Citation: | WANG Liming, LI Hongjing, BAI Chunxia, SUI Yueting, LIU Tao. Experimental Study on Comprehensive Recovery of Rare Earth and Fluorite from an Iron Tailings of Concentrator in Bayan Obo[J]. Conservation and Utilization of Mineral Resources, 2022, 42(6): 52-59. doi: 10.13779/j.cnki.issn1001-0076.2022.06.007 |
The Bayan Obo Iron Mine is a rare large-scale polymetallic deposit in the world, only iron ore and rare earth were utilized for many years. The recovery rate of rare earth in the beneficiation process is low, resulting in a considerable amount of rare earth and fluorite resources contained in the ore body being discharged into the tailings pond alongside the iron tailings. To achieve comprehensive recovery of rare earth and fluorite resources, the research on comprehensive recovery of rare earth and fluorite was carried out with the iron tailings of a concentrator in Bayan Obo. The process flow adopted in the test was rare earth flotation - fluorite preconcentration - fluorite concentration - high intensity magnetic separation. Sodium silicate, SR and 2# oil were used in rare earth flotation. Sodium silicate and SF were used in fluorite preconcentration. Acidified sodium silicate, SY and sodium oleate were used in fluorite concentration. Finally, rare earth concentrate with REO grade of 50.54%, REO recovery of 92.32% and fluorite concentrate with CaF2 grade of 95.51% and recovery of 50.98% were obtained.
[1] | 何宏平, 杨武斌. 我国稀土资源现状和评价[J]. 大地构造与成矿学, 2022, 46(5): 829−841. HE H P, YANG W B. REE mineral resources in China: review and perspective[J]. Geotectonica et Metallogenia, 2022, 46(5): 829−841. |
[2] | 李潇雨, 惠博, 熊文良, 等. 白云鄂博稀土资源综合利用现状概述[J]. 矿产综合利用, 2021(5): 17−24. doi: 10.3969/j.issn.1000-6532.2021.05.003 LI X Y, HUI B, XIONG W L, et al. Multipurpose utilization of rare earth resources in Bayan Obo[J]. Multipurpose Utilization of Mineral Resources, 2021(5): 17−24. doi: 10.3969/j.issn.1000-6532.2021.05.003 |
[3] | 李丽匣, 刘廷, 袁致涛, 等. 我国萤石矿选矿技术进展[J]. 矿产保护与利用, 2015(6): 46−53. LI L X, LIU T, YUAN Z T, et al. The development in beneficiation of fluorite in China[J]. Conservation and Utilization of Mineral Resources, 2015(6): 46−53. |
[4] | 邹灏, 张寿庭, 方乙, 等. 中国萤石矿的研究现状及展望[J]. 国土资源科技管理, 2012(5): 35−42. doi: 10.3969/j.issn.1009-4210.2012.05.006 ZOU H, ZHANG S T, FANG Y, et al. Current sityation and prospect of flyorite deposit researches in China[J]. Scientific and Technological Management of Land and Resources, 2012(5): 35−42. doi: 10.3969/j.issn.1009-4210.2012.05.006 |
[5] | 王振亮, 鲁瑞君, 林天亮, 等. 浅谈世界萤石资源现状及萤石产业发展方向[J]. 中国非金属矿工业导刊. 2013(3): 3-5. WANG Z L, LU R J, LIN T L, et al. Disussion on the situation of the world fluorite resource and the development direction of fluorite industry[J]. China Non-metallic Minerals Industry, 2013(3): 3-5. |
[6] | 牛丽贤, 张寿庭. 中国萤石产业发展战略思考[J]. 中国矿业, 2010(8): 21−25. doi: 10.3969/j.issn.1004-4051.2010.08.007 NIU L X, ZHANG S T. Reviews on strategy of china fluorite industry development[J]. China Mining Magazine, 2010(8): 21−25. doi: 10.3969/j.issn.1004-4051.2010.08.007 |
[7] | 王文利, 白志民. 中国萤石资源及产业发展现状[J]. 金属矿山, 2014(3): 1−9. WANG W L, BAI Z M. Fluorite resources in China and its industrial development status[J]. Metal Mine, 2014(3): 1−9. |
[8] | 王吉平, 商朋强, 熊先孝, 等. 中国萤石矿床成矿规律[J]. 中国地质, 2015(1): 18−32. doi: 10.3969/j.issn.1000-3657.2015.01.003 WANG J P, SHANG P Q, XIONG X X, et al. Metallogenic regularity of fluorite deposits in china[J]. Geology in China, 2015(1): 18−32. doi: 10.3969/j.issn.1000-3657.2015.01.003 |
[9] | ZHOU W B, JOSUE MORENO, ROBERTO TORRES, et al. Flotation of fluorite from ores by using acidized water glass as depressant[J]. Minerals Engineering, 2013: 45. |
[10] | DONG Y W, JIANG Z H, LIANG L K, et al. Hydrogen permeability of slags containing calcium fluoride[J]. Journal of Central South University of Technology, 2011, 18(4). |
[11] | 周文波, 程杰, 冯齐, 等. 酸化水玻璃在墨西哥某高钙型萤石矿选矿试验中的作用[J]. 非金属矿, 2013, 36(3): 31−32+36. ZHOU W B, CHENG J, FENG Q, et al. The effect of acidized water glass on beneficiation test of mexico high calcium type fluorite ore[J]. Non-Metallic Mines, 2013, 36(3): 31−32+36. |
[12] | 杨治仁, 边雪, 吴文远. 油酸钠为捕收剂时四种抑制剂对人造萤石的抑制研究[J]. 有色金属(选矿部分), 2016(2): 90−92+97. YANG Z Y, BIAN X, WU W Y, et al. Studyon four types of depressants on depression of artificial fluorite by using sodium oleate as collector[J]. Nonferrous Metals(Mineral Processing Section), 2016(2): 90−92+97. |
[13] | 吕子虎, 卫敏, 吴东印, 等. 新型捕收剂在萤石浮选中的应用研究[J]. 矿冶工程, 2013, 33(5): 56−58. doi: 10.3969/j.issn.0253-6099.2013.05.014 LV Z H, WEI M, WU D Y, et al. Application of new collector in fluorite flotation[J]. Mining and Metallurgical Engineering, 2013, 33(5): 56−58. doi: 10.3969/j.issn.0253-6099.2013.05.014 |
Principle process of comprehensive recovery of rare earth and fluorite
Flow chart of rare earth flotation process
Effect of sodium silicate dosage on rare earth flotation
Effect of SR dosage on rare earth flotation
Process flow chart of closed circuit test on rare earth flotation
Process flow chart of fluorite preconcentration
Effect of sodium silicate dosage on roughing in fluorite preconcentration
Effect of SF dosage on roughing in fluorite preconcentration
Process flow chart of closed circuit test on fluorite preconcentration
Microscopic image of fluorite intergrowth
Process flow chart of fluorite concentration
Effect of acidified sodium silicate dosage on roughing in fluorite concentration
Effect of SY dosage on roughing in fluorite concentration
Effect of sodium oleate dosage on roughing in fluorite concentration
Process flow chart of closed circuit test on fluorite concentration
Process flow chart of closed circuit test on overall process