Citation: | QIN Yufang, WANG Qiwei, JIN Hailong, LI Na. Occurrence and Distribution of Niobium in Aegirine-type Rare Earth Ore in Bayan Obo Mine[J]. Conservation and Utilization of Mineral Resources, 2021, 41(3): 144-149. doi: 10.13779/j.cnki.issn1001-0076.2021.03.021 |
The occurrence and distribution of niobium in the aegirine-type rare earth ore in the main and east mines of Bayan Obo deposit were systematically analyzed by means of multi element analysis, Polarizing microscope, field emission scanning electron microscope, micro area energy spectrum analysis and AMICS automatic mineral analysis system. The results show that the grade of niobium (Nb2O5) in the aegirine-type rare earth ore in the main and east mines is 0.22% and 0.14% respectively, and the grade of niobium in the main ore is higher than that in the east ore. There are 82.78% and 80.21% of Nb in the aegirine-type rare earth ore of the main and east ores respectively in the form of independent minerals, such as calcite, niobite, ferroniobium rutile, pyrochlore and Baotou ore.The two niobium minerals, mainly calcite and pyrochlore, are the most widely distributed in the aegirine-type rare earth ore of the main and east mines of Bayan Obo deposit, in which the distribution rate of niobium element is generally higher than that of niobite, ferroniobium rutile and other niobium minerals.The mineral content of calcite in the main ore is higher than that in the east ore, and there is no obvious change in pyrochlore content between the main ore and the east ore. According to the above research results, it is suggested to adopt the stage grinding stage separation process of gravity separation, magnetic separation, flotation and chemical separation.
[1] | CHAKHMOUEADIAN A R, SMITH M P, KYNICKY J. From "strategic" tungsten to "green" neodymium: A century of critical metals at a glance[J]. Ore Geology Reviews, 2015, 64: 455-458. doi: 10.1016/j.oregeorev.2014.06.008 |
[2] | 蒋少涌, 温汉捷, 许成, 等. 关键金属元素的多圈层循环与富集机理: 主要科学问题及未来研究方向[J]. 中国科学基金, 2019(33): 112-118. |
[3] | 翟明国, 吴福元, 胡瑞忠, 等. 战略性关键金属矿产资源: 现状与问题[J]. 中国科学基金, 2019(33): 106-111. |
[4] | MACKAY DAR, SIMANDL GJ. Geology, market and supply chain of niobium and tantalum-a review[J]. Mineralium Deposita, 2014.49(8): 1025-1047. doi: 10.1007/s00126-014-0551-2 |
[5] | MITCHELLl RH. Primary and secondary niobium mineral deposits associated with carbonatites[J]. Ore Geology Reviews, 2015, 64: 626-641. doi: 10.1016/j.oregeorev.2014.03.010 |
[6] | 郑硌, 顾雪祥, 章永梅, 等. 安哥拉Huila省Bonga碳酸岩型铌矿床烧绿石地球化学组成、演化及其与岩浆-热液作用过程的关系. 地学前缘, 2014, 21(5): 69-89. |
[7] | 于秀兰, 刘嘉, 王之昌. 包钢选矿厂尾矿综合利用进展[J]. 矿产综合利用, 2007(3): 32-34. doi: 10.3969/j.issn.1000-6532.2007.03.009 |
[8] | 程建忠, 侯运炳, 车丽萍. 白云鄂博矿床稀土资源的合理开发及综合利用[J]稀土, 2007, 28(1): 70- 74. doi: 10.3969/j.issn.1004-0277.2007.01.019 |
[9] | 何海洋, 何敏, 李建武. 我国铌矿资源供需形势分析[J]. 中国矿业. 2018, 27(11): 1-5. |
[10] | 王维维, 杨占峰, 候少春, 等. 白云鄂博铌资源特征及开发利用新进展[J]. 矿产保护与利用. 2020(11): 49-53. |
[11] | 王建英, 文登学, 贾艳. 白云鄂博稀选尾矿中铌的回收试验[J]. 矿产综合利用, 2019(3): 121-126. doi: 10.3969/j.issn.1000-6532.2019.03.027 |
[12] | 张轰玉, 杨占峰, 焦登铭, 等. 白云鄂博主矿霓石型铌稀土铁矿石中铌在独立矿物中的富集状态和分布规律研究[J]. 有色金属(选矿部分), 2020(1) : 6 -12. doi: 10.3969/j.issn.1671-9492.2020.01.002 |
[13] | 侯晓志, 杨占峰, 王振江, 等. 白云鄂博矿萤石型铁矿石中钍的赋存状态及分布规律研究[J]. 中国稀土学报, 2018, 36(3): 365-371. |
[14] | 侯晓志, 杨占峰, 王振江, 等. 白云鄂博矿云母型矿石中钍的赋存状态及分布规律研究[J]. 中国稀土学报, 2018, 36(5): 633-640. |
[15] | 张国忠. 白云鄂博矿矿冶工艺学(上)[M]. 包头: 包钢头钢铁集团公司科技处, 1995. |
[16] | FRANDRICHR, GU Y, BURROWS D, et al. Modern SEM-basedmineral liberation analysis[J]. International Journal ofMineral Processing, 2007, 84: 310-320. doi: 10.1016/j.minpro.2006.07.018 |
[17] | GU Y. Automated scanning electron microscope based mineralliberation analysis[J]. Journal of Minerals and Materials Characterization and Engineering, 2003(2): 33-41. |
[18] | 王绍华, 杨占峰, 王振江. 白云鄂博尾矿中铌、稀土的赋存状态研究[J]. 有色金属工程, 2019, 9(11): 60-66. |
[19] | 刘牡丹, 刘勇, 刘珍珍. 复杂稀有金属伴生矿资源的综合利用现状[J]. 稀有金属与硬质合金, 2015, 43(6): 24-27. |
[20] | 徐广尧. 包头铌资源综合利用关键技术研究[C]//2007年中国稀土资源综合利用与环境保护研讨会论文集. 海口: 中国稀土学会地采选专业委员会, 2007: 16-21. |
[21] | 张培善, 杨主明, 陶克捷. 我国铌钽稀土矿物学及工业利用[J]. 稀有金属, 2005, 29(2): 206-210. |
[22] | 杨主明, 宋仁奎, 陶克捷, 等. 易解石族矿物的稀土成分变化特征[J]. 中国稀土学报. 2003, 21(6): 716-720. doi: 10.3321/j.issn:1000-4343.2003.06.023 |
[23] | BAMBI A C J M, COSTANZO A, GONCALVES A O, et al. Tracing the chemical evolution of primary pyrochlore from plutonic to volcanic carbonatites: the role of fluorine[J]. Mineralogical Magazine, 2012, 76(2): 377-392. doi: 10.1180/minmag.2012.076.2.07 |
FESEM backscattered electron image of niobite
FESEM backscattered electron image of ferroniobium rutile
FESEM backscattered electron images of calcite
FESEM backscattered electron image of pyrochlore