Citation: | DAI Ruoding, LI Wuzhong, CHEN Jin, HUO Miaomiao, CHAI Qingping. Investigation on Recycling of Kaolin from Solid Waste in Weathered Rock and Preparation of ZSM-5 Molecular Sieve[J]. Conservation and Utilization of Mineral Resources, 2021, 41(4): 114-118. doi: 10.13779/j.cnki.issn1001-0076.2021.07.007 |
ZSM-5 molecular sieve was synthesized by water heat from a weathered rock in Huizhou, Guangdong Province。Firstly, the kaolin from the weathered rock was recovered by beneficiation. Reduction-complexation method was used to chemically remove iron from it. Next the kaolin was thermally activated and ZSM-5 molecular sieve was synthesized by hydrothermal method using TPAOH as a template. The samples were characterized by TEM, XRD and N2 adsorption-desorption. The results showed that the ZSM-5 molecular sieve had a certain mesoporous structure, good crystallinity and regular pores.
[1] | WANG JQ, HUANG YX, PAN Y, et al. Hydrothermal synthesis of high purity zeolite a from natural kaolin without calcination[J]. Microporous and Mesoporous Materials, 2014, 199: 50-56. doi: 10.1016/j.micromeso.2014.08.002 |
[2] | YANG KEYU, YAN SIYANG, SANG YUE, et al. Construction of Hierarchical ZSM-5 Zeolites by Chelating-Alkaline Medium[J]. Materials Today Sustainability, 2021(prepublish). |
[3] | 刘粤, 车庆丰, 易为, 等. 微介孔Ni/ZSM-5分子筛对甲苯催化重整的影响[J]. 可再生能源, 2021, 39(4): 427-433. |
[4] | 黄国良. 全风化花岗岩的工程特性及工程措施[J]. 科技视界, 2015(15): 94. |
[5] | 卢党军. 我国砂质高岭土资源特点与开发利用现状[J]. 非金属矿, 2009, 32(3): 52-54. |
[6] | 曾利群, 鄢雨南, 陈信峰. 深圳地区风化花岗岩渣土资源化利用试验研究[J]. 非金属矿, 2020, 43(5): 80-83. |
[7] | 俞旺新, 张恩. 煤矸石粉掺量对花岗岩残积土的抗压性能研究[J]. 广西大学学报(自然科学版), 2020, 45(3): 598-605. |
[8] | 田朋飞, 简文星, 宋治, 等. 赣南花岗岩残积土基本物理特性与路用性能研究[J]. 公路交通科技, 2020, 37(9): 41-49. |
[9] | 陈国华. 二氧化硫脲对高岭土增白试验分析[J]. 化工管理, 2019(33): 25-26. |
[10] | 郭春雷, 王维维, 金海龙, 等. 高岭土除铁增白研究进展[J]. 现代矿业, 2019, 35(1): 96-101. |
[11] | LI Y, SUN H, FENG R, et al. Synthesis of ZSM-5 zeolite from diatomite for fluid catalytic cracking(FCC) application[J]. Applied Petrochemical Research, 2015, 5(4): 347-353. |
[12] | PAN F, LU X, ZHU Q, et al. Direct synthesis of HZSM-5 from natural clay[J]. Journal of Materials Chemistry A, 2015, 3(7): 4058-4066. |
XRD pattern of classification products
XRD pattern of FX25 hydrocyclnone overflow K: kaolin; H: hematite
XRD pattern of ZSM-5 molecular sieve
TEM photographs of ZSM-5 molecular sieve