Citation: | LI Guang, SHI Jia, FANG Shenyu, ZHU Diwen, NIE Dapeng, CUI Rui. Study on the Influence of Ultrasonic and Thermal Effects on the Floatability of Calcite in Sodium Silicate and Sodium Oleate System[J]. Conservation and Utilization of Mineral Resources, 2021, 41(6): 131-138. doi: 10.13779/j.cnki.issn1001-0076.2021.06.016 |
In this paper, the effect of ultrasonic treatment on the floatability of suppressed calcite in sodium silicate and sodium oleate system was studied and the mechanism of ultrasonic treatment was explored. The test results show that the flotation recovery of calcite can be greatly increased from 7.5% to 82.1% under the conditions of ultrasonic cleaning machine power of 150 W, frequency of 40 kHz and ultrasonic treatment time of 20 min. Ultrasonic treatment can reduce the pH value of pulp and increase the overall temperature of pulp, but the range of change does not affect the floatability of calcite. Increasing the temperature of water medium in ultrasonic cleaning machine has a synergistic effect on improving the floatability of calcite. Under the conditions of 150 W power, 40 kHz frequency, 10 min ultrasonic time and 70 ℃ water medium temperature, the flotation recovery of calcite can reach 86.2%. Ultrasound can selectively weaken the inhibitory effect of sodium silicate on calcite, but does not affect the collection effect of sodium oleate on calcite. Ultrasonic treatment can promote the dissolution of sodium silicate adsorbed on calcite surface, but has little effect on sodium oleate adsorbed on calcite surface.
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X-ray diffraction pattern of calcite powder
Flotation flow chart
Effect of sodium oleate concentration (a), pH(b) and sodium silicate dosage (c) on flotation recovery of calcite
Effect of ultrasonic cleaning machine power (a) and ultrasonic processing time (b) on flotation recovery of calcite
Effect of ultrasonic cleaning machine power (a)、(c)and ultrasonic processing time (b) on pH value of pulp
Hydrolytic component analysis of sodium silicate
Effect of ultrasonic cleaning machine power (a)、(c)and ultrasonic processing time (b) on pulp temperature
Effect of ultrasonic medium temperature on flotation recovery of calcite
Effect of ultrasonic cleaning machine power (a) and ultrasonic treatment time (b) on calcite flotation recovery in sodium oleate system
Effect of ultrasonic treatment (ultrasonic cleaning machine power (a) and ultrasonic treatment time (b)) sodium silicate on calcite flotation recovery
Effect of ultrasonic treatment on the conductivity of deionized water, calcium silicate solution and calcium oleate solution