| Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological Sciences | Host |
| Citation: |
BAI Yalin, YANG Junlong, GUO Yanhua, WANG Jun, HE Haitao. Beneficiation-metallurgy Combined Process for the Disseminated Copper-nickel Oxide Ore in Xinjiang[J]. Conservation and Utilization of Mineral Resources, 2023, 43(1): 105-111. doi: 10.13779/j.cnki.issn1001-0076.2023.01.011
|
Beneficiation-metallurgy Combined Process for the Disseminated Copper-nickel Oxide Ore in Xinjiang
-
Abstract
The disseminated copper-nickel oxide ore in Xinjiang contained 0.89% copper and 0.55% nickel. An in-depth study of the ore properties was carried out to develop and utilize this mineral resource. According to the results, the industrial type of ore belonged to ultrabasic rock weathering crust type copper-nickel ore, and copper was mainly in the form of malachite and chrysocolla, and nickel was mainly exsited in chlorite. The oxidation rates of copper and nickel were 74.16% and 96.57% respectively. The ore was severely weathered and contained large mud, which belonged to a refractory copper-nickel oxide ore. Based on the study of ore properties, comparative tests of flotation, agitation leaching and pool leaching were carried out. The results showed that the recovery of copper and nickel by pool leaching was better. When the grinding fineness was -0.074 mm accounting for 45%, the pulp concentration was 20%, sulfuric acid dosage was 50 g/L and leaching time was 24 d, the copper leaching rate was 81.27% and the nickel leaching rate was 60.32%. The copper-nickel leaching solution was treated by a method of copper replacement with iron - iron neutralization -nickel precipitation with sodium sulphide ,and the sponge copper grade was 92.05%, copper replacement rate was 97.35%, nickel grade in nickel sulfide was 24.32%, and nickel precipitation rate was 86.78%. Finally, the recovery rate of copper was 79.12%, and the recovery rate of nickel was 52.35%. The process serves as a technical basis for the development and utilization of the mine, as well as a reference for the development and utilization of the same type of copper-nickel oxide ore.
-
-
References
[1] 伦绍雄, 陆薇宇. 细粒嵌布贫铜镍矿的特征及其对选矿的影响[J]. 武汉工程大学学报, 2013, 35(11): 32−36. doi: 10.3969/j.issn.1674-2869.2013.11.008 LUN S X, LU W Y. Mineralongical feature of lean copper-nickel ore with finely disseminated and its effects on mineral processing[J]. Wuhan Tnst. Tech, 2013, 35(11): 32−36. doi: 10.3969/j.issn.1674-2869.2013.11.008 [2] 徐凤平. 四川会理某铜镍矿选矿试验研究[D]. 昆明: 昆明理工大学, 2007: 9-12. XU F P. Experimental study on beneficiation of a copper-nickel ore in Huili of Sichuan province[D]. Kunming: Kunming University of Science and Technology, 2007: 9-12. [3] 谢杰, 胡春梅. 国内外硫化铜镍矿选矿现状及未来发展方向[J]. 矿产保护与利用, 2018(5): 143−150. doi: 10.13779/j.cnki.issn1001-0076.2018.05.018 XIE J, HU C M. Current status and future development of dressing technology on the sulfide nickel - copper ore at home and abroad[J]. Conservation and Utilization of Mineral Resources, 2018(5): 143−150. doi: 10.13779/j.cnki.issn1001-0076.2018.05.018 [4] 何浩, 邵延海. 我国硫化铜镍矿浮选工艺及药剂研究现状[J]. 矿产保护与利用, 2020(2): 100−104. doi: 10.13779/j.cnki.issn1001-0076.2020.02.013 HE H, SHAO Y H. Research status on flotation process and reagent for copper - nickel sulfid ore[J]. Conservation and Utilization of Mineral Resources, 2020(2): 100−104. doi: 10.13779/j.cnki.issn1001-0076.2020.02.013 [5] 李滦宁, 马玖彤, 张凤君, 等. 铜精矿中铜镍的浸出研究[J]. 湿法冶金, 2001, 20(1): 14−17. doi: 10.3969/j.issn.1009-2617.2001.01.003 LI L N, MA J T, ZHANG F J, et al. Study on leaching of copper and nickel from copper concentrate[J]. Hydrometallurgy of China, 2001, 20(1): 14−17. doi: 10.3969/j.issn.1009-2617.2001.01.003 [6] 唐劭禹, 许阳芳, 杨磊, 等. 浮选-磁选联合工艺处理新疆某铜镍矿[J]. 矿产保护与利用, 2021(5): 90−96. TANG S Y, XU Y F, YANG L, et al. Treatment of a copper nickel ore in Xinjiang by flotation - magnetic separation combined process[J]. Conservation and Utilization of Mineral Resources, 2021(5): 90−96. [7] 李博文, 阳恒, 程少逸, 等. 金川硫化铜镍矿酸性介质中新型浮选药剂体系研究[J]. 矿产保护与利用, 2022(2): 25−31. doi: 10.13779/j.cnki.issn1001-0076.2022.07.002 LI B W, YANG H, CHENG S Y, et al. Research on the flotation reagent regime of jinchuan copper - nickel sulfide ore in acidic medium[J]. Conservation and Utilization of Mineral Resources, 2022(2): 25−31. doi: 10.13779/j.cnki.issn1001-0076.2022.07.002 [8] 朱福良, 黄达, 于倩倩, 等. 铜镍合金中Cu、Ni的选择性浸出研究[J]. 湿法冶金, 2008, 27(4): 227−229. doi: 10.3969/j.issn.1009-2617.2008.04.009 ZHU F L, HUANG D, YU Q Q, et al. Selective leaching of copper and nickel from copper-nickel alloy[J]. Hydrometallurgy of China, 2008, 27(4): 227−229. doi: 10.3969/j.issn.1009-2617.2008.04.009 [9] 马红周, 朱丽芳, 袁守谦, 等. 用硫酸从含铜镍渣中浸出铜的试验研究[J]. 湿法冶金, 2013, 32(6): 357−359. doi: 10.13355/j.cnki.sfyj.2013.06.007 MA H Z, ZHU L F, YUAN S Q, et al. Leaching of copper from nickel slag containing copper using sulfuric acid[J]. Hydrometallurgy of China, 2013, 32(6): 357−359. doi: 10.13355/j.cnki.sfyj.2013.06.007 [10] 阮书锋, 居中军, 李强, 等. 活性氧化镁从硫酸盐介质中选择性沉淀镍钴的研究[J]. 有色金属(冶炼部分), 2013(9): 1−4. RUAN S F, JU Z J, LI Q, et al. Study on selective precipitation on of nickel and cobalt from sulfate medium with active magnesium oxide[J]. Non-ferrous metal(Smelting part), 2013(9): 1−4. [11] 吕晋芳, 童雄, 崔毅琦. 云南低品位铜镍矿选矿试验研究[J]. 矿产综合利用, 2011(3): 25−28. doi: 10.3969/j.issn.1000-6532.2011.03.006 LV J F, TONG X, CUI Y Q. Experimental study on mineral processing technology for a low-grade copper-nickel ore from Yunnan[J]. Multipurpose Utilization of Mineral Resources, 2011(3): 25−28. doi: 10.3969/j.issn.1000-6532.2011.03.006 [12] 张英, 王毓华, 汤玉和, 等. 某低品位铜镍硫化矿浮选试验研究[J]. 矿冶工程, 2009, 29(3): 40−42. doi: 10.3969/j.issn.0253-6099.2009.03.012 ZHANG Y, WANG Y H, TANG Y H, et al. Experimental study on the flotation of a low-grade copper-nickel sulfide ore[J]. Ming and Metallurgical Engineering, 2009, 29(3): 40−42. doi: 10.3969/j.issn.0253-6099.2009.03.012 [13] 周韫, 廖乾, 解振朝, 等. 氧化铜钴精矿浸出试验研究[J]. 矿冶工程, 2016, 36(6): 84−86. doi: 10.3969/j.issn.0253-6099.2016.06.021 ZHOU Y, LIAO Q, XIE Z Z, et al. Leaching test of an oxidized copper-cobalt concentrate[J]. Mining Engineering, 2016, 36(6): 84−86. doi: 10.3969/j.issn.0253-6099.2016.06.021 [14] 李江涛, 库建刚, 程琼. 某硫化铜镍矿浮选试验研究[J]. 矿产保护与利用, 2006(1): 37−39. doi: 10.3969/j.issn.1001-0076.2006.01.008 LI J T, KU J G, CHENG Q, et al. Flotation experiment study of copper-nickel sulfide ore[J]. Conservation and Utilization of Mineral Resources, 2006(1): 37−39. doi: 10.3969/j.issn.1001-0076.2006.01.008 [15] 邢姜, 冷红光, 韩百岁, 等. 红土镍矿湿法冶金工艺现状及研究进展[J]. 有色矿冶, 2021, 37(5): 27−32. doi: 10.3969/j.issn.1007-967X.2021.05.008 XING J, LENG H G, HAN B S, et al. Metallurgical technology situation and research progress of laterite nickel ore[J]. Non-ferrous Mining and Metallurgy, 2021, 37(5): 27−32. doi: 10.3969/j.issn.1007-967X.2021.05.008 -
Access History
Figures(10)
Tables(9)
Export File
Citation
BAI Yalin, YANG Junlong, GUO Yanhua, WANG Jun, HE Haitao. Beneficiation-metallurgy Combined Process for the Disseminated Copper-nickel Oxide Ore in Xinjiang[J]. Conservation and Utilization of Mineral Resources, 2023, 43(1): 105-111. doi: 10.13779/j.cnki.issn1001-0076.2023.01.011
Format
Content
DownLoad:
-
Figure 1.
Veined malachite and limonite are filled in ore fissures
-
Figure 2.
X-ray energy spectrum analysis of chlorite
-
Figure 3.
Process flow and conditions of grinding fineness test
-
Figure 4.
Results of grinding fineness test
-
Figure 5.
Results of dosage of sulfuric acid
-
Figure 6.
Results of leaching time test
-
Figure 7.
Process flow of separation principle of copper and nickel
-
Figure 8.
Results of dosage of iron powder
-
Figure 9.
Results of dosage of displacement time test
-
Figure 10.
Closed circuit test process and conditions