Research Progress on Impurity Characteristics and Deep Chemical Purification Technology in High-purity Quartz

ZHANG Haiqi; MA Yameng; TAN Xiumin; WU Zhichao

doi:10.13779/j.cnki.issn1001-0076.2022.01.031

2022 Vol. 42, No. 4

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Article navigation > Conservation and Utilization of Mineral Resources > 2022 > 42(4): 159-165

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ZHANG Haiqi, MA Yameng, TAN Xiumin, WU Zhichao. Research Progress on Impurity Characteristics and Deep Chemical Purification Technology in High-purity Quartz[J]. Conservation and Utilization of Mineral Resources, 2022, 42(4): 159-165. doi: 10.13779/j.cnki.issn1001-0076.2022.01.031

Citation:

ZHANG Haiqi, MA Yameng, TAN Xiumin, WU Zhichao. Research Progress on Impurity Characteristics and Deep Chemical Purification Technology in High-purity Quartz[J]. Conservation and Utilization of Mineral Resources, 2022, 42(4): 159-165. doi: 10.13779/j.cnki.issn1001-0076.2022.01.031

Research Progress on Impurity Characteristics and Deep Chemical Purification Technology in High-purity Quartz

1.
Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, CAGS, Zhengzhou 450006, Henan, China
2.
China National Engineering Research Center for Utilization of Industrial Minerals, Zhengzhou 450006, Henan, China
3.
Key Laboratory for Polymetallic Ores' Evaluation and Utilization, MNR, Zhengzhou 450006, Henan, China

More Information

Corresponding author: MA Yameng, 452836361@qq.com

Received Date: 20 July 2022

Publish Date: 25 August 2022

Abstract

Abstract

With the rapid development of strategic emerging industries, high purity quartz has become one of the key basic raw materials for many cutting-edge fields. The strategic position of high-purity quartz is becoming more and more prominent, and the dependence of China's high-end high-purity quartz sand on foreign countries is still high, so it is urgent to accelerate the key technology of high-purity quartz sand preparation in China. Based on the overview of high purity quartz resources at home and abroad, the impurity characteristics in high purity quartz were analyzed from two aspects: the existence of impurities and the influence of impurities on product quality, and the progress of two key technologies for deep purification of high purity quartz, acid treatment method and heat treatment method, were systematically summarized.
- high purity quartz /
- purification /
- impurity elements /
- chemical leaching /
- chlorination roasting

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References

[1]	贾德龙, 张万益, 陈丛林, 等. 高纯石英全球资源现状与我国发展建议[J]. 矿产保护与利用, 2019, 39(5): 111-117. doi: 10.13779/j.cnki.issn1001-0076.2019.05.011 CrossRef Google Scholar JIA D L, ZHANG W Y, CHEN C L, et al. Global resource status China's development suggestions of high purity quartz[J]. Conservation and Utilization of Mineral Resources, 2019, 39(5): 111-117. doi: 10.13779/j.cnki.issn1001-0076.2019.05.011 CrossRef Google Scholar
[2]	HAUS R, PRINZ S, PRIESS C. Assessment of high purity quartz resources[M]//GÖTZE J and MÖCKEL R. Quartz: Deposits, Mineralogy and Analytics. Berlin Heideberg: Springer-Verlag, 2012: 29-51. Google Scholar
[3]	汪灵, 党陈萍, 李彩侠, 等. 中国高纯石英技术现状与发展前景[J]. 地学前缘, 2014, 21(5): 267-273. doi: 10.13745/j.esf.2014.05.021 CrossRef Google Scholar WANG L, DANG C P, LI C X, et al. Technology of high-purity quartz in China: Status quo and prospect[J]. Earth Science Frontiers, 2014, 21(5): 267-273. doi: 10.13745/j.esf.2014.05.021 CrossRef Google Scholar
[4]	PLATIAS S, VATALIS K I, CHARALABIDIS G. Innovative processing techniques for the production of a critical raw material the high purity quartz[J]. Procedia Economics and Finance, 2013(5): 597-604. Google Scholar
[5]	汪灵. 石英的矿床工业类型与应用特点[J]. 矿产保护与利用, 2019, 39(6): 39-47. doi: 10.13779/j.cnki.issn1001-0076.2019.06.007 CrossRef Google Scholar WANG L. Industrial types and application characteristics of quartz ore deposits[J]. Conservation and Utilization of Mineral Resources, 2019, 39(6): 39-47. doi: 10.13779/j.cnki.issn1001-0076.2019.06.007 CrossRef Google Scholar
[6]	王九一. 全球高纯石英原料矿的资源分布与开发现状[J]. 岩石矿物学杂志, 2021, 40(1): 131-141. doi: 10.3969/j.issn.1000-6524.2021.01.012 CrossRef Google Scholar WANG J Y. Global high purity quartz deposits: Resources distribution and exploitation status[J]. Acta Petrologica et Mineralogica, 2021, 40(1): 131-141. doi: 10.3969/j.issn.1000-6524.2021.01.012 CrossRef Google Scholar
[7]	SWANSON S E, VEAL W B. Mineralogy and petrogenesis of pegmatites in the spruce pine district, north carolina, USAS[J]. Journal of Geosciences, 2010, 55: 27-42. Google Scholar
[8]	MVLLER A, IHLEN P M, WANVIK J E, et al. High-purity quartz mineralisation in kyanite quartzites, Norway[J]. Miner Deposita, 2007, 42: 523-535. Google Scholar
[9]	焦丽香. 我国脉石英资源开发利用现状及供需分析[J]. 中国非金属矿工业导刊, 2019(2): 11-14. Google Scholar JIAO L X. Current situation and supply demand analysis of the development and utilization of vein quartz resources in China[J]. China Non-Metallic Minerals Industry, 2019(2): 11-14. Google Scholar
[10]	HAUS R. High demands on high purity[J]. Industrial Minerals, 2005, 10: 62-67. Google Scholar
[11]	吴逍, 孙红娟, 彭同江, 等. 青海某地脉石英矿工艺矿物学研究及可选性试验[J]. 矿冶, 2015, 24(2): 71-77. Google Scholar WU X, SUN H J, PENG T J, et al. Process mineralogy study and beneficiation test of a vein quartz ore from Qinghai province[J]. Mining and Metallurgy, 2015, 24(2): 71-77. Google Scholar
[12]	钟乐乐. 超高纯石英纯化制备及机理研究[D]. 武汉: 武汉理工大学, 2015. Google Scholar ZHONG L L. Study on purifying preparation and mechanism of ultra-pure quartz[D]. Wuhan: Wuhan University of Technology, 2015. Google Scholar
[13]	欧阳恒, 张术根, 谷湘平. 溆浦高纯硅矿床石英流体包裹体研究[J]. 中国非金属矿工业导刊, 2006(2): 55-57+64. Google Scholar OU Y H, ZHANG S G, GU X P. Fluid inclusions in quartz of high purity silica deposit of Xupu, Hunan[J]. China Non-Metallic Mining Industry Herald, 2006(2): 55-57+64. Google Scholar
[14]	CISNEROS M, ASHLEY K, BODNAR R. Evaluation and application of the quartz-inclusions-in-epidote mineral barometer[J]. American Mineralogist, 2020, 105(8): 1140-1151. Google Scholar
[15]	YIN R, JING L, HOU Q, et al. Study on optimization quartz mine for removal gas-liquid inclusions in quartz sand under microwave and acid corrosion[J]. Advanced Materials Research, 2013, 800: 3-7. Google Scholar
[16]	DENNEN W H. Stoichiometric substitution in natural quartz[J]. Geochimica et Cosmochimica Acta, 1966, 30(12): 1235-1241. Google Scholar
[17]	Roedder E. Fluid inclusions-reviews in mineralogy[M]. Washington: Mineralogical Society of America, 1984: 644. Google Scholar
[18]	SIMPSON D R. Aluminum phosphate variants in feldspars[J]. American Mineralogist, 1977, 62: 351. Google Scholar
[19]	MCLAREN A C, COOK R F, HYDE S T, et al. The mechanism of the formation and growth of water bubbles and associated dislocation loops in synthetic quartz[J]. Physics and Chemistry of Minerals, 1983, 9(2): 79. Google Scholar
[20]	郭文达, 韩跃新, 朱一民, 等. 高纯石英砂资源及加工技术分析[J]. 金属矿山, 2019(2): 22-28. Google Scholar GUO W D, HAN Y X, ZHU Y M, et al. Analysis of high-purity quartz sand resources and it's processing technologies[J]. Metal Mine, 2019(2): 22-28. Google Scholar
[21]	DALMARTELLO E, BERNARDIS S, LARSEN R B, et al. Electrical fragmentation as a novel route for there finement of quartz raw materials for trace mineral impurities[J]. Powder Technology, 2012, 224: 209-216. Google Scholar
[22]	KOVALCHUK B M, KHARLOV A V, VIZIR V A, et al. High-voltage pulsed generator for dynamic fragmentation of rocks[J]. The Review of Scientific Instruments, 2010, 81(10): 11-18. Google Scholar
[23]	KLINE W E, FOGLER H S. Dissolution of silicate minerals by hydrofluoric acid[J]. Industrial & Engineering Chemistry Fundamentals, 1981, 20(2): 155-161. Google Scholar
[24]	MVLLER A, WIEDENBECK M, VAN-DEN-KERKHOF A M. Trace elements in quartz-a combined electron microprobe, secondary ion mass spectrometry, laser-ablation ICP-MS, and cathodoluminescence study[J]. European Journal of Mineralogy, 2003, 15(4): 747-763. Google Scholar
[25]	吴逍. 高纯石英原料选择评价及提纯工艺研究[D]. 绵阳: 西南科技大学, 2016. Google Scholar WU X. Selection and evaluation of high purity quartz materials and purification technology research[D]. Mianyang: Southwest University of Science and technology, 2016. Google Scholar
[26]	岳丽琴. 高纯石英制备技术评述[J]. 矿产综合利用, 2014(1): 16-19. Google Scholar YUE L Q. Review on preparation technology of high purity quartz[J]. Multipurpose Utilization of Mineral Resources, 2014(1): 16-19. Google Scholar
[27]	苏英, 周永恒, 黄武, 等. 石英玻璃与HF酸反应动力学的研究[J]. 硅酸盐学报, 2004, 32(3): 287-293. Google Scholar SU Y, ZHOU Y H, HUANG W, et al. Study on reaction kinetics between silica glasses and hydrofluoric acid[J]. Journal of The Chinese Ceramic Society, 2004, 32(3): 287-293. Google Scholar
[28]	刘加威. 石英砂焙烧-酸洗除杂工艺研究[D]. 合肥: 安徽大学, 2017. Google Scholar LIU J W. Study on purification of silica sands by roasting and acids leaching[D]. Hefei: Anhui University, 2017. Google Scholar
[29]	张雪梅, 汪徐春, 邓军草, 等. 酸络合除石英砂中铁的研究[J]. 硅酸盐通报, 2012, 31(4): 852-860. Google Scholar ZHANG X M, WANG X C, DENG J, et al. Study on oxalic acid complexation method of removing iron from quartz[J]. Bulletin of the Chinese Ceramic Society, 2012, 31(4): 852-860. Google Scholar
[30]	田金星. 高纯石英砂的提纯工艺研究[J]. 中国矿业, 1999(3): 59-62. Google Scholar TIAN J X. Researches of extraction technology of high grade quartz sand[J]. China Mining Magazine, 1999(3): 59-62. Google Scholar
[31]	张研研. 花岗伟晶岩长石尾矿制多晶硅及HIT太阳电池模拟研究[D]. 阜新: 辽宁工程技术大学, 2014. Google Scholar ZHANG Y Y. Research on preparation of polysilicon with granitic pegmatite feldspar tailings and HIT solar cell by simulation[D]. Fuxin: Liaoning Technology University, 2014. Google Scholar
[32]	夏章杰, 林敏, 雷绍民, 等. 酸浸出去除石英中Fe、K、Al元素及机理研究[J]. 矿产综合利用, 2018(5): 42-45. Google Scholar Xia Z J, Lin M, Lei S M, et al. Study on removal of Fe, K and Al in quartz by acid leaching[J]. Multipurpose Utilization of Mineral Resources, 2018(5): 42-45. Google Scholar
[33]	雷绍民, 慎舟, 黄冬冬. 用于制备熔融石英的块状石英常温浸出技术研究[J]. 矿业研究与开发, 2013, 1(8): 48-51. Google Scholar LEI S M, SHEN Z, HUANG D D. Research on the leaching technology of massive quartz at normal temperature[J]. Mining Research and Development, 2013, 1(8): 48-51. Google Scholar
[34]	曾华东, 雷绍民, 刘云涛, 等. 石英氧化浸出提纯中的络合离子的作用及机理[J]. 矿业研究与开发, 2012(12): 67-70. Google Scholar ZENG H D, LEI S M, LIU Y T, et al. Effect and complexation mechanism of complex ion in quartz purification by oxidation leaching[J]. Mining Research and Development, 2012(12): 67-70. Google Scholar
[35]	夏章杰. 磷酸浸出-碳酸钠焙烧纯化脉石英及机理研究[D]. 武汉: 武汉理工大学, 2018. Google Scholar XIA Z J. Research on purification and mechanism of phosphoric acid leaching-sodium carbonate roasting of vein quartz[D]. Wuhan: Wuhan University of Technology, 2018. Google Scholar
[36]	林敏. 脉石英中白云母、晶格杂质分离及机理[D]. 武汉: 武汉理工大学, 2018. Google Scholar LIN M. Mechanism of removing muscovite and lattice imputiry elements from vein quartz[D]. Wuhan: Wuhan University of Technology, 2018. Google Scholar
[37]	马超, 冯安生, 刘长淼, 等. 高纯石英原料矿物学特征与加工技术进展[J]. 矿产保护与利用, 2019, 39(6): 48-57. Google Scholar MA C, FENG A S, LIU C M, et al. Mineralogical characteristics and progress in processing technology of raw materials of high purity quartz[J]. Conservation and Utilization of Mineral Resources, 2019, 39(6): 48-57. Google Scholar
[38]	从金瑶. 几种伟晶岩石英的矿石学特征及杂质去除工艺研究[D]. 绵阳: 西南科技大学, 2019. Google Scholar CONG J Y. Study on oreological characteristics and impurity removal process of several pegmatite quartz[D]. Mianyang: Southwest University of Science and Technology, 2019. Google Scholar
[39]	侯清麟, 王迎霞, 侯熠徽. 剔除硅石矿中气液包裹体方法的研究[J]. 包装学报, 2019, 11(6): 38-42. Google Scholar HOU Q L, WANG Y X, HOU Y H. Study on gas-liquid inclusion methods for removing silica ores[J]. Packaging Journal, 2019, 11(6): 38-42. Google Scholar
[40]	BELASHEV B Z, SKAMNITSKAYA L S. Irradiation methods for removal of fluid inclusions from minerals[J]. Materials and Geoenvironment, 2009, 56(2): 138-147. Google Scholar
[41]	YAN Q X, LI X H, WANG Z X, et al. Extraction of lithium from lepidolite using chlorination roasting-water leaching process[J]. Transactions of Nonferrous Metals Society of China, 2012, 22(7): 1753-1759. Google Scholar
[42]	LORITSCH K B., JAMES R D. Purified quartz and process for purifying quartz: U.S. Patent 5037625[P]. 1991-08-06. Google Scholar