Citation: | LIU Lei, SUN Huaxing, GUO Lixiang, HUANG Junwei, ZHAO Hengqin. Protection Technology of Large Scale Crystalline Graphite from Tanzania[J]. Conservation and Utilization of Mineral Resources, 2023, 43(3): 96-104. doi: 10.13779/j.cnki.issn1001-0076.2023.03.011 |
The fixed carbon content of a crystalline graphite ore from Tanzania is 3.74%, among of which the +147 µm size flake graphite accounts for 97.18%. In this paper, the different rough concentrates and further regrinding and reflotation tests between high pressure roller mill and ball mill were compared.The results showed that the effect of the new process of "particles bed comminution (high pressure roller mill)−grading and grading separation" was better. The regrinding of coarse−grained low−carbon products avoided the damage of gangue to large−scale graphite with high dissociation degree in coarse concentrate, and the carbon grade increased rapidly. Its recleaning concentrate and medium−grained medium−carbon were combined into one product, and fine−grained high−carbon products were regrinding and re−concentration in two stages respectively. The fixed carbon content of both concentrates were greater than 96%. Compared with the conventional process, "five times regrinding and six times flotation" were reduced. The final carbon grade of the concentrate was higher than 95% and the +0.15 mm particle size was about 65% in both processes. The +0.30 mm content in the new process was 3.37% higher.
[1] | D. JARA A, BETEMARIAM A, WOLDETINSAE G, et al. Purification, application and current market trend of natural graphite: a review[J]. International Journal of Mining Science and Technology, 2019, 29(5): 671−689. doi: 10.1016/j.ijmst.2019.04.003 |
[2] | 牛敏, 刘磊, 陈龙, 等. 层压粉碎—分质分选技术用于保护大鳞片石墨的研究[J]. 矿产保护与利用, 2018(4): 83−88. NIU M, LIU L, CHEN L, et al. Study on the protection of large scale graphite by particle bed breakage - grading separation technology[J]. Conservation and Utilization of Mineral Resource, 2018(4): 83−88. |
[3] | 刘磊, 牛敏, 郭珍旭, 等. 黑龙江某鳞片石墨层压粉碎-分质分选技术研究[J]. 非金属矿, 2019, 42(6): 57−61. LIU L, NIU M, GUO Z X, et al. Study on particle bed breakage-grading separation technology of flake graphite from heilongjiang[J]. Non-Metallic mines, 2019, 42(6): 57−61. |
[4] | 刘磊, 郭理想, 孙华星, 等. 甘肃阿克塞晶质石墨浮选工艺对比研究[J]. 非金属矿, 2020, 43(6): 56−59+63. LIU L, GUO L X, SUN H X, et al. Comparative study on flotation technology of crystalline graphite from Akesai in Gansu province[J]. Non-Metallic mines, 2020, 43(6): 56−59+63. |
[5] | TONG Z, LIU L, YUAN Z, et al. The effect of comminution on surface roughness and wettability of graphite particles and their relation with flotation[J]. Minerals Engineering, 2021, 169: 106959. doi: 10.1016/j.mineng.2021.106959 |
[6] | MA F, TAO D, TAO Y, et al. An innovative flake graphite upgrading process based on HPGR, stirred grinding mill, and nanobubble column flotation[J]. International Journal of Mining Science and Technology, 2021, 31(6): 1063−1074. doi: 10.1016/j.ijmst.2021.06.005 |
[7] | ZHANG H, LI H, FENG A, et al. Application of stirred mill to upgrading of graphite concentrate by flotation[J]. Canadian Metallurgical Quarterly, 2018, 57(2): 245−251. doi: 10.1080/00084433.2017.1409934 |
[8] | 邱杨率, 余永富, 管俊芳, 等. 非洲三个地区石墨矿矿石特征及可选性研究[J]. 矿产保护与利用, 2018(5): 45−50. QIU Y S,YU Y F,GUAN J F, et al. Study on ore characteristics and beneficiability of three flaky graphite mines in Africa[J]. Conservation and Utilization of Mineral Resource, 2018(5): 45−50. |
Structural characteristics of graphite ores
Flotation and grading-classification test process flow chart of grinding products
Fineness test results of primary regrinding: (a)coarse-grained low-carbon. (b)medium-grained medium-carbon. (c)fine-grained high-carbon
The closed-circuit test flowsheet of conventional coarse concentrate mixed mesh regrinding and reflotation process
The closed-circuit test flowsheet of new process of " particles bed comminution-grading and grading separation