Citation: | MA Xiaoxiao, WANG Yubin, HUA Kaiqiang, LI Shuqin, LI Liang. Effect of Sodium Hexametaphosphate on Preparation of Ultrafine Gypsum Powder and Its Mechanism[J]. Conservation and Utilization of Mineral Resources, 2021, 41(1): 146-151. doi: 10.13779/j.cnki.issn1001-0076.2021.01.021 |
Ultrafine gypsum powder was prepared with sodium hexametaphosphate as a grinding agent by colloid mill, and ultra-fine grinding products were characterized through methods such as laser particle size analysis and XRD. The results showed that when the slurry concentration was 20%, and the discharge width was 12 mm, and the dosage of sodium hexametaphosphate was 0.20%, and the ultrafine grinding time was 15 min, the superfine gypsum powder with d50 of 11.12 μm could be obtained. Moreover, the change of grain size and micro-strain of gypsum particles caused by ultra-fine grinding damage the lattice, resulting in the decrease of crystallinity ultrafine grinding products and the tendency of amorphous. In addition, hydrogen phosphate ions could be adsorbed on the surface of gypsum particles to make the ζ potential of gypsum surface shifted from -8.83 mV to -13.39 mV, and the turbidity of gypsum slurry increased from 13 NTU to 17 NTU while its viscosity decreased from 72.49 mPa·s to 48.91 mPa·s, which promotes the dispersion of gypsum particles. Under the combined action of the above factors, the particle size of superfine gypsum powder was reduced and the superfine grinding efficiency of gypsum was improved. The research has certain reference significance for preparing ultrafine gypsum powder and improving the quality of ultrafine gypsum powder.
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The XRD pattern of gypsum
Test flow chart
Effect of dosage of sodium hexametaphosphate on the size of gypsum
XRD patterns of gypsum ultrafine grinding products
Effect of dosage of sodium hexametaphosphate on the half-peak width and crystallinity of gypsum
Effect of dosage of sodium hexametaphosphate on the grain size and microscopic strain of gypsum
Relationship between distribution coefficient of sodium hexametaphosphate and pH value
Effect of dosage of sodium hexametaphosphate on surface potential of gypsum (a)、slurry turbidity (b) and slurry viscosity (c)