431−437. doi: 10.1016/j.colsurfa.2016.06.046 CrossRef Google Scholar
[28]	FENG Q C, ZHAO W J, WEN S M, et al. Activation mechanism of lead ions in cassiterite flotation with salicylhydroxamic acid as collector[J]. Separation and Purification Technology, 2017, 178: 193−199. doi: 10.1016/j.seppur.2017.01.053 CrossRef Google Scholar
[29]	欧乐明, 黄思捷, 朱阳戈. 硫化矿浮选体系中金属离子对石英浮选行为的影响[J]. 中南大学学报(自然科学版), 2012, 43(2): 407−411. Google Scholar OU L M, HUANG S J, ZHU Y G. Influence of metal ions on floatability of quartz in flotation of sulfide ores[J]. Journal of Central South University (Science and Technology), 2012, 43(2): 407−411. Google Scholar
[30]	欧乐明, 曾维伟, 冯其明, 等. Zn²⁺、Cu²⁺对菱锌矿和石英浮选的影响及作用机理[J]. 有色金属(选矿部分), 2011(5): 53−57. Google Scholar OU L M, ZENG W W, FENG Q M, et al. Influence and mechanism of zine and copper ion on flotation of smithsonite and quarte[J]. Nonferrous Metals(Minerals Processing Section), 2011(5): 53−57. Google Scholar
[31]	TRAHAR W J, SENIOR G D, HEYES G W, et al. The activation of sphalerite by lead — a flotation perspective[J]. International Journal of Mineral Processing, 1997, 49: 121−148. doi: 10.1016/S0301-7516(96)00041-5 CrossRef Google Scholar
[32]	黄裕卿, 邓荣东, 印万忠, 等. 黄药体系下铅离子诱导异极矿强化硫化浮选及其机理[J]. 中国有色金属学报, 2020, 30(9): 2224−2233. doi: 10.11817/j.ysxb.1004.0609.2020-35857 CrossRef Google Scholar HUANG Y Q, DENG R D, YING W Z, et al. Lead ions induced strengthening sulfidation-flotation of hemimorphite in xanthate system and its mechanism[J]. The Chinese Journal of Nonferrous Metals, 2020, 30(9): 2224−2233. doi: 10.11817/j.ysxb.1004.0609.2020-35857 CrossRef Google Scholar
[33]	张国范, 张凤云. 浮选过程中金属离子对异极矿硫化的影响[J]. 中南大学学报(自然科学版), 2017, 48(7): 1689−1696. Google Scholar ZHANG G F, ZHANG F Y. Effect of metal ions on sulfiding flotation of hemimorphite[J]. Journal of Central South University of Science and Technology, 2017, 48(7): 1689−1696. Google Scholar
[34]	邹坚坚. 富银铅锌矿浮选分离试验研究[D]. 长沙: 中南大学, 2013 Google Scholar ZOU J J. Research on the flotation separation of rich sliver lead-zine ore[D]. Changsha: Central South University, 2013. Google Scholar
[35]	RALSTON J, HEALY T W. Activation of zinc sulphide with CuⅡ, CdⅡ and PbⅡ: I activation in weakly acidic media[J]. International Journal of Mineral Processing, 1980, 7(3): 175−201. doi: 10.1016/0301-7516(80)90016-2 CrossRef Google Scholar
[36]	POPOV S R, VUINI D R, STROJEK J W, et al. Effect of dissolved lead ions on the ethylxanthate adsorption on sphalerite in weakly acidic media[J]. International Journal of Mineral Processing, 1989, 27(1/2): 51−62. doi: 10.1016/0301-7516(89)90005-7 CrossRef Google Scholar
[37]	HOUOT R, RAVENEAU P. Activation of sphalerite flotation in the presence of lead ions[J]. International Journal of Mineral Processing, 1992, 35(3/4): 253−271. doi: 10.1016/0301-7516(92)90037-W CrossRef Google Scholar
[38]	LIU J, EJTEMAEI M, NGUYEN A V, et al. Surface chemistry of pb-activated sphalerite[J]. Minerals Engineering, 2020, 145: 106058−106058. doi: 10.1016/j.mineng.2019.106058 CrossRef Google Scholar
[39]	唐箫琴, 刘小妹, 陈晔. 闪锌矿表面铅活化及黄药吸附的密度泛函理论研究[J]. 有色金属工程, 2021(11): 90−95. Google Scholar TANG X Q, LIU X M, CHEN Y. CHEN Y. Density function theory(DFT) study on lead activation and adsorption on sphalerite surface[J]. Nonferrous Metals Engineering, 2021(11): 90−95. Google Scholar
[40]	FUERSTENAU M C, HAN K N. Metal-surfactant precipitation and adsorption in froth flotation[J]. Journal of Colloid and Interface Science, 2002, 256: 175−182. doi: 10.1006/jcis.2001.8089 CrossRef Google Scholar
[41]	王淀佐, 胡岳华. 氢氧化物表面沉淀在石英浮选中的作用[J]. 中南矿冶学院学报, 1990(3): 248−253. Google Scholar WANG D Z, HU Y H. The investigation of role of surface precipitation of meta hydroxide in flotation of quartz[J]. Journal of Central South University, 1990(3): 248−253. Google Scholar
[42]	HAN H S, LIU W I, HU Y H, et al. A novel flotation scheme: selective flotation of tungsten minerals from calcium minerals using Pb–BHA complexes in shizhuyuan[J]. Rare Metals, 2017, 36(6): 533−540. doi: 10.1007/s12598-017-0907-8 CrossRef Google Scholar
[43]	宫贵臣, 刘杰, 韩跃新, 等. 铜离子对锡石浮选的影响及其机理研究[J]. 金属矿山, 2019(2): 102−105. Google Scholar GONG G C, LIU J, HAN Y X, et al. Study on the effect and mechanism of Cu²⁺ on cassiterite flotation[J]. Metal Mine, 2019(2): 102−105. Google Scholar
[44]	汪泰, 刘殿文, 王成行, 等. 水杨羟肟酸体系下铜离子活化浮选锡石作用机制[J]. 中国有色金属学报, 2022 Google Scholar WANG T, LIU D W, WANG C H, et al. Mechanism of activated flotation of cassiterite by copper ion in salicylhydroxamic acid system[J]. Chinese Journal of Nonferrous Metals, 2022. Google Scholar
[45]	王宇斌, 文堪, 张鲁. 利用铜离子改善油酸钠体系下白云母的可浮性[J]. 矿产保护与利用, 2017(6): 45-51 Google Scholar WANG Y B, WEN K, ZHANG L. The floatability of muscovite in sodium oleate system was improved by copper ion[J] Conservation and Utilization of Mineral Resources, 2017(6): 45-51. Google Scholar
[46]	张波, 李解, 张雪峰, 等. Cu²⁺, Fe³⁺对萤石浮选的活化作用机制[J]. 稀有金属, 2016, 40(9): 963−968. Google Scholar ZHANG B, LI J, ZHANG X F, et al. Activation and mechanism of Cu²⁺ and Fe³⁺ in flotation system of fluorite ore[J]. Chinese Journal of Rare Metal, 2016, 40(9): 963−968. Google Scholar
[47]	DENG J S, WENG S M, LIU J, et al. Adsorption and activation of copper ions on chalcopyrite surfaces: A new viewpoint of self-activation[J]. Transactions of Nonferrous Metals Society of China, 2014, 24(12): 3955−3963. doi: 10.1016/S1003-6326(14)63556-1 CrossRef Google Scholar
[48]	邓久帅. 黄铜矿流体包裹体组分释放及其与弛豫表面的相互作用[D]. 昆明: 昆明理工大学, 2013 Google Scholar DENG J S. The release of chalcopyrite fluid inclusion components and their interaction with the relaxed surface[D]. Kunming: Kunming University of Science and Technology, 2013. Google Scholar
[49]	张芹, 胡岳华, 顾帼华, 等. 铁闪锌矿的浮选行为及其表面吸附机理[J]. 中国有色金属学报, 2004(4): 676−680. Google Scholar ZHANG Q, HU Y H, GU G H, et al. Mechanism of Cu²⁺ ion activation flotation of marmatite in absence and presence of ethyl xanthate[J]. Chinese Journal of Nonferrous Metals, 2004(4): 676−680. Google Scholar
[50]	FINKELSTEIN N P. The activation of sulphide minerals for flotation: a review[J]. International Journal of Mineral Processing, 1997, 52(2): 81−120. Google Scholar
[51]	BUCKLEY A N, SKINNER S L, HARMER S L, et al. Examination of the proposition that Cu(Ⅱ) can be required for charge neutrality in a sulfide lattice — Cu in tetrahedrites and sphalerite[J]. Canadian journal of Chemistry, 2007, 85(10): 767−781. doi: 10.1139/v07-078 CrossRef Google Scholar
[52]	余润兰, 邱冠周, 胡岳华, 等. Cu²⁺活化铁闪锌矿的电化学[J]. 金属矿山, 2004(2): 35−37+40. doi: 10.3321/j.issn:1001-1250.2004.02.011 CrossRef Google Scholar YU R L, QIU G Z, HU Y H, et al. Electrochemical activation of sphalerite by Cu²⁺[J]. Metal Mines, 2004(2): 35−37+40. doi: 10.3321/j.issn:1001-1250.2004.02.011 CrossRef Google Scholar
[53]	ZHOU C, YOON R H. Electrochemistry of copper activation of sphalerite at pH 9.2[J]. International Journal of Mineral Processing, 2000, 58(1): 57−66. Google Scholar
[54]	KARTIO I J, YOON R H, BASILIO C I. An XPS study of sphalerite activation by copper[J]. Langmuir: The ACS Journal of Surfaces and Colloids, 1998, 14(18): 5274−5278. doi: 10.1021/la970440c CrossRef Google Scholar
[55]	PRESTIDGE C A, THIEL A G, RALSTON J, et al. The interaction of ethyl xanthate with copper(Ⅱ)-activated zinc sulphide: kinetic effects[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects, 1994, 85(1): 51−68. Google Scholar
[56]	GERSON A R, LANGE A G, PRINCE K E, et al. The mechanism of copper activation of sphalerite[J]. Appl Surf Sci, 1999, 137(1): 207−223. Google Scholar
[57]	李佳磊, 宋凯伟, 刘殿文, 等. 闪锌矿浮选的活化与去活化研究进展[J]. 过程工程学报, 2018, 18(1): 11−19. Google Scholar LI J L, SONG G W, LIU D W, et al. Research progress on activation and deactivation of sphalerite flotation[J]. The Chinese Journal of Process Engineering, 2018, 18(1): 11−19. Google Scholar
[58]	张德文. 金属离子对铜蓝和黄铁矿浮选行为的影响[J]. 有色金属, 2018(3): 92−96. Google Scholar ZHANG D W. The effect of metal ions on the flotation behavior of copper blue and pyrite[J]. Nonferrous Metals, 2018(3): 92−96. Google Scholar
[59]	EJTEMAEI M, NGUYEN A V. Characterisation of sphalerite and pyrite surfaces activated by copper sulphate[J]. Minerals Engineering, 2017, 100: 223−232. doi: 10.1016/j.mineng.2016.11.005 CrossRef Google Scholar
[60]	WEISENER C, GERSON A. Cu(Ⅱ) adsorption mechanism on pyrite: an XAFS and XPS study[J]. Surface and Interface Analysis, 2000, 30(1): 454−458. doi: 10.1002/1096-9918(200008)30:1<454::AID-SIA807>3.0.CO;2-1 CrossRef Google Scholar
[61]	DAI P L, WEI Z C, CHEN L Z, et al. Adsorption of butyl xanthate on arsenopyrite (001) and Cu²⁺-activated arsenopyrite (001) surfaces: A DFT study[J]. Chemical Physics, 2022, 562. Google Scholar
[62]	ALBRECHT T, W. J, ALBRECHT, ADDAI-MENSAH J, et al. Critical copper concentration in sphalerite flotation: effect of temperature and collector[J]. International Journal of Mineral Processing, 2016, 146: 15-22. Google Scholar
[63]	CHANDRA A P, PUSKAR L, SIMPSON D J, et al. Copper and xanthate adsorption onto pyrite surfaces: Implications for mineral separation through flotation[J]. International Journal of Mineral Processing, 2012, 114/115/116/117: 16−26. doi: 10.1016/j.minpro.2012.08.003 CrossRef Google Scholar
[64]	陈琳璋, 侯清麟, 银锐明, 等. 钙离子影响十二烷基磺酸钠捕收石英的机理研究[J]. 湖南工业大学学报, 2012, 26(6): 8-12. Google Scholar CHEN L Z, HOU Q L , YIN R M, et al. The mechanism of calcium ions effects on quartz collection in the system of dodecyl sulphonate[J]. Journal of Hunan University of Technology, 2012, 26(6): 8-12. Google Scholar
[65]	张晋霞, 冯雅丽, 牛福生. 矿浆中金属离子对蓝晶石矿物浮选行为的影响[J]. 东北大学学报(自然科学版), 2014, 35(12): 1787−1791. doi: 10.12068/j.issn.1005-3026.2014.12.026 CrossRef Google Scholar ZHANG J X, FENG Y L, NIU F S. Influence of metal ions in pulp on floatability of kyanite minerals[J]. Journal of Northeastern University. Natural Science, 2014, 35(12): 1787−1791. doi: 10.12068/j.issn.1005-3026.2014.12.026 CrossRef Google Scholar
[66]	HUANG W X, LIU W B, ZHONG W L, et al. Effects of common ions on the flotation of fluorapatite and dolomite with oleate collector[J]. Minerals Engineering, 2021, 174: 107213. Google Scholar
[67]	DáVILA-PULIDO I G, URIBE-SALAS A, áLVAREZ-SILVA METAL. The role of calcium in xanthate adsorption onto sphalerite[J]. Minerals Engineering, 2015, 71: 113−119. doi: 10.1016/j.mineng.2014.09.004 CrossRef Google Scholar
[68]	郭玉, 寇珏, 孙体昌, 等. 十二烷基磺酸钠和月桂酸在石英表面的吸附机理研究[J]. 矿冶工程, 2015, 35(2): 50-54. Google Scholar GUO Y, KOU J, SUN T C, et al. Adsorption mechanism of sodium dodecyl sulfate and lauric acid on quartz by QCM-D[J]. Mining and Metallurgical Engineering, 2015, 71: 113-119. Google Scholar
[69]	石云良, 邱冠周, 胡岳华, 等. 石英浮选中的表面化学反应[J]. 矿冶工程, 2001(3): 43−45+48. Google Scholar SHI Y L, QIU G Z, HU Y H, et al. Surface chemical reactions in oleate flotation quartz[J]. Mining and Metallurgical Engineering, 2001(3): 43−45+48. Google Scholar
[70]	从金瑶, 王维清, 林一明, 等. 油酸钠体系下钙离子活化石英浮选机理研究[J]. 非金属矿, 2018, 41(6): 77−79. Google Scholar CONG J Y, WANG W Q, LIN Y M, et al. Flotation mechanism of calcium ion activation quartz in system of sodium oleate[J]. Non-metallic Mines, 2018, 41(6): 77−79. Google Scholar
[71]	刘荣祥, 李解, 苏文柔, 等. 红外光谱、XPS分析比较Ca²⁺, Fe³⁺对石英的活化机理[J]. 光谱学与光谱分析, 2020, 40(6): 1876−1882. Google Scholar LIU R X, LI J, SU W R, et al. FTIR and XPS analysis comparing the activation mechanism of Ca²⁺ and Fe³⁺ on quartz[J]. Spectroscopy and Spectral Analysis, 2020, 40(6): 1876−1882. Google Scholar
[72]	卯松, 何晓太, 张覃. 钙离子对胶磷矿和白云石可浮性的影响研究[J]. 矿冶工程, 2013, 33(4): 56−58. Google Scholar MAO S, HE X T, ZHANG Q. Study of influence of calcium ion on floatability of colloiphanite and dolomite under the presence of inorganic anions[J]. Mining and Metallurgical Engineering, 2013, 33(4): 56−58. Google Scholar
[73]	王宇斌, 文堪, 张鲁, 等. Ca²⁺与白云母作用机理的XPS分析[J]. 矿物学报, 2018, 38(4): 462−468. Google Scholar WANG Y B, WEN K, ZHAN L, et al. XPS analysis of interaction mechanism between Ca²⁺ and Muscovite[J]. Journal of Mineralogy, 2018, 38(4): 462−468. Google Scholar
[74]	曾勇, 刘建, 王瑜, 等. 典型金属离子对闪锌矿浮选行为的影响及作用机制的研究进展[J]. 矿产保护与利用, 2019, 39(2): 109−117. Google Scholar ZENG Y, LIU J, WANG Y, et al. Research progress on the influence of typical metal ions on the flotation behavior of sphalerite and its mechanism[J]. Conservation and Utilization of Mineral Resources, 2019, 39(2): 109−117. Google Scholar
[75]	唐劭禹, 张凌燕, 张冲, 等. Fe³⁺对十二烷基磺酸钠捕收石英的活化作用研究[J]. 非金属矿, 2017, 40(5): 79−81. Google Scholar TANG S Y, ZHANG L Y, ZHANG C, et al. Study on activation of sodium dodecyl sulfonate collecting quartz by Fe³⁺[J]. Non-Metallic Mines, 2017, 40(5): 79−81. Google Scholar
[76]	欧乐明, 叶家笋, 曾维伟, 等. 铁离子和亚铁离子对菱锌矿和石英浮选的影响[J]. 有色金属(选矿部分), 2012(6): 79−82. Google Scholar OU L M, YE J S, ZENG W W, et al. The influence of iron and ferrous ions on the flotation of siderite and quartz[J]. Nonferrous Metals (Mineral Processing Section), 2012(6): 79−82. Google Scholar
[77]	班小淇, 顾畔, 印万忠, 等. 菱镁矿浮选体系中Fe³⁺对白云石的选择性活化及机理分析[J]. 矿产综合利用, 2022(5): 125-129. Google Scholar BAN X Q, GU P, YIN W Z, et al. Selective activation of dolomite by Fe³⁺ in magnesite flotation system and its mechanism analysis[J]. Comprehensive Utilization of Mineral Resources, 2022(5): 125−129. Google Scholar
[78]	王宇斌, 雷大士, 张小波, 等. 油酸钠体系下Fe³⁺与白云母的作用机理研究[J]. 硅酸盐通报, 2018, 37(4): 1435−1440. Google Scholar WANG Y B, LEI D S, ZHANG X B, et al. Interaction mechanism of Fe³⁺ with Muscovite in sodium oleate system[J]. Silicate Bulletin, 2018, 37(4): 1435−1440. Google Scholar
[79]	ZHENG Q, QIAN Y, ZOU D, et al. Surface mechanism of Fe³⁺ions on the improvement of fine monazite flotation with octyl hydroxamate as the collector[J]. Frontiers in Chemistry, 2021, 9: 700347. doi: 10.3389/fchem.2021.700347 CrossRef Google Scholar
[80]	ZENG W W, ZHANG Q F, SHI Q, et al. Effects and mechanism of Fe³⁺ on flotation separation of feldspar and epidote with sodium oleate at natural pH[J]. Separations, 2022, 9: 110. Google Scholar
[81]	ZHANG J, WANG W Q, LIU J, et al. Fe(Ⅲ) as an activator for the flotation of spodumene, albite, and quartz minerals[J]. Minerals Engineering, 2014, 61: 16−22. doi: 10.1016/j.mineng.2014.03.004 CrossRef Google Scholar
[82]	XIE R Q, ZHU YM, LIU J, et al. Effects of metal ions on the flotation separation of spodumene from feldspar and quartz[J]. Minerals Engineering, 2021, 168: 106931. Google Scholar
[83]	于洋, 宋磊, 周少珍, 等. 多价金属阳离子对几种含钙盐类矿物可浮性的影响[J]. 化工矿物与加工, 2015, 44(9): 9−13. Google Scholar YU Y, SONG L, ZHOU S Z, et al. Influence of multivalent metal cations on floatability of several calcium salt minerals[J]. Industrial Minerals and Processing, 2015, 44(9): 9−13. Google Scholar
[84]	曾维伟, 刘旭. 铝离子对长石和绿帘石浮选的影响及其作用机理[J]. 矿冶工程, 2021, 41(6): 56−60+64. Google Scholar ZENG W W, LIU X. Effect and mechanism of Al³⁺ on flotation of feldspar and epidote[J]. Mining and Metallurgical Engineering, 2021, 41(6): 56−60+64. Google Scholar
[85]	陈俐全, 张凌燕, 陈志强, 等. 铝离子对油酸钠浮选石英的影响及作用机理简[J]. 金属矿山, 2018(1): 120−124. Google Scholar CHEN L Q, ZHANG L Y, CHEN Z Q, et al. Effect and mechanism of aluminum ion on quartz flotation in the system of sodium oleate[J]. Metal Mine, 2018(1): 120−124. Google Scholar
[86]	陈荩, 陈万雄, 孙中溪. 金属离子活化石英的判据及规律[J]. 金属矿山, 1982(6): 30−33+56. Google Scholar CHEN J, CHEN W X, SUN Z X. Criterion and law of metal ions activated quartz[J]. Metal Mine, 1982(6): 30−33+56. Google Scholar
[87]	沙惠雨, 刘长淼, 方霖, 等. 常见金属阳离子对黑云母浮选行为影响研究[J]. 金属矿山, 2017(1): 94−98. Google Scholar SHA H Y, IIU C M, FANG L, et al. Effect of metallic cations on floatability performance of pure biotite[J]. Metal Mine, 2017(1): 94−98. Google Scholar
[88]	印万忠, 孙传尧. 硅酸盐矿物浮选原理研究现状[J]. 矿产保护与利用, 2001(3): 17-22 Google Scholar YIN W Z, SUN C Y, Review on research status on flotation principles of silicate mineral[J]. Conservation and Utilization of Mineral Resources, 2001(3): 17-22. Google Scholar
[89]	林慧博, 印万忠, 孙传尧. 硅酸盐矿物表面金属离子吸附规律的XPS分析[J]. 有色矿冶, 2003(3): 21−24. Google Scholar LIN H B, YIN W Z, SUN C Y. XPS analysis on adsorption law of metal ion on surface of silicate minerals[J]. Non-ferrous Mining and Metallurgy, 2003(3): 21−24. Google Scholar
[90]	于福顺, 孙永峰, 蒋曼, 等. 金属阳离子在锂辉石浮选中的活化行为及作用机理[J]. 中国有色金属学报, 2021, 31(1): 203−210. Google Scholar YU F S, SUN Y F, JIANG M, et al. Activation behavior and mechanism of metallic cations in spodumene flotation[J]. Chinese Journal of Nonferrous Metals, 2021, 31(1): 203−210. Google Scholar
[91]	廉会良, 范迎菊, 李娜, 等. Cu²⁺和Pb²⁺对硫化锌矿物表面的活化作用[J]. 济南大学学报(自然科学版), 2013, 27(1): 63−66. Google Scholar LAN H L, FAN Y J, LI N, et al. Activation of Cu²⁺ and Pb²⁺ on the surface of zinc sulfide minerals[J]. Journal of Ji’nan University (Natural Science Edition), 2013, 27(1): 63−66. Google Scholar
[92]	朱一民, 周菁. 金属阳离子活化雌黄的浮选及机理[J]. 有色矿山, 2001(1): 28−31+36. Google Scholar ZHU Y M, ZHO Q. Flotation and mechanism of metal cation activated female yellow[J]. Non-ferrous Mines, 2001(1): 28−31+36. Google Scholar
[93]	高玚. 硅钙条件下新型捕收剂浮选微细粒锡石试验研究及应用[D]. 南宁: 广西大学, 2022 Google Scholar GAO Y. Experimental study and application of new collector in flotation of fine cassiterite under silica-calcium condition[D]. Nanning: Guangxi University, 2022. Google Scholar
[94]	张周位. 锡石浮选体系中金属离子作用机理及其应用[D]. 长沙: 中南大学, 2013 Google Scholar ZHANG Z W. Study on the mechanism and application of metal ions in cassiterite flotation system[D]. Changsha: Centra South University, 2013. Google Scholar
[95]	宫贵臣, 刘杰, 韩跃新. 金属离子对微细粒锡石浮选行为的影响[J]. 矿产综合利用, 2016(4): 43−47. doi: 10.3969/j.issn.1000-6532.2016.04.010 CrossRef Google Scholar GONG G C, LIU J, HAN Y X. Effect of metal ions on flotation behaviors of fine cassiterite[J]. Multipurpose Utilization of Mineral Resources, 2016(4): 43−47. doi: 10.3969/j.issn.1000-6532.2016.04.010 CrossRef Google Scholar
[96]	陈禹蒙. 锡石与方解石、斜绿泥石的浮选分离基础研究[D]. 昆明: 昆明理工大学, 2019 Google Scholar CHEN Y M. Basic research on flotation separation of cassiterite, calcite clinochlore[D]. Kunming: Kunming university of Science and Technology, 2019. Google Scholar