Citation: | ZHU Rui, LI Chunquan, DING Tianle, SUN Zhiming, ZHENG Shuilin. Characteristics of Kaolinite and Research Progress of its Composite Catalytic Materials[J]. Conservation and Utilization of Mineral Resources, 2021, 41(6): 57-65. doi: 10.13779/j.cnki.issn1001-0076.2021.06.007 |
In recent years, kaolinite-based composite catalytic materials have been widely used in light/electrolytic water hydrogen production, fluidized catalytic cracking, wastewater and waste gas treatment and environmental antibacterial due to their low cost, excellent chemical stability, and high-efficiency catalytic performance. Its renewable cycle characteristics and excellent performance can contribute to the construction of clear waters and green mountains as well as help to achieve the carbon peaking and carbon neutrality goals. In this paper, the latest progress of kaolinite-based catalytic materials in different catalytic fields and their synthesis and application are reviewed. The application of kaolinite-based photocatalytic materials, kaolinite for catalytic cracking, kaolinite-based persulfate active materials, kaolinite-based H2O2 active materials and electrocatalytic materials are mainly introduced. Meanwhile, the action mechanism and application form of kaolinite in various catalytic materials are also introduced. Finally, the development of kaolinite-based catalytic materials in the field of environmental purification and energy was summarized and prospected.
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(a) Schematic diagram of kaolinite solving TiO2 agglomeration[21]; (b) Schematic diagram of kaolinite multi-layer structure and carrier transport channel strategy[22]; (c) Schematic diagram of interfacial adsorption process of melamine modified g-C3N4/ kaolinite composite[23]; (d) Schematic diagram of gravity sedimentation of pure α-FeOOH and α-FeOOH/kaolinite composite
(a) Catalytic process of kaolinite-based catalytic cracking material; (b) Texture characteristics of natural kaolin and synthetic Y-type zeolite[40]
(a) Mechanism diagram of natural kaolinite/PMS system[11]; (b) Mechanism diagram of CuFe2O4/kaolinite/PMS system [54]; (c) Mechanism diagram of γ-FeOOH/N vacancies-g-C3N4/kaolinite/PMS/VIS system [57]