Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2022 Vol. 42, No. 2
Article Contents

YANG Xiaojian, HU Guotao, WANG Shihan. Research Progress of Magnesium Removal Technology from Medium and Low Grade Phosphate Rocks[J]. Conservation and Utilization of Mineral Resources, 2022, 42(2): 67-73. doi: 10.13779/j.cnki.issn1001-0076.2022.02.008
Citation: YANG Xiaojian, HU Guotao, WANG Shihan. Research Progress of Magnesium Removal Technology from Medium and Low Grade Phosphate Rocks[J]. Conservation and Utilization of Mineral Resources, 2022, 42(2): 67-73. doi: 10.13779/j.cnki.issn1001-0076.2022.02.008

Research Progress of Magnesium Removal Technology from Medium and Low Grade Phosphate Rocks

  • In recent years, with the continuous development of the phosphorus chemical industry, the high-grade phosphate rock resources that can be used directly have been exhausted. At present, most of the phosphorus resources in my country are high magnesium phosphate rocks that are difficult to select, and a large amount of magnesium impurities have adverse effects on the production of phosphorus chemical industry. Therefore, the research on magnesium removal technology of phosphate rocks is particularly important. This paper analyzes the influence of magnesium impurities in phosphate rocks on the processing of phosphate rocks, expounds in detail the application and effect of flotation method, leaching method and high-temperature calcination method in the removal of magnesium from phosphate rock, compares and analyzes the advantages and disadvantages of different magnesium removal technologies, and points out that although most magnesium can be removed by flotation, it is difficult to remove magnesium in depth. Therefore, the combined process of flotation, leaching or high temperature calcination can be used to realize the deep removal of magnesium, and it is suggested that the research on phosphate rock magnesium removal technology should be developed towards the direction of compound, economic and environmental protection.

  • 加载中
  • [1] 张卫峰, 马文奇, 张福锁, 等. 中国、美国、摩洛哥磷矿资源优势及开发战略比较分析[J]. 自然资源学报, 2005, 20(3): 378-386. doi: 10.3321/j.issn:1000-3037.2005.03.009

    CrossRef Google Scholar

    ZHANG W F, MA W Q, ZHANG F S, et al. Comparative analysis of phosphate rock resource advantages and development strategies among China, the United States and Morocco[J]. Journal of natural resources, 2005, 20(3): 378-386. doi: 10.3321/j.issn:1000-3037.2005.03.009

    CrossRef Google Scholar

    [2] 张亚明, 李文超, 王海军. 我国磷矿资源开发利用现状[J]. 化工矿物与加工, 2020, 49(6): 43-46.

    Google Scholar

    ZHANG Y M, LI W C, WANG H J. Current situation of development and utilization of phosphate rock resources in China[J]. Chemical minerals and processing, 2020, 49(6): 43-46.

    Google Scholar

    [3] 陈欣, 王励生. 三维图形处理在磷矿脱镁动力学研究中的应用[J]. 工程科学与技术, 2001, 33(6): 41-44.

    Google Scholar

    CHEN X, WANG L S. Application of three-dimensional graphics processing in the study of magnesium removal kinetics of phosphate rock[J]. Engineering Science and technology, 2001, 33(6): 41-44.

    Google Scholar

    [4] 余静. 利用低品位磷矿生产湿法磷酸的新工艺及动力学研究[D]. 成都: 四川大学, 2005.

    Google Scholar

    YU J. Study on new process and kinetics of wet process phosphoric acid production from low-grade phosphate rock[D]. Chengdu: Sichuan University, 2005.

    Google Scholar

    [5] MARUSIA R V, IGNACIO V, JUAN M. Radiological, chemical and morphological characterizations of phosphate rock and phosphogypsum from phosphoric acid factories in SW Spain[J]. Journal of Hazardous Materials, 2010, 181(1/2/3): 193-203.

    Google Scholar

    [6] ZERA K, LABOG M G, BAYRAKC S. Physical Structure and Chemical and Mineralogical Composition of the Mazidag (Turkey) Phosphate Rock[J]. Eng. Chem. Res., 2000, 39: 679-683. doi: 10.1021/ie990441v

    CrossRef Google Scholar

    [7] ABDEL-ZAHER M. ABOUZEID. Physical and thermal treatment of phosphate ores-An overview[J]. International Journal of Mineral Processing, 2008, 85(4): 59-84. doi: 10.1016/j.minpro.2007.09.001

    CrossRef Google Scholar

    [8] MOHAMED I, AL-WAKEEL. Effect of mechanical treatment on the mineralogical constituents of Abu-Tartour phosphate ore, Egypt[J]. International Journal of Mineral Processing, 2005, 75(1/2): 101-112.

    Google Scholar

    [9] TIBERIUS C, VAIMAKIS, EVANGELOS D., ECONOMOU. Evaluation of the Mechanism of Greek Calcareous Phosphate Ore[J]. Eng. Chem. Res., 1998, 37: 4306-4313. doi: 10.1021/ie9709087

    CrossRef Google Scholar

    [10] HEY D, DIETERMAN A J. Production of wet process phosphporic acid: US3653827 A[P]. 1972-04-04.

    Google Scholar

    [11] GHARABAGHI M, IRANNAJAD M, NOAPARAST M. A review of the beneficiation of calcareous phosphate ores using organic acid leaching[J]. Hydrometallurgy, 2010, 103(1-4): 96-107. doi: 10.1016/j.hydromet.2010.03.002

    CrossRef Google Scholar

    [12] 刘江林, 熊明金, 曾波. 胶磷矿采用浮选柱脱除镁杂质的可行性[J]. 磷肥与复肥, 2008, 23(4): 5-8. doi: 10.3969/j.issn.1007-6220.2008.04.002

    CrossRef Google Scholar

    LIU J L, XIONG M J, ZENG B. Feasibility of removing magnesium impurities from collophanite by flotation column[J]. Phosphate fertilizer and compound fertilizer, 2008, 23(4): 5-8. doi: 10.3969/j.issn.1007-6220.2008.04.002

    CrossRef Google Scholar

    [13] 廖吉星, 项双龙. 磷矿浆化学浸提法脱镁工艺研究[J]. 磷肥与复肥, 2014, 29(5): 8-10. doi: 10.3969/j.issn.1007-6220.2014.05.003

    CrossRef Google Scholar

    LIAO J X, XIANG S L. Study on magnesium removal process by chemical leaching of phosphorus ore pulp[J]. Phosphate fertilizer and compound fertilizer, 2014, 29(5): 8-10. doi: 10.3969/j.issn.1007-6220.2014.05.003

    CrossRef Google Scholar

    [14] 杨建中, 李志祥. 湿法磷酸生产用磷矿化学法净化技术研究[J]. 磷肥与复肥, 2003(1): 12-15. doi: 10.3969/j.issn.1007-6220.2003.01.004

    CrossRef Google Scholar

    YANG J Z, LI Z X. Study on chemical purification technology of phosphate rock for wet process phosphoric acid production[J]. Phosphate fertilizer and compound fertilizer, 2003(1): 12-15. doi: 10.3969/j.issn.1007-6220.2003.01.004

    CrossRef Google Scholar

    [15] 陈欣, 张志业. 镁对磷矿影响及合理利用途径的研究[J]. 磷酸盐工业, 2004, 4(1): 7-12.

    Google Scholar

    CHEN X, ZHANG Z Y. Study on the influence of magnesium on phosphate rock and its rational utilization[J]. Phosphate industry, 2004, 4(1): 7-12.

    Google Scholar

    [16] 伍沅, 黄玉琼, 贺小平, 等. 镁对磷矿化学加工的影响与对策[J]. 武汉化工学院学报, 1991, 13(4): 35-40.

    Google Scholar

    WU Y, HUANG Y Q, HE X P, et al Influence of magnesium on chemical processing of phosphate rock and its countermeasures[J]. Journal of Wuhan Institute of Chemical Technology, 1991, 13(4): 35-40.

    Google Scholar

    [17] 叶林, 姜振胜, 余俊, 等. 提高磷矿品位的单一反浮选试验[J]. 武汉工程大学学报, 2012(9): 22-25. doi: 10.3969/j.issn.1674-2869.2012.09.006

    CrossRef Google Scholar

    YE L, JIANG Z S, YU J, et al Single reverse flotation test for improving phosphate rock grade[J]. Journal of Wuhan University of engineering, 2012(9): 22-25. doi: 10.3969/j.issn.1674-2869.2012.09.006

    CrossRef Google Scholar

    [18] FUESTENAU D W, 李云龙. 表面转化对白云石和磷灰石化学性质和浮选行为的影响[J]. 国外金属矿选矿, 1992, 29(11): 11-17.

    Google Scholar

    FUESTENAU D W, Li Y L. Effect of surface transformation on chemical properties and flotation behavior of dolomite and apatite[J]. Foreign metal ore beneficiation, 1992, 29(11): 11-17.

    Google Scholar

    [19] 刘集银, 王自友. 白云石的晶体结构特征和X-射线研究[J]. 矿物岩石, 1988(1): 28-33.

    Google Scholar

    LIUJ Y, WANG Z Y. Crystal structure characteristics and X-ray study of dolomite[J]. Mineral rock, 1988(1): 28-33.

    Google Scholar

    [20] 孙建业, 刘亭, 姜振胜. 捕收剂DP-1在雷波地区某磷矿反浮选工艺中的应用[J]. 磷肥与复肥, 2020, 35(5): 33-35. doi: 10.3969/j.issn.1007-6220.2020.05.011

    CrossRef Google Scholar

    SUN J Y, LIU T, JIANG Z S. Application of collector DP-1 in reverse flotation process of a phosphate rock in Leibo area[J]. Phosphate fertilizer and compound fertilizer, 2020, 35(5): 33-35. doi: 10.3969/j.issn.1007-6220.2020.05.011

    CrossRef Google Scholar

    [21] 黄文萱, 刘文彪, 迟晓鹏, 等. 复配捕收剂在胶磷矿反浮选脱镁中的研究[J]. 非金属矿, 2021, 44(1): 56-58. doi: 10.3969/j.issn.1000-8098.2021.01.016

    CrossRef Google Scholar

    HUANG W X, LIU W B, CHI X P, et al Study on compound collector in magnesium removal by reverse flotation of collophanite[J]. Nonmetallic ore, 2021, 44(1): 56-58. doi: 10.3969/j.issn.1000-8098.2021.01.016

    CrossRef Google Scholar

    [22] 杜橙幻, 葛英勇, 刘智, 等. 湖南某中低品位磷矿浮选试验研究[J]. 化工矿物与加工, 2017, 46(9): 24-26+58.

    Google Scholar

    DU C H, GEY Y, LIU Z, et al Experimental study on Flotation of a medium and low grade phosphate rock in Hunan[J]. Chemical minerals and processing, 2017, 46(9): 24-26+58.

    Google Scholar

    [23] 韩俊尧, 刘安荣, 王振杰. 贵州某钙镁质胶磷矿选磷降镁反浮选试验研究[J]. 化工矿物与加工, 2017, 46(11): 4-7.

    Google Scholar

    HAN J Y, LIU A R, WANG Z J. Experimental study on reverse flotation for phosphorus separation and magnesium reduction of a calcium magnesium collophanite in Guizhou[J]. Chemical Minerals and Processing, 2017, 46(11): 4-7.

    Google Scholar

    [24] GUIMARAES R C, ARAUJO A C, PERES A. Reagents in igneous phosphate ores flotation[J]. Minerals Engineering, 2004, 18(2): 199-204.

    Google Scholar

    [25] SIS H, CHANDER S. Reagents used in the flotation of phosphate ores: a critical review[J]. Minerals Engineering, 2003, 16(7): 577-585. doi: 10.1016/S0892-6875(03)00131-6

    CrossRef Google Scholar

    [26] 王向荣. 低品位胶磷矿浮选工艺研究[D]. 武汉: 武汉理工大学, 2005.

    Google Scholar

    WANG X R. Study on flotation process of low-grade collophanite[D]. Wuhan: Wuhan University of Technology, 2005.

    Google Scholar

    [27] 傅克文, 孙立田, 时承东. 大峪口胶磷矿正反浮选新工艺的试验研究及工业化应用[J]. 化工矿物与加工, 2013, 42(12): 25-27.

    Google Scholar

    FU K W, SUN L T, SHI C D. Experimental study and industrial application of a new positive and negative flotation process for Dayukou collophanite[J]. Chemical Minerals and Processing, 2013, 42(12): 25-27.

    Google Scholar

    [28] 黄祖范. 王集磷矿50吨/日规模直接浮选试验[J]. 化工矿山技术, 1984(6): 3-4.

    Google Scholar

    HUANG Z F. Direct flotation test of Wangji phosphate rock on a scale of 50 tons/day[J]. Chemical mining technology, 1984(6): 3-4.

    Google Scholar

    [29] 张泽强, 张翼, 李冬莲. 胶磷矿浮选技术的改进[J]. 武汉工程大学学报, 2016, 38(2): 168-172. doi: 10.3969/j.issn.1674-2869.2016.02.012

    CrossRef Google Scholar

    ZhANG Z Q, ZHANG Y, LI D L. Improvement of flotation technology of collophanite[J]. Journal of Wuhan University of engineering, 2016, 38(2): 168-172. doi: 10.3969/j.issn.1674-2869.2016.02.012

    CrossRef Google Scholar

    [30] 郑世波, 吴良图. 大峪口磷矿选矿试验及选矿厂工艺调试[J]. 化工矿山技术, 1997(2): 17-19+12.

    Google Scholar

    ZHENG S B, WU L T. Commissioning and beneficiation process of Dayukou phosphate mine[J]. Chemical mining technology, 1997(2): 17-19+12

    Google Scholar

    [31] Al-FARISS T F, ARAFAT Y, El-ALEEM F A, et al. Investigating sodium sulphate as a phosphate depressant in acidic media[J]. Separation & Purification Technology, 2014, 124(6): 163-169.

    Google Scholar

    [32] Al-FARISS T F, ARAFAT Y, El-ALEEM F A, et al. Column versus mechanical flotation for calcareous phosphate fines upgrading[J]. Particulate Science&Technology An International Journal, 2013, 31(5): 488-493.

    Google Scholar

    [33] 石波, 徐伟, 田言, 等. WF-04反浮选贵州某钙镁质磷矿及作用机理研究[J]. 化工矿物与加工, 2021, 50(10): 10-13.

    Google Scholar

    SHI B, XU W, TIAN Y, et al Study on flotation mechanism of Guizhou magnesium calcium ore and its reaction[J]. Chemical Minerals and Processing, 2021, 50(10): 10-13.

    Google Scholar

    [34] 谢国先, 张路莉, 刘鑫, 等. 胶磷矿选矿工艺的研究现状[J]. 磷肥与复肥, 2012, 27(1): 16-19.

    Google Scholar

    XIE G X, ZHANG L L, LIU X, et al Research status of beneficiation process of collophanite[J]. Phosphate fertilizer and compound fertilizer, 2012, 27(1): 16-19.

    Google Scholar

    [35] GUAN C. Theoretical background of the crago phosphate flotation process[J]. Minerals& Metallurgical Processing, 2009, 26(2): 55-64.

    Google Scholar

    [36] GE Y-Y, GAN S-P, ZENG X-B, et al. Double reverse flotation process of collophanite and regulating frothaction[J]. Transactions of Nonferrous Metals Society of China, 2008, 18(2): 449-45.

    Google Scholar

    [37] 谢国先, 罗廉明, 夏敬源, 等. 钙(镁)质胶磷矿脱镁反浮选酸的作用机理探析[J]. 化工矿物与加工, 2010, 39(10): 9-10+13.

    Google Scholar

    XIE G X, LUO L M, XIA J Y, et al Analysis on the action mechanism of acid in de magnesium reverse flotation of calcium (magnesium) collophanite[J]. Chemical Minerals and Processing, 2010, 39(10): 9-10+13.

    Google Scholar

    [38] 余永富, 葛英勇, 潘昌林. 磷矿选矿进展及存在的问题[J]. 矿冶工程, 2008(1): 29-33.

    Google Scholar

    YU Y F, GE Y Y, PAN C L. Progress and existing problems in phosphate rock beneficiation[J]. Mining and Metallurgy Engineering, 2008(1): 29-33.

    Google Scholar

    [39] 张雪杰, 张志业, 王辛龙. 高镁磷矿化学脱镁过程的工艺研究[J]. 化工矿物与加工, 2010, 39(2): 1-3+13.

    Google Scholar

    ZHANG X J, ZHANG Z Y, WANG X L. Study on chemical demineralization process of high magnesium phosphate rock[J]. Chemical Minerals and Processing, 2010, 39(2): 1-3+13.

    Google Scholar

    [40] 关影莲, 肖雅龄, 吕瑶姣. 用SO2处理硅钙质磷块岩[J]. 化工矿物与加工, 1982(2): 40-41.

    Google Scholar

    GUAN Y L, XIAO Y L, LV Y J. Treatment of silico calcareous phosphorite with SO2[J]. Chemical Minerals and Processing, 1982(2): 40-41.

    Google Scholar

    [41] 陈小林, 刘代俊, 谭得勤, 等. 磷尾矿硝酸脱镁制取氢氧化镁工艺研究[J]. 化工矿物与加工, 2012, 41(3): 6-8.

    Google Scholar

    CHEN X L, LIU D J, TAN D Q, et al Study on Preparation of magnesium hydroxide by removing magnesium nitrate from phosphorus tailings[J]. Chemical Minerals and Processing, 2012, 41(3): 6-8.

    Google Scholar

    [42] 云南三环化工有限公司研发中心. 湿法磷酸副产氟硅酸用于磷矿脱镁试验研究[J]. 磷肥与复肥, 2003, 18(6): 7-9.

    Google Scholar

    R & D center of Yunnan Sanhuan Chemical Co., Ltd Experimental study on magnesium removal from phosphate rock by fluosilicic acid, a by-product of wet process phosphoric acid[J]. Phosphate Fertilizer and Compound Fertilizer, 2003, 18(6): 7-9.

    Google Scholar

    [43] ABU-EISHAH, EI-JALLAD, TOUQAN M. Beneficiation of calcare-ous phosphate rocks using dilute acetic acid solution: opti-mization of operating conditions for Ruseifa phosphate[J]. International of Journal Mineral Processing, 1991, 31: 115-126.

    Google Scholar

    [44] ZAFAR Z I. Beneficiation of low grade carbonate-rich phosphate rocks using dilute acetic acid solution[J]. Fertilizer Research, 1993, 34(2): 173-180.

    Google Scholar

    [45] 盛勇, 刘晓春, 胡曼川. 从高低品位磷矿中回收镁的方法: 201112028736.6[P]. 2011-01-27.

    Google Scholar

    SHENG Y, LIU X C, HU M C. Method for recovering magnesium from high and low grade phosphate rock: 201112028736.6[P]. 2011-01-27.

    Google Scholar

    [46] WATTI A, ALNJJAR M, HAMMAL A. Improving the specifications of Syrian raw phosphate by thermal treatment[J]. Arabian Journal of Chemistry, 2011, 10(3): 109-111.

    Google Scholar

    [47] SıNıRKAYA M, KADIRÖZER A, GVLABOGLU M. Investigation of the changes of P2O5 content of phosphate rock during simultaneous calcination/sulfation[J]. Powder Technology, 2011, 211(1): 72-76.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Tables(1)

Article Metrics

Article views(2533) PDF downloads(181) Cited by(0)

Access History

Other Articles By Authors

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint