Citation: | GAO Hulin, LIU Jian, LUO Deqiang, DONG Wenchao, YU Yunlong, HAO Jiamei, QIN Xiaoyan. Experimental Study on Flotation Separation of Ilmenite and Pyroxene and Action Mechanism of Depressants[J]. Conservation and Utilization of Mineral Resources, 2022, 42(1): 61-67. doi: 10.13779/j.cnki.issn1001-0076.2022.01.009 |
Using MOH as collector, sodium silicate, oxalic acid and LD-C (carboxymethyl cellulose) as depressants, single mineral flotation of ilmenite and pyroxene was carried out. In addition, the interaction mechanism of LD-C with ilmenite and pyroxene was studied by solution chemistry of flotation, zeta potential test and infrared spectroscopic test. The test results show that the selective depression effect of LD-C on pyroxene was significantly better than that of sodium silicate and oxalic acid. Under weak acidic conditions, and the dosage of collector MOH was 160 mg/L, depressant LD-C was 2 mg/L, the recovery of ilmenite can reach 80% and that of pyroxene was 9%. The interaction of LD-C on pyroxene can hinder the subsequent adsorption of MOH while that on ilmenite has little effect on the adsorption of MOH. This due to the fact that the active sites of Ca and Mg exposed on the pyroxene surface during flotation can make LD-C adsorb on pyroxene strongly, which hindering the adsorption of collector.
[1] | 李政, 陈从喜. 全球钛资源行业发展现状[J]. 地球学报, 2021(2): 245-250. LI Z, CHEN C X. Development status of global titanium resources industry [J]. Acta Geoscientica Sinica, 2021(2): 245-250. |
[2] | 许国栋, 王桂生. 钛金属和钛产业的发展[J]. 稀有金属, 2009(6): 903-912. doi: 10.3969/j.issn.0258-7076.2009.06.028 XU G D, WANG G S. Development of titanium and its industry [J]. Chinese Journal of Rare Metals, 2009(6): 903-912. doi: 10.3969/j.issn.0258-7076.2009.06.028 |
[3] | 陈攀, 翟计划, 王洪彬, 等. 微细粒钛铁矿浮选捕收剂改性试验研究[J]. 稀有金属, 2018(2): 205-212. CHEN P, ZHAI J H, WANG H B, et al. Experimental study on modification of collector for fine grained ilmenite [J]. Chinese Journal of Rare Metals, 2018(2): 205-212. |
[4] | 刘伟军. 红格矿区钛铁矿与含硅脉石矿物浮选分离机理与工艺研究[D]. 绵阳: 西南科技大学, 2016. LIU W J. Flotation separation mechanism and technology of ilmenite and silicon gangue minerals of hongge [D]. Mianyang: Southwest University of Science and Technology, 2016. |
[5] | 刘向春, 高峰, 邓军平, 等. ABO3型钛铁矿结构化合物的容差因子[J]. 无机材料学报, 2008(5): 881-885. doi: 10.3321/j.issn:1000-324X.2008.05.004 LIU X C, GAO F, DENG J P, et al. Tolerance factor of ABO3-type ilmenite compound [J]. Journal of Inorganic Materials, 2008(5): 881-885. doi: 10.3321/j.issn:1000-324X.2008.05.004 |
[6] | 赵文迪, 章晓林, 景满, 等. 钛铁矿选别工艺进展[J]. 有色金属(选矿部分), 2020(2): 50-56. doi: 10.3969/j.issn.1671-9492.2020.02.009 ZHAO W D, ZHANG X L, JING M, et al. Progress of ilmenite separation process [J]. Nonferrous Metals(Mineral Processing Section), 2020(2): 50-56. doi: 10.3969/j.issn.1671-9492.2020.02.009 |
[7] | YUAN Z T, DU Y S, MENG Q Y, et al. Adsorption differences of carboxymethyl cellulose depressant on ilmenite and titanaugite[J]. Minerals Engineering, 2021(166): 106887. |
[8] | GUILLOT L M, MARTINEZ A F, AGUDO E R, et al. Carbonation of calcium-magnesium pyroxenes: physical-chemical controls and effects of reaction-driven fracturing[J]. Geochimica et Cosmochimica Acta, 2021(304): 258-280. |
[9] | 陈列锰, 宋谢炎, 聂晓勇, 等. 甘肃金川Ⅱ号岩体辉石化学特征及其地质意义[J]. 矿物岩石, 2008(1): 88-96. doi: 10.3969/j.issn.1001-6872.2008.01.013 CHEN L M, SONG X Y, NIE X Y, et al. Mineral chemistry and geological significance of pyroxene in section Ⅱ of Jinchuan pluton, Gansu Province [J]. Journal of Mineralogy and Petrology, 2008(1): 88-96. doi: 10.3969/j.issn.1001-6872.2008.01.013 |
[10] | 马龙秋, 杜雨生, 孟庆有, 等. 钛铁矿浮选药剂及其作用机理研究进展[J]. 金属矿山, 2018(3): 7-12. MA L C, DU Y S, MENG Q Y, et al. Research progress on flotation reagents of ilmenite and their interaction mechanisms [J]. Metal Mine, 2018(3): 7-12. |
[11] | 邓传宏, 马军二, 张国范, 等. 水玻璃在钛铁矿浮选中的作用[J]. 中国有色金属学报, 2010(3): 551-556. DENG C H, MA J E, ZHANG G F, et al. Effect of water glass on floatation of ilmenite [J]. The Chinese Journal of Nonferrous Metals, 2010(3): 551-556. |
[12] | LIU X, HUANG G Y, LI C X, et al. Depressive effect of oxalic acid on titanaugite during ilmenite flotation [J]. Minerals Engineering, 2015(79): 62-67. |
[13] | 朱建光, 陈树民, 姚晓海, 等. 用新型捕收剂MOH浮选微细粒钛铁矿[J]. 有色金属(选矿部分), 2007(6): 42-45. ZHU J G, CHEN S M, YAO X H, et al. Flotation of micro-fine ilmenite using new type collector-MOH [J]. Nonferrous Metals(Mineral Processing Section), 2007(6): 42-45. |
[14] | 朱阳戈. 微细粒钛铁矿浮选理论与技术研究[D]. 长沙: 中南大学, 2012. ZHU Y G. Research on theory and technology of micro-fine ilmenite flotation [D]. Changsha: Central South University, 2012. |
[15] | 徐翔, 章晓林, 许炳梁, 等. 钛铁矿浮选中的抑制剂研究[J]. 矿冶, 2010(4): 21-23. XU X, ZHANG X L, XU B L, et al. Reserch on depressants in ilmenite flotation. [J]. Mining and Metallurgy, 2010(4): 21-23. |
[16] | 申帅平. 微细粒级钛铁矿分选特性研究[D]. 沈阳: 东北大学, 2014. SHEN S P. Research on separation characteristics of micro-fine ilmenite [D]. Shenyang: Northeastern University, 2014. |
[17] | YANG Y H, XU L H, TIAN J, et al. Selective flotation of ilmenite from olivine using the acidified water glass as depressant [J]. International Journal of Mineral Processing, 2016(157): 73-79. |
[18] | 魏志聪, 徐翔, 方建军, 等. 钛铁矿和钛辉石对羧甲基纤维素的吸附机理研究[J]. 矿冶, 2011(1): 8-10. WEI Z C, XU X, FANG J J, et al. Study on the adsorption mechanism of carboxymethyl cellulose on ilmenite and titanaugite [J]. Mining and Metallurgy, 2011(1): 8-10. |
[19] | 张其东. 辉钼矿与滑石可浮性差异调控基础研究[D]. 沈阳: 东北大学, 2016. ZHANG Q D. Fundamental study on regulation and control floatability difference of molybdenite and talc [D]. Shenyang: Northeastern University, 2016. |
[20] | 潘高产, 卢毅屏. CMC和古尔胶对滑石浮选的抑制作用研究[J]. 有色金属(选矿部分), 2013(2): 74-78. PAN G C, LU Y P. Study on the inhibition effect of CMC and guar gum in the talc flotation [J]. Nonferrous Metals(Mineral Processing Section), 2013(2): 74-78. |
[21] | DU Y S, MENG Q Y, YUAN Z T, et al. Study on the flotation behavior and mechanism of ilmenite and titanaugite with sodium oleate [J]. Minerals Engineering, 2020, 152: 106366. |
[22] | ZHU Y G, ZHANG G F, FENG Q M, et al. Effect of surface dissolution on flotation separation of fine ilmenite from titanaugite [J]. Transactions of Nonferrous Metals Society of China, 2011, 21(5): 1149-1154. |
Schematic diagram of the ilmenite and pyroxene crystal structure: (a) ilmenite; (b) pyroxene
X-ray diffraction patterns of ilmenite and pyroxene: (a)ilmenite; (b) pyroxene
Effect of collector dosage on floatability of ilmenite and pyroxene (diesel dosage10 mg/L; pulp pH: 5~6)
Relationship between water glass dosage and mineral buoyancy (collector dosage: 160 mg/L; diesel dosage: 10 mg/L; pulp pH: 5~6)
Relationship between oxalic acid dosage and mineral buoyancy (collector dosage: 160 mg/L; diesel dosage: 10 mg/L; pulp pH: 5~6)
Relationship between LD-C amount and mineral buoyancy (collector dosage: 160 mg/L; diesel dosage: 10 mg/L; pulp pH: 5~6)
Logarithm diagram of ilmenite flotation solution concentration
The Zeta potential of ilmenite, ilmenite +LD-C and ilmenite +LD-C+MOH at different pH (MOH dosage: 160 mg/L; LD-C dosage: 20 mg/L)
The Zeta potential of pyroxene, pyroxene +LD-C and pyroxene +LD-C+MOH at different pH (MOH dosage: 160 mg/L; LD-C dosage: 20 mg/L)
Infrared spectrum of the interaction between LD-C and ilmenite
Infrared spectrum of the interaction between LD-C and pyroxene