Research Progress on Adsorption of Heavy Metal ions from Water by Hydrotalcite/Bentonite

CHENG Bingbing; YU Chang; MO Wei; HE Chunyan; HUANG Yuhua

doi:10.13779/j.cnki.issn1001-0076.2021.06.010

2021 Vol. 41, No. 6

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Article navigation > Conservation and Utilization of Mineral Resources > 2021 > 41(6): 88-95

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CHENG Bingbing, YU Chang, MO Wei, HE Chunyan, HUANG Yuhua. Research Progress on Adsorption of Heavy Metal ions from Water by Hydrotalcite/Bentonite[J]. Conservation and Utilization of Mineral Resources, 2021, 41(6): 88-95. doi: 10.13779/j.cnki.issn1001-0076.2021.06.010

Citation:

CHENG Bingbing, YU Chang, MO Wei, HE Chunyan, HUANG Yuhua. Research Progress on Adsorption of Heavy Metal ions from Water by Hydrotalcite/Bentonite[J]. Conservation and Utilization of Mineral Resources, 2021, 41(6): 88-95. doi: 10.13779/j.cnki.issn1001-0076.2021.06.010

Research Progress on Adsorption of Heavy Metal ions from Water by Hydrotalcite/Bentonite

School of Resources, Environment and Materials, Guangxi University, Nanning 530004, Guangxi, China

More Information

Corresponding author: MO Wei, mowei1616@163.com

Received Date: 23 September 2021

Publish Date: 25 December 2021

Abstract

Abstract

Both hydrotalcite and bentonite are clay materials with special layered structures. Among them, hydrotalcite has good anion exchange properties, while bentonite has good cation exchange properties. In recent years, these two kinds of materials have attracted much attention in water treatment. In this paper, the structure and properties of hydrotalcite and bentonite were summarized, and the application of hydrotalcite, bentonite and their modified materials in the treatment of wastewater containing heavy metal ions such as Pb²⁺, Cd²⁺, Zn²⁺, Cu²⁺ and HAsO₄^2-、Cr₂O₇^2- were introduced emphatically. The results showed that the hydrotalcite roasting products had good adsorption capacity for complex anions (such as HAsO₄^2- and Cr₂O₇^2-) in water, and the adsorption mechanism was mainly interlayer ion exchange. Hydrotalcite after organic or inorganic modification treatment also had good adsorption performance of heavy metal cation (such as Pb²⁺, Cd²⁺, Zn²⁺, Cu²⁺, etc.), and it was likely to exist surface complexation, precipitation, isomorphic substitution, electrostatic attraction and physical adsorption at the same time during adsorption process. Compared with natural bentonite, activated modified bentonite, inorganic modified bentonite, organic modified bentonite or inorganic-organic compound modified bentonite usually had better adsorption performance, and the adsorption was usually physical adsorption, ion exchange, chemical bond or surface complexation. However, the modified hydrotalcite or bentonite was easy to cause secondary pollution to the environment, and it was not conducive to the recycling of adsorbent. Therefore, it was of great significance to research and develop single or composite adsorption materials of hydrotalcite or bentonite with high efficiency and environmental protection.
- hydrotalcite-like /
- bentonite /
- heavy metal ion /
- adsorption

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References

[1]	李天国, 徐晓军, 聂蕊, 等. 有色金属采选废水的来源、特征、危害及净化技术研究进展[J]. 化工进展, 2015(10): 3769-3778. Google Scholar
[2]	王自超. 车河选厂硫化矿浮选废水处理及回用研究[D]. 北京: 北京有色金属研究总院, 2012. Google Scholar
[3]	MARIA SELENE BERBER-MENDOZA, ROBERTO LEYVA-RAMOS, PEDRO ALONSO-DAVILA. Effect of pH and temperature on the ion-exchange isotherm of Cd (Ⅱ) and Pb(Ⅱ) on clinoptilolite[J]. Chemical Technology and Biotechnology, 2006, 81: 966-973. doi: 10.1002/jctb.1483 CrossRef Google Scholar
[4]	U. KUMAR, M. BANDYOPADHYAY. Sorption of cadmium from aqueous solution using pretreated rice husk[J]. Bioresour Technol, 2006, 97: 104-109. doi: 10.1016/j.biortech.2005.02.027 CrossRef Google Scholar
[5]	E. MORTARGES. Intercalation of Al³⁺ polyethylerexide complex into mortmmorillonite clay[J]. Clay minerals, 1995, 43(4): 1121-1123. Google Scholar
[6]	WU M J, WU J Z, ZHANG J, et al. A review on fabricating heterostructures from layered double hydroxides for enhanced photocatalytic activities[J]. Catalysis Science & Technology, 2018, 8: 1207-1228. Google Scholar
[7]	KOVANDA F, EVA JINDOVÁ, LANG K, et al. Preparation of layered double hydroxides intercalated with organic anions and their application in LDH/poly (butyl methacrylate) nanocomposites[J]. Applied Clay Science, 2010, 48(1-2): 260-270. doi: 10.1016/j.clay.2009.11.012 CrossRef Google Scholar
[8]	季桂娟, 张培萍, 姜桂兰. 膨润土加工与应用[M]. 北京: 化学工业出版社, 2013. Google Scholar
[9]	王钺博. 蒙脱石多孔异质结构与表面性质调控及其对气态有机分子吸附的影响[D]. 广州: 中国科学院研究生院(广州地球化学研究所), 2016. Google Scholar
[10]	彭同江, 孙红娟, 罗利明. 膨润土的矿物学特征与可控改造技术研究[J]. 矿产保护与利用, 2019, 39(6): 93-100. Google Scholar
[11]	KAMBLE S P, DIXIT P, RAYALU S S, et al. Defluoridation of drinking water using chemically modified bentonite clay[J]. Desalination, 2009, 249(2): 687-693. doi: 10.1016/j.desal.2009.01.031 CrossRef Google Scholar
[12]	INGLEZAKIS V J, STYLIANOU M, LOIZIDOU M. Ion exchange and adsorption equilibrium studies on clinoptilolite, bentonite and vermiculite[J]. Journal of Physics & Chemistry of Solids, 2010, 71(3): 279-284. Google Scholar
[13]	VIEIRA M, AFA NETO, GIMENES M L, et al. Sorption kinetics and equilibrium for the removal of nickel ions from aqueous phase on calcined Bofe bentonite clay[J]. Journal of Hazardous Materials, 2010, 177(1-3): 362-371. doi: 10.1016/j.jhazmat.2009.12.040 CrossRef Google Scholar
[14]	王鹏瑞, 杨丹, 张雪, 等. 钙铝和铁铝水滑石的制备及其吸附水中六价铬的性能[J]. 中国粉体技术, 2021, 27(3): 59-67. Google Scholar
[15]	徐文皓, 朱健, 王平, 等. Mg-Al水滑石的制备及对Cr(Ⅵ)阴离子吸附效果研究[J]. 中国农学通报, 2015, 31(16): 212-217. doi: 10.11924/j.issn.1000-6850.casb15010108 CrossRef Google Scholar
[16]	XILIN WU, XIAOLI TAN, SHITONG YANG, et al. Coexistence of adsorption and coagulation processes of both arsenate and NOM from contaminated groundwater by nanocrystallined Mg/Al layered double hydroxides[J]. water research, 2013, 47: 4159-4168. doi: 10.1016/j.watres.2012.11.056 CrossRef Google Scholar
[17]	GUO Y, ZHU Z, QIU Y, et al. Adsorption of arsenate on Cu/Mg/Fe/La layered double hydroxide from aqueous solutions[J]. Journal of Hazardous Materials, 2012, 239-240(15): 279-288. Google Scholar
[18]	POUDEL M B. Novel insight into the adsorption of Cr(Ⅵ) and Pb(Ⅱ) ions by MOF derived Co-Al layered double hydroxide @hematite nanorods on 3D porous carbon nanofiber network[J]. Chemical Engineering Journal, 2021(11): 129312. Google Scholar
[19]	李嘉丽, 周书葵, 李智东, 等. 功能化水滑石的构筑及其在重金属处理中的研究进展[J]. 应用化工, 2020, 49(2): 420-425. doi: 10.3969/j.issn.1671-3206.2020.02.034 CrossRef Google Scholar
[20]	MANUEL SÀNCHEZ-CANTÙ, JOSÈ ALBERTO GALICIA-AGUILAR, DEISY SANTAMARÍA-JUÁREZ, et al. Evaluation of the mixed oxides produced from hydrotalcite-like compound's thermal treatment in arsenic uptake[J]. Applied Clay Science, 2016(121/122): 146-153. Google Scholar
[21]	N. N. DAS, J. KONAR, M. K. MOHANATA, et al. Adsorption of Cr (Ⅵ) and Se (Ⅳ) from their aqueous solutions onto Zr4+ substituted ZnAl/MgAl-layered double hydroxides: effect of Zr4+ substitution in the layer[J]. Journal of Colloid and Interface Science, 2004, 270(1): 1-8. doi: 10.1016/S0021-9797(03)00400-4 CrossRef Google Scholar
[22]	张颖新. 改性水滑石对Cr(Ⅵ)、Mn(Ⅱ)的吸附研究[D]. 武汉: 华中科技大学, 2015. Google Scholar
[23]	RICARDO ROJAS, M. ROSARIO PEREZ, EUSTAQUIO M. ERRO, et al. EDTA modified LDHs as Cu²⁺ scavengers: removal kinetics and sorbent stability[J]. Colloid and interface Science, 2009, 331(2): 425-431. doi: 10.1016/j.jcis.2008.11.045 CrossRef Google Scholar
[24]	GONG H, LI H, TAN L, et al. In Situ Growth of Layered Double Hydroxides on Sawdust for Pb(Ⅱ) Adsorption[J]. Chemistry Select, 2019, 4(19): 5386-8393. Google Scholar
[25]	LIANG XUEFENG, HOU WANGUO, XU YINGMING, et al. Sorption of lead ion by latered double hydroxide intercalated with diethylenetri aminepentaacetic acid[J]. Colloid Surface, 2010, 366(1/2/3): 50-57. Google Scholar
[26]	谢沅沅. 磁性碳/镁铁水滑石纳米材料选择性去除Cu(Ⅱ)和Pb(Ⅱ)的研究[D]. 长沙: 湖南大学, 2019. Google Scholar
[27]	袁良霄, 刘有才, 黄叶钿, 等. Zn/Al类水滑石磁性生物炭复合材料的制备及其对Pb²⁺的吸附性能[J]. 环境科技, 2020, 33(2): 38-43. doi: 10.3969/j.issn.1674-4829.2020.02.009 CrossRef Google Scholar
[28]	田莉玉, 王玉洁, 刘淑芹. 膨润土作为药用赋形剂对Pb²⁺, Cd²⁺, Cr⁶⁺离子的吸附研究[J]. 吉林地质, 2008(2): 104-105. doi: 10.3969/j.issn.1001-2427.2008.02.023 CrossRef Google Scholar
[29]	杨萃娜. 膨润土对电镀废水中重金属离子的吸附研究[D]. 邯郸: 河北工程大学, 2008. Google Scholar
[30]	王忠安, 朱一民, 魏德洲, 等. 钙基膨润土吸附废水中锌离子的研究[J]. 有色矿冶, 2006(2): 45-47+63. doi: 10.3969/j.issn.1007-967X.2006.02.016 CrossRef Google Scholar
[31]	孙鑫淮, 刘峙嵘. 钠基膨润土对水相中锌离子的吸附性能研究[J]. 广州化工, 2010, 38(8): 167-169. doi: 10.3969/j.issn.1001-9677.2010.08.060 CrossRef Google Scholar
[32]	ESMAEILI A, ESLAMI H. Efficient removal of Pb(Ⅱ) and Zn(Ⅱ) ions from aqueous solutions by adsorption onto a native natural bentonite[J]. MethodsX, 2019, 6: 1979-1985. doi: 10.1016/j.mex.2019.09.005 CrossRef Google Scholar
[33]	ZHEN M U, MENG X G, ISLAM R, et al. ADSORPTION PERFORMANOE OF HEAVY METAL CADMIUM BY BIOCHAR AND BENTONITE[J]. Environmental Engineering, 2019, 37(11): 92-97+58. Google Scholar
[34]	CHOUMANE F Z, BENGUELLA B. Effects of Algerian Clays Properties on the Adsorption of Cd (Ⅱ)[J]. Journal of Environmentally Friendly Processes, 2013, 2(1): 10-25. Google Scholar
[35]	BARKAT M, CHEGROUCHE S, MELLAH A, et al. Application of algerian bentonite in the removal of cadmium (Ⅱ) and chromium (Ⅵ) from aqueous solutions[J]. Journal of Surface Engineered Materials & Advanced Technology, 2014, 4(4): 210-226. Google Scholar
[36]	徐媛媛, 辛晓东, 郑显鹏, 等. 改性膨润土吸附重金属离子的研究与应用进展[J]. 工业水处理, 2009, 29(5): 1-4. doi: 10.3969/j.issn.1005-829X.2009.05.001 CrossRef Google Scholar
[37]	孙长顺, 金奇庭, 郭新超, 等. 无机柱撑膨润土对有机锡废水中锡的吸附研究[J]. 环境污染与防治, 2007(10): 749-753. doi: 10.3969/j.issn.1001-3865.2007.10.007 CrossRef Google Scholar
[38]	邹成龙, 梁吉艳, 姜伟, 等. 改性膨润土吸附处理重金属离子的研究进展[J]. 安徽农业科学, 2017, 45(10): 53-55. doi: 10.3969/j.issn.0517-6611.2017.10.018 CrossRef Google Scholar
[39]	刘力章, 马少健. 废水处理用膨润土改性方法综述[J]. 有色矿冶, 2005(S1): 110-112. Google Scholar
[40]	NASEEM R, TAHIR S S. Removal of Pb (Ⅱ) from aqueous/acidic solutions by using bentonite as an adsorbent[J]. 2001, 35(16): 3982-3986. Google Scholar
[41]	肖利萍, 孙晓明, 潘纯林, 等. 焙烧颗粒膨润土的制备及其对废水中Mn²⁺的吸附研究[J]. 给水排水, 2011, 47(3): 133-135. Google Scholar
[42]	李梦耀, 钱会. 膨润土的改性及吸附Hg(Ⅱ)、Pb(Ⅱ)的研究[J]. 中国非金属矿工业导刊, 2006(5): 49-51. Google Scholar
[43]	胡恭任, 于瑞莲. 酸改性膨润土处理含铅废水[J]. 中国矿业, 2007(2): 100-102. Google Scholar
[44]	王代芝, 姬艳萍. 酸改性膨润土处理含铅废水的研究[J]. 中国非金属矿工业导刊, 2005(2): 44-46. Google Scholar
[45]	PAWAR R R, LALHMUNSIAMA, BAJAJ H C, et al. Activated bentonite as a low-cost adsorbent for the removal of Cu(Ⅱ) and Pb(Ⅱ) from aqueous solutions: Batch and column studies[J]. Journal of Industrial & Engineering Chemistry, 2016, 34: 213-223. Google Scholar
[46]	穆文菲. 膨润土处理重金属离子废水的研究进展[J]. 化工中间体, 2012, 9(7): 27-30. Google Scholar
[47]	范远, 陈金思. 三氯化铁改性膨润土对铬(Ⅵ)的吸附性能研究[J]. 山东化工, 2010, 39(8): 8-11+14. Google Scholar
[48]	庞婷雯, 杨志军, 黄逸聪, 等. 巯基化、钠化和酸化膨润土对Cu²⁺, Pb²⁺和Zn²⁺的吸附性能研究[J]. 光谱学与光谱分析, 2018, 38(4): 1203-1208. Google Scholar
[49]	李媛媛, 董泳秀, 刘文华, 等. 巯基化膨润土对As³⁺的吸附解吸性能研究[J]. 环境保护科学, 2015, 41(1): 104-108. Google Scholar
[50]	李志娟, 刘广军, 刘海燕. 系列改性膨润土处理含铜废水的应用研究[J]. 广东化工, 2015, 42(5): 18-19+9. Google Scholar
[51]	任广军, 王颖, 王昕, 张春丽. Fe-Al柱撑膨润土对水溶液中铅离子的吸附性能研究[J]. 材料保护, 2007(8): 79-81+88. Google Scholar
[52]	邹成龙, 聂发辉, 鲁秀国, 等. 羟基铝柱撑膨润土对水中Cr(Ⅵ)的吸附性能研究[J]. 化工新型材料, 2021, 49(1): 184-189. Google Scholar
[53]	向宇思阳, 王桂萍. AlCl₃改性膨润土处理TNT废水的试验研究[J]. 工业水处理, 2020, 40(7): 80-82+86. Google Scholar
[54]	肖讴, 李晓军, 王大勇. 羟基铁铝柱撑膨润土对水溶液中高氯酸盐的吸附性能研究[C]//中国环境科学学会环境工程分会. 中国环境科学学会2019年科学技术年会——环境工程技术创新与应用分论坛论文集(四). 中国环境科学学会环境工程分会: 《环境工程》编辑部, 2019: 7. Google Scholar
[55]	王彦, 胥学鹏. 有机改性膨润土吸附锌离子的性能[J]. 环境保护科学, 2010, 36(2): 31-33. Google Scholar
[56]	唐玮媛. 改性膨润土深度处理重金属废水技术研究[D]. 邯郸: 河北工程大学, 2014. Google Scholar
[57]	钟如怀, 李振宇. 有机改性膨润土对镉离子及苯酚的吸附性能研究[J]. 中国石油和化工标准与质量, 2019, 39(3): 59-60. Google Scholar
[58]	LIN Z, YANG Y, LIANG Z, et al. Preparation of chitosan/calcium alginate/bentonite composite hydrogel and its heavy metal Ions adsorption properties[J]. Polymers, 2021, 13(11): 1891. Google Scholar
[59]	JIN SU, HUAI GUO HUANG, XIAO YING JIN, et al. Synthesis, characterization and kinetic of a surfactant modified bentonite used to remove As(Ⅲ)and As(Ⅴ) from aqueous solution[J]. Journal of Hazardous Materials, 2011, (185): 63-70. Google Scholar