Citation: | XU Zuoxing, QIAN Gongming, LIU Lulu, LIU Wei, CAI Xianyan, FENG Junyan. Study on Mechanism of Lead Ion Removed by Hydroxyapatite (HAP)[J]. Conservation and Utilization of Mineral Resources, 2020, 40(1): 37-41. doi: 10.13779/j.cnki.issn1001-0076.2020.01.006 |
Lead ions were removed by using HAP prepared by chemical precipitation method. Morphology of Hydroxyapatite (HAP) was observed by SEM, EDS and XRD. The results showed that the reaction mechanism of lead removal was mainly precipitation and ion exchange at pH=3, and precipitation and hydrolysis at pH=5. The removal rate of lead was positively correlated with pH value and reaction temperature of the solution, negatively correlated with the initial lead ion concentration of the solution, and the reaction process was a complicated multistage reaction. When pH=4, the removal rate of lead ions is close to 99%, while the lead ions in aqueous solution drop below the prescribed emission standard (1 mg / L).
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Lead removal rate of HAP at different reaction times
Lead removal rate of HAP under different pH values
SEM images of HAP at different pH values:(a) initial HAP; (b) pH=3;(c) pH=5
EDS image of Ca2+ on HAP surface at different pH values:(a) initial HAP; (b) pH=3;(c) pH=5
EDS image of Pb2+ on HAP surface at different pH values:(a) initial HAP; (b) pH=3;(c) pH=5
Changes of Ca2+ and Pb2+ contents at HAP surface under different pH values
XRD patterns of the main products at different pH values:(a) initial HAP; (b) pH=3;(c) pH=5