METALLOGENIC REGULARITY AND PROSPECTING OF BORON DEPOSITS IN EASTERN LIAONING-SOUTHERN JILIN METALLOGENIC BELT

ZHAO Yan; XIE Yuan-hong; XIN Hou-tian; GAO Rong-zhen; ZHANG Yan-fei; LIANG Shuai; CHEN Jing-sheng; YANG Zhong-zhu; WU Xin-wei

doi:10.13686/j.cnki.dzyzy.2024.04.005

2024 Vol. 33, No. 4

Article Contents

Article navigation > Geology and Resources > 2024 > 33(4): 493-508

Next Article Previous Article

ZHAO Yan, XIE Yuan-hong, XIN Hou-tian, GAO Rong-zhen, ZHANG Yan-fei, LIANG Shuai, CHEN Jing-sheng, YANG Zhong-zhu, WU Xin-wei. METALLOGENIC REGULARITY AND PROSPECTING OF BORON DEPOSITS IN EASTERN LIAONING-SOUTHERN JILIN METALLOGENIC BELT[J]. Geology and Resources, 2024, 33(4): 493-508. doi: 10.13686/j.cnki.dzyzy.2024.04.005

Citation:

ZHAO Yan, XIE Yuan-hong, XIN Hou-tian, GAO Rong-zhen, ZHANG Yan-fei, LIANG Shuai, CHEN Jing-sheng, YANG Zhong-zhu, WU Xin-wei. METALLOGENIC REGULARITY AND PROSPECTING OF BORON DEPOSITS IN EASTERN LIAONING-SOUTHERN JILIN METALLOGENIC BELT[J]. Geology and Resources, 2024, 33(4): 493-508. doi: 10.13686/j.cnki.dzyzy.2024.04.005

METALLOGENIC REGULARITY AND PROSPECTING OF BORON DEPOSITS IN EASTERN LIAONING-SOUTHERN JILIN METALLOGENIC BELT

1.
Shenyang Center of China Geological Survey, Shenyang 110034, China
2.
Northeast Geological S&T Innovation Center of China Geological Survey, Shenyang 110034, China
3.
Liaoning Chemical Geological Prospecting Institute Co., Ltd., Jinzhou 121000, Liaoning Province, China
4.
School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China

Received Date: 25 February 2024

Revised Date: 01 June 2024

Publish Date: 25 August 2024

Abstract

Abstract

The eastern Liaoning-southern Jilin metallogenic belt is the leading site of hard rock-type boron deposit in China. Based on the previous research results of Precambrian geology, Jiao-Liao-Ji orogenic belt, as well as metallogenesis, the paper summarizes the coupling relationship between Paleoproterozoic orogeny and boron metallogenic events in eastern Liaoning region, and establishes the metallogenic model of boron deposits in eastern Liaoning-southern Jilin metallogenic belt. With the field survey on the typical boron deposits of Houxianyu, Wengquangou and Zhuanmiao-Yangmugan, the previous B and Mg isotopic data of the deposits are summarized and drawn for analysis. The results show that the boron deposits have experienced three main processes, i.e. early enrichment, mineralization during Paleoproterozoic orogeny and later reformation. Mg-rich marble and initially enriched B are the main ore-forming material sources. The basic and ultrabasic rocks play an important role in trapping B-rich fluids during orogenic metamorphism and contribute some ore-forming materials. The late metamorphism destroys orebody and partially improves the grade of ores. Finally, the paper also analyzes the main factors restricting boron prospecting in eastern Liaoning region, suggests that more attention be paid on the Paleoproterozoic formation and structure mapping, structural analysis and choice of suitable exploration means. The idea of further boron ore prospecting is also discussed.
- North China Craton /
- strategic mineral /
- eastern Liaoning-southern Jilin metallogenic belt /
- boron deposit /
- metallogenic regularity /
- metallogenic model

FullText(HTML)

References

[1]	中国科学院地质研究所. 东北内生硼矿床的矿物组成和矿床成因研究[M]. 北京: 科学出版社, 1974: 1-36. Google Scholar Institute of Geology, Chinese Academy of Sciences. Mineral composition and genesis of endogenous boron deposits in Northeast China[M]. Beijing: Science Press, 1974: 1-36. (in Chinese) Google Scholar
[2]	彭齐鸣, 许虹. 辽东-吉南地区早元古宙变质蒸发岩系及硼矿床[M]. 长春: 东北师范大学出版社, 1994: 1-235. Google Scholar Peng Q M, Xu H. The Paleoproterozoic metaevaporitic and boron deposits in eastern Liaoning and southern Jilin[M]. Changchun: Northeast Normal University Press, 1994: 1-235. (in Chinese) Google Scholar
[3]	Peng Q M, Palmer M R. The Paleoproterozoic Mg and Mg-Fe borate deposits of Liaoning and Jilin provinces, Northeast China[J]. Economic Geology, 2002, 97(1): 93-108. doi: 10.2113/gsecongeo.97.1.93 CrossRef Google Scholar
[4]	刘敬党, 肖荣阁, 王文武, 等. 辽东硼矿区域成矿模型[M]. 北京: 地质出版社, 2007: 1-246. Google Scholar Liu J D, Xiao R G, Wang W W, et al. Regional metallogenesis of borate deposit in eastern Liaoning, China[M]. Beijing: Geology Press, 2007: 1-246. Google Scholar
[5]	林秋婷, 陈晨, 刘海洋. 硼的地球化学性质及其在俯冲带的循环与成矿初探[J]. 岩石学报, 2020, 36(1): 5-12. Google Scholar Lin C, Chen C, Liu H Y. Boron prospecting based on boron cycling in subduction zone[J]. Acta Petrologica Sinica, 2020, 36(1): 5-12. Google Scholar
[6]	焦森, 郑厚义, 屈云燕, 等. 全球硼矿资源供需形势分析[J]. 国土资源情报, 2020(10): 85-89. doi: 10.3969/j.issn.1674-3709.2020.10.015 CrossRef Google Scholar Jiao S, Zheng H Y, Qu Y Y, et al. Supply and demand situation of global boron resources[J]. Land and Resources Information, 2020(10): 85-89. doi: 10.3969/j.issn.1674-3709.2020.10.015 CrossRef Google Scholar
[7]	姜春潮. 辽吉东部前寒武纪地质[M]. 沈阳: 辽宁科学技术出版社, 1987: 281-287. Google Scholar Jiang C C. Precambrian geology of the eastern part of Liaoning and Jilin[M]. Shenyang: Liaoning Science and Technology Publishing House, 1987: 281-287. (in Chinese) Google Scholar
[8]	陈荣度. 辽东裂谷的地质构造演化[J]. 中国区域地质, 1990(4): 306-315, 333. Google Scholar Chen R D. The tectonic evolution of the Liaodong rift[J]. Regional Geology of China, 1990(4): 306-315, 333. Google Scholar
[9]	白瑾, 黄学光, 王惠初, 等. 中国前寒武纪地壳演化[M]. 2版. 北京: 地质出版社, 1996: 28-127. Google Scholar Bai J, Huang X G, Wang H C, et al. Evolution of the crust in Precambrian of China[M]. 2nd ed. Beijing: Geological Publishing House, 1996: 28-127. (in Chinese) Google Scholar
[10]	张艳飞, 刘敬党, 王刚, 等. 辽东地区硼矿床区域成矿系统分析[J]. 地质与勘探, 2011, 47(4): 605-614. Google Scholar Zhang Y F, Liu J D, Wang G, et al. Analysis of the metallogenic system for borate deposits in eastern Liaoning Province[J]. Geology and Exploration, 2011, 47(4): 605-614. Google Scholar
[11]	翟明国, 张连昌, 陈斌, 等. 华北克拉通前寒武纪重大地质事件与成矿[M]. 北京: 科学出版社, 2018: 241-255. Google Scholar Zhai M G, Zhang L C, Chen B, et al. Precambrian major geological events and mineralization in North China Craton[M]. Beijing: Science Press, 2018: 241-255. (in Chinese) Google Scholar
[12]	李东涛, 张朋, 赵岩, 等. 辽东-吉南成矿带地质背景与矿产[M]. 北京: 地质出版社, 2021: 1-56. Google Scholar Li D T, Zhang P, Zhao Y, et al. Geological setting and mineral resources of the Liaodong-Ji'nan metallogenic belt[M]. Beijing: Geological Publishing House, 2021: 1-56. (in Chinese) Google Scholar
[13]	Helvaci C, Alonso R N. Borate deposits of Turkey and Argentina: A summary and geological comparison[J]. Turkish Journal of Earth Sciences, 2000, 9(1): 1-27. Google Scholar
[14]	Helvaci C, Öztürk Y Y, Emmermann A. Fluorescence survey of Turkish borate minerals: Comparative measurements of fluorescence spectra of the most important borate mineral species, Turkey[J]. Journal of Mineralogy and Geochemistry, 2017, 194(1): 1-17. Google Scholar
[15]	Zhao G C, Cawood P A, Li S Z, et al. Amalgamation of the North China Craton: Key issues and discussion[J]. Precambrian Research, 2012, 222-223: 55-76. doi: 10.1016/j.precamres.2012.09.016 CrossRef Google Scholar
[16]	Li Z, Li J, Chen B. Early Precambrian tectono-thermal events: Coupled U-Pb-Hf of detrital zircons from Jiao-Liao-Ji belt, North China Craton[J]. Arabian Journal of Geosciences, 2018, 11(15): 424. doi: 10.1007/s12517-018-3791-0 CrossRef Google Scholar
[17]	Li Z, Wei C J, Chen B, et al. Late Neoarchean reworking of the Mesoarchean crustal remnant in northern Liaoning, North China Craton: A U-Pb-Hf-O-Nd perspective[J]. Gondwana Research, 2020, 80: 350-369. doi: 10.1016/j.gr.2019.10.020 CrossRef Google Scholar
[18]	张秋生, 杨振升, 刘连登. 辽东半岛早期地壳与矿床[M]. 北京: 地质出版社, 1988: 1-574. Google Scholar Zhang Q S, Yang Z S, Liu L D. Early crust and mineral deposits of Liaodong Peninsula, China[M]. Beijing: Geological Publishing House, 1988: 1-574. Google Scholar
[19]	卢良兆, 徐学纯, 刘福来. 中国北方早前寒武纪孔兹岩系[M]. 长春: 长春出版社, 1996: 219-230. Google Scholar Lu L Z, Xu X C, Liu F L. Khondalite series in Early pre-Cambrian North China[M]. Changchun: Changchun Press, 1996: 219-230. (in Chinese) Google Scholar
[20]	李三忠, 韩宗珠, 刘永江, 等. 辽河群区域变质特征及其大陆动力学意义[J]. 地质论评, 2001, 47(1): 9-18. Google Scholar Li S Z, Han Z Z, Liu Y J, et al. Continental dynamics and regional metamorphism of the Liaohe Group[J]. Geological Review, 2001, 47(1): 9-18. Google Scholar
[21]	贺高品, 叶慧文. 辽东-吉南地区早元古代两种类型变质作用及其构造意义[J]. 岩石学报, 1998, 14(2): 152-162. doi: 10.3321/j.issn:1000-0569.1998.02.003 CrossRef Google Scholar He G P, Ye H W. Two types of Early Proterozoic metamorphism and its tectonic significance in eastern Liaoning and southern Jilin areas[J]. Acta Petrologica Sinica, 1998, 14(2): 152-162. doi: 10.3321/j.issn:1000-0569.1998.02.003 CrossRef Google Scholar
[22]	Li S Z, Zhao G C, Sun M, et al. Deformation history of the Paleoproterozoic Liaohe assemblage in the eastern block of the North China Craton[J]. Journal of Asian Earth Sciences, 2005, 24(5): 659-674. doi: 10.1016/j.jseaes.2003.11.008 CrossRef Google Scholar
[23]	Li S Z, Zhao G C, Sun M, et al. Are the South and North Liaohe groups of North China Craton different exotic terranes?Nd isotope constraints[J]. Gondwana Research, 2006, 9(1/2): 198-208. Google Scholar
[24]	Li S Z, Zhao G C, Santosh M, et al. Paleoproterozoic structural evolution of the southern segment of the Jiao-Liao-Ji belt, North China Craton[J]. Precambrian Research, 2012, 200-203: 59-73. doi: 10.1016/j.precamres.2012.01.007 CrossRef Google Scholar
[25]	白瑾. 华北陆台北缘前寒武纪地质及铅锌成矿作用[M]. 北京: 地质出版社, 1993: 47-89. Google Scholar Bai J. The Precambrian geology and Pb-Zn mineralization in the northern margin of North China platform[M]. Beijing: Geology Press, 1993: 47-89. (in Chinese) Google Scholar
[26]	王惠初, 陆松年, 初航, 等. 辽阳河栏地区辽河群中变质基性熔岩的锆石U-Pb年龄与形成构造背景[J]. 吉林大学学报(地球科学版), 2011, 41(5): 1322-1334, 1361. Google Scholar Wang H C, Lu S N, Chu H, et al. Zircon U-Pb age and tectonic setting of meta-basalts of Liaohe Group in Helan area, Liaoyang, Liaoning Province[J]. Journal of Jilin University (Earth Science Edition), 2011, 41(5): 1322-1334, 1361. Google Scholar
[27]	陈斌, 李壮, 王家林, 等. 辽东半岛~2.2 Ga岩浆事件及其地质意义[J]. 吉林大学学报(地球科学版), 2016, 46(2): 303-320. Google Scholar Chen B, Li Z, Wang J L, et al. Liaodong Peninsula~2.2 Ga magmatic event and its geological significance[J]. Journal of Jilin University (Earth Science Edition), 2016, 46(2): 303-320. Google Scholar
[28]	毕君辉, 邢德和, 葛文春, 等. 辽东地区北辽河群变酸性火山岩形成的时代及构造背景: 古元古代陆内裂谷, 还是活动大陆边缘?[J]. 地学前缘, 2018, 25(3): 295-308. Google Scholar Bi J H, Xing D H, Ge W C, et al. Age and tectonic setting of meta-acid volcanic rocks from the North Liaohe Group in the Liaodong area: Paleoproterozoic intracontinental rift or active continental margin?[J]. Earth Science Frontiers, 2018, 25(3): 295-308. Google Scholar
[29]	Li Z, Chen B, Wei C J, et al. Provenance and tectonic setting of the Paleoproterozoic metasedimentary rocks from the Liaohe Group, Jiao-Liao-Ji belt, North China Craton: Insights from detrital zircon U-Pb geochronology, whole-rock Sm-Nd isotopes, and geochemistry[J]. Journal of Asian Earth Sciences, 2015, 111: 711-732. doi: 10.1016/j.jseaes.2015.06.003 CrossRef Google Scholar
[30]	Li Z, Chen B, Wei C J. Is the Paleoproterozoic Jiao-Liao-Ji belt (North China Craton) a rift?[J]. International Journal of Earth Sciences, 2017, 106(1): 355-375. doi: 10.1007/s00531-016-1323-2 CrossRef Google Scholar
[31]	Li Z, Chen B, Yan X L. The Liaohe Group: An insight into the Paleoproterozoic tectonic evolution of the Jiao-Liao-Ji belt, North China Craton[J]. Precambrian Research, 2019, 326: 174-195. doi: 10.1016/j.precamres.2018.01.009 CrossRef Google Scholar
[32]	Yang C W, Liu J L, Yang H X, et al. Tectonics of the Paleoproterozoic Jiao-Liao-Ji orogenic belt in the Liaodong Peninsula, North China Craton: A review[J]. Journal of Asian Earth Sciences, 2019, 176: 141-156. doi: 10.1016/j.jseaes.2019.01.028 CrossRef Google Scholar
[33]	Zhao Y, Lin S F, Zhang P, et al. Geochronology and geochemical characteristics of Paleoproterozoic syn-orogenic granitoids and constraints on the geological evolution of the Jiao-Liao-Ji orogenic Belt, North China Craton[J]. Precambrian Research, 2021, 365: 106386. doi: 10.1016/j.precamres.2021.106386 CrossRef Google Scholar
[34]	Zhao Y, Lyu J C, Han X, et al. Geochronology and geological implications of Paleoproterozoic post-collisional monzogranitic dykes in the NE Jiao-Liao-Ji Belt, North China Craton[J]. Minerals, 2023, 13(7): 928. doi: 10.3390/min13070928 CrossRef Google Scholar
[35]	Peng P, Wang X P, Windley B F, et al. Spatial distribution of~1950-1800 Ma metamorphic events in the North China Craton: Implications for tectonic subdivision of the craton[J]. Lithos, 2014, 202-203: 250-266. doi: 10.1016/j.lithos.2014.05.033 CrossRef Google Scholar
[36]	Xu Z H, Sun F Y, Xin W, et al. Formation and evolution of Paleoproterozoic orogenic belt in southern Jilin, Jiao-Liao-Ji belt, North China Craton: Constraints from geophysics[J]. Precambrian Research, 2019, 333: 105433. doi: 10.1016/j.precamres.2019.105433 CrossRef Google Scholar
[37]	于泓超. 胶-辽-吉造山带吉南地区古元古代沉积-岩浆作用及构造意义[D]. 长春: 吉林大学, 2023: 1-151. Google Scholar Yu H C. Paleoproterozoic sedimentary-magmatism and its tectonic significance in the southern Jilin Province of Jiao-Liao-Ji orogenic belt[D]. Changchun: Jilin University, 2023: 1-151. Google Scholar
[38]	刘俊来, 陈小宇, 张健, 等. 大陆地壳活动带片麻岩穹隆构造与分层流变[J]. 地质学报, 2022, 96(9): 3158-3181. Google Scholar Liu J L, Chen X Y, Zhang J, et al. Gneiss domes and stratified middle to lower crustal flow in continental mobile belt[J]. Acta Geologica Sinica, 2022, 96(9): 3158-3181. Google Scholar
[39]	Cai J, Liu F L, Liu P H, et al. Discovery of granulite-facies metamorphic rocks in the Ji'an area, northeastern Jiao-Liao-Ji belt, North China Craton: Metamorphic P-T evolution and geological implications[J]. Precambrian Research, 2017, 303: 626-640. doi: 10.1016/j.precamres.2017.08.018 CrossRef Google Scholar
[40]	Liu P H, Liu F L, Tian Z H, et al. Petrological and geochronological evidence for Paleoproterozoic granulite-facies metamorphism of the South Liaohe Group in the Jiao-Liao-Ji belt, North China Craton[J]. Precambrian Research, 2019, 327: 121-143. doi: 10.1016/j.precamres.2019.03.002 CrossRef Google Scholar
[41]	Wang X H, Oh C W, Wang X P, et al. The~1.87 Ga granulite facies metamorphism of the South Liaohe Group in the Jiao-Liao-Ji belt and its tectonic implications[J]. Lithos, 2021, 392-393: 106081. doi: 10.1016/j.lithos.2021.106081 CrossRef Google Scholar
[42]	朱裕生, 王全明, 张晓华, 等. 中国成矿区带划分及有关问题[J]. 地质与勘探, 1999, 35(4): 1-4. Google Scholar Zhu Y S, Wang Q M, Zhang X H, et al. Some problems on division of metallogenic belts in China[J]. Geology and Prospecting, 1999, 35(4): 1-4. Google Scholar
[43]	徐志刚, 陈毓川, 王登红, 等. 中国成矿区带划分方案[M]. 北京: 地质出版社, 2008: 1-138. Google Scholar Xu Z G, Chen Y C, Wang D H, et al. Scheme of the classification of the minerogenetic units in China[M]. Beijing: Geological Publishing House, 2008: 1-138. Google Scholar
[44]	陈毓川. 中国主要成矿区带矿产资源远景评价[M]. 北京: 地质出版社, 1999: 1-536. Google Scholar Chen Y C. The prospective evaluation of mineral resources in the main metallogenic regions in China[M]. Beijing: Geological Publishing House, 1999: 1-536. (in Chinese) Google Scholar
[45]	马玉波, 邢树文, 肖克炎, 等. 辽东-吉南Fe-菱镁矿-Cu-Au成矿带主要地质成矿特征及潜力分析[J]. 地质学报, 2016, 90(7): 1298-1315. doi: 10.3969/j.issn.0001-5717.2016.07.004 CrossRef Google Scholar Ma Y B, Xing S W, Xiao K Y, et al. Geological metallogenic characteristics and resource analysis of the Liaodong-Jinan Fe-Mg-Cu-Au metallogenic belt[J]. Acta Geologica Sinica, 2016, 90(7): 1298-1315. doi: 10.3969/j.issn.0001-5717.2016.07.004 CrossRef Google Scholar
[46]	中国地质调查局, 中国地质科学院矿产资源研究所, 中国地质调查局沈阳地质调查中心. 中国重要成矿区带成矿特征、资源潜力和选区部署——辽东-吉南成矿区[M]. 北京: 中国原子能出版社, 2016: 93-193. Google Scholar China Geological Survey, Institute of Mineral Resources of Chinese Academy of Geological Sciences, Shenyang Center of China Geological Survey. Metallogenic characteristics, resources potential and area selection of important metallogenic zones in China: Liaodong-Ji'nan metallogenic zone[M]. Beijing: China Atomic Energy Press, 2016: 93-193. (in Chinese) Google Scholar
[47]	Tam P Y, Zhao G C, Liu F L, et al. Timing of metamorphism in the Paleoproterozoic Jiao-Liao-Ji belt: New SHRIMP U-Pb zircon dating of granulites, gneisses and marbles of the Jiaobei massif in the North China Craton[J]. Gondwana Research, 2011, 19(1): 150-162. doi: 10.1016/j.gr.2010.05.007 CrossRef Google Scholar
[48]	Tian Z H, Liu F L, Windley B F, et al. Polyphase structural deformation of low-to medium-grade metamorphic rocks of the Liaohe Group in the Jiao-Liao-Ji orogenic belt, North China Craton: correlations with tectonic evolution[J]. Precambrian Research, 2017, 303: 641-659. doi: 10.1016/j.precamres.2017.08.017 CrossRef Google Scholar
[49]	陈井胜, 邢德和, 刘淼, 等. 辽宁辽阳地区辽河群酸性火山岩锆石U-Pb年代学及其地质意义[J]. 岩石学报, 2017, 33(9): 2792-2810. Google Scholar Chen J S, Xing D H, Liu M, et al. Zircon U-Pb chronology and geological significance of felsic volcanic rocks in the Liaohe Group from the Liaoyang area, Liaoning Province[J]. Acta Petrologica Sinica, 2017, 33(9): 2792-2810. Google Scholar
[50]	刘军, 李铁刚, 段超. 辽宁猫岭大型金矿床成岩成矿年龄及同位素地球化学特征[J]. 地质通报, 2018, 37(7): 1325-1337. Google Scholar Liu J, Li T G, Duan C. Geochronology and isotopic geochemistry characteristics of the Maoling large gold deposit, Liaoning Province, China[J]. Geological Bulletin of China, 2018, 37(7): 1325-1337. Google Scholar
[51]	Xu W, Liu F L. Geochronological and geochemical insights into the tectonic evolution of the Paleoproterozoic Jiao-Liao-Ji belt, Sino-Korean Craton[J]. Earth-Science Reviews, 2019, 193: 162-198. doi: 10.1016/j.earscirev.2019.04.019 CrossRef Google Scholar
[52]	Zhao Y, Zhang P, Li Y, et al. Geochemistry of two types of Palaeoproterozoic granites, and zircon U-Pb dating, and Lu-Hf isotopic characteristics in the Kuandian area within the Jiao-Liao-Ji belt: Implications for regional tectonic setting[J]. Geological Journal, 2020, 55(11): 7564-7580. doi: 10.1002/gj.3869 CrossRef Google Scholar
[53]	赵岩, 张朋, 毕中伟, 等. 辽东岫岩地区两类古元古代花岗岩年代学、地球化学及地质意义[J]. 地球科学, 2020, 45(11): 4072-4090. Google Scholar Zhao Y, Zhang P, Bi Z W, et al. Geochronology and geochemistry of two types of Paleoproterozoic granites and their geological implications in the Xiuyan area, Liaodong Peninsula[J]. Earth Science, 2020, 45(11): 4072-4090. Google Scholar
[54]	赵岩, 杨宏智, 杨凤超, 等. 辽东半岛青城子矿田典型金矿成因: 来自硫、氢、氧同位素的证据[J]. 地质与资源, 2020, 29(1): 21-28. doi: 10.3969/j.issn.1671-1947.2020.01.003 CrossRef Google Scholar Zhao Y, Yang H Z, Yang F C, et al. Genesis of the typical gold deposits in Qingchengzi orefield, Liaodong Peninsula: Evidences from S-D-O isotopes[J]. Geology and Resources, 2020, 29(1): 21-28. doi: 10.3969/j.issn.1671-1947.2020.01.003 CrossRef Google Scholar
[55]	刘平华, 蔡佳, 邹雷. 辽东半岛北部三家子石榴斜长角闪岩变质演化P-T-t轨迹及其地质意义: 来自相平衡模拟与锆石U-Pb定年的约束[J]. 岩石学报, 2017, 33(9): 2649-2674. Google Scholar Liu P H, Cai J, Zou L. Metamorphic P-T-t path and its geological implication of the Sanjiazi garnet amphibolites from the northern Liaodong Peninsula, Jiao-Liao-Ji belt: Constraints on phase equilibria and zircon U-Pb dating[J]. Acta Petrologica Sinica, 2017, 33(9): 2649-2674. Google Scholar
[56]	田忠华, 刘福来, 刘超辉, 等. 多期构造变形事件对吉林南部大横路Cu-Co矿床富集成矿的制约[J]. 地质学报, 2023, 97(11): 3673-3695. Google Scholar Tian Z H, Liu F L, Liu C H, et al. Constraints of multi-stage tectonic deformational events on enrichment and mineralization of the Dahenglu Cu-Co ore deposit in southern Jilin Province[J]. Acta Geologica Sinica, 2023, 97(11): 3673-3695. Google Scholar
[57]	Misch D, Pluch H, Mali H, et al. Genesis of giant Early Proterozoic magnesite and related talc deposits in the Mafeng area, Liaoning Province, NE China[J]. Journal of Asian Earth Sciences, 2018, 160: 1-12. doi: 10.1016/j.jseaes.2018.04.005 CrossRef Google Scholar
[58]	胡古月, 孙新胜, 郑军, 等. 辽东半岛海城-大石桥菱镁矿矿床成因探讨[J]. 地质学报, 2022, 96(4): 1340-1355. doi: 10.3969/j.issn.0001-5717.2022.04.013 CrossRef Google Scholar Hu G Y, Sun X S, Zheng J, et al. The genesis of Haicheng-Dashiqiao magnesite deposits, Liaodong Peninsula[J]. Acta Geologica Sinica, 2022, 96(4): 1340-1355. doi: 10.3969/j.issn.0001-5717.2022.04.013 CrossRef Google Scholar
[59]	赵宇霆. 辽宁凤城翁泉沟地区含铀硼铁矿床成岩成矿年代学研究[D]. 北京: 中国地质大学, 2018: 1-85. Google Scholar Zhao Y T. Diagenetic and metallogenic geochronology of uranium-bearing boron iron deposit in Wengquangou area, Fengcheng, Liaoning Province[D]. Beijing: China University of Geosciences, 2018: 1-85. Google Scholar
[60]	Zhao Y, Zhang P, Yang H Z, et al. Paleoproterozoic mineralization of the Lijiapuzi gold deposit in the Liaodong Peninsula, NE China: Constraints from ⁴⁰Ar-³⁹Ar age, S-Pb isotopes, and in situ analyses[J]. Minerals, 2022, 12(8): 971. doi: 10.3390/min12080971 CrossRef Google Scholar
[61]	薛建玲, 许虹, 高一鸣, 等. 辽宁后仙峪硼矿床中电气石的矿物学特征及其成岩成矿意义[J]. 中国地质, 2006, 33(6): 1386-1392. doi: 10.3969/j.issn.1000-3657.2006.06.023 CrossRef Google Scholar Xue J L, Xu H, Gao Y M, et al. Mineralogical characteristics of tourmaline in the Houxianyu boron deposit in Liaoning and their significance for rock and ore formation[J]. Geology in China, 2006, 33(6): 1386-1392. doi: 10.3969/j.issn.1000-3657.2006.06.023 CrossRef Google Scholar
[62]	李雪梅, 孙丰月, 李碧乐, 等. 辽东地区后仙峪及翁泉沟硼矿床流体包裹体特征研究[J]. 现代地质, 2007, 21(4): 645-653. doi: 10.3969/j.issn.1000-8527.2007.04.009 CrossRef Google Scholar Li X M, Sun F Y, Li B L, et al. Study on the fluid inclusions from Houxianyu and Wengquangou borate deposits in eastern Liaoning Province[J]. Geoscience, 2007, 21(4): 645-653. doi: 10.3969/j.issn.1000-8527.2007.04.009 CrossRef Google Scholar
[63]	王翠芝, 肖荣阁, 刘敬党. 辽东硼矿的成矿机制及成矿模式[J]. 地球科学——中国地质大学学报, 2008, 33(6): 813-824. Google Scholar Wang C Z, Xiao R G, Liu J D. Ore-forming genesis and model of Eastern Liaoning borate deposits[J]. Earth Science-Journal of China University of Geosciences, 2008, 33(6): 813-824. Google Scholar
[64]	邹日, 冯本智. 营口后仙峪硼矿容矿火山-热水沉积岩系特征[J]. 地球化学, 1995, 24(S1): 46-54. Google Scholar Zou R, Feng B Z. The features of ore-hosting volcanic-hydrothermal sedimentary series in Houxianyu boron deposits, Yingkou, Liaoning[J]. Geochimica, 1995, 24(S1): 46-54. Google Scholar
[65]	肖荣阁, 大井隆夫, 费红彩, 等. 辽东地区沉积变质硼矿床及硼同位素研究[J]. 现代地质, 2003, 17(2): 137-142. doi: 10.3969/j.issn.1000-8527.2003.02.004 CrossRef Google Scholar Xiao R G, Takao O, Fei H C, et al. Sedimentary-metamorphic boron deposits and their boron isotopic compositions in eastern Liaoning Province[J]. Geoscience, 2003, 17(2): 137-142. doi: 10.3969/j.issn.1000-8527.2003.02.004 CrossRef Google Scholar
[66]	夏学惠, 阎飞, 赵玉海, 等. 辽东裂谷硼铁矿床地质及成矿作用[J]. 矿床地质, 2006, 25(1): 83-88. doi: 10.3969/j.issn.0258-7106.2006.01.010 CrossRef Google Scholar Xia X H, Yan F, Zhao Y H, et al. Geological features and ore-forming process of uranium-bearing vonsenite deposit in Liaodong rift, eastern Liaoning Province, China[J]. Mineral Deposits, 2006, 25(1): 83-88. doi: 10.3969/j.issn.0258-7106.2006.01.010 CrossRef Google Scholar
[67]	温德娟, 滕寿仁. 辽宁省翁泉沟铁硼矿地球化学找矿模型初探[J]. 地质与资源, 2014, 23(3): 256-260. doi: 10.3969/j.issn.1671-1947.2014.03.011 CrossRef Google Scholar Wen D J, Teng S R. Preliminary discussion on the geochemical prospecting model for the Wengquangou iron-boron deposit in Liaoning Province[J]. Geology and Resources, 2014, 23(3): 256-260. doi: 10.3969/j.issn.1671-1947.2014.03.011 CrossRef Google Scholar
[68]	胡古月, 李延河, 范昌福, 等. 辽东翁泉沟硼镁铁矿矿床海相蒸发成因: 来自稳定同位素地球化学证据[J]. 矿床地质, 2014, 33(4): 821-832. doi: 10.3969/j.issn.0258-7106.2014.04.012 CrossRef Google Scholar Hu G Y, Li Y H, Fan C F, et al. Marine evaporative genesis of Wengquangou ludwigite deposit in eastern Liaoning Province: Evidences from stable isotopic compositions[J]. Mineral Deposits, 2014, 33(4): 821-832. doi: 10.3969/j.issn.0258-7106.2014.04.012 CrossRef Google Scholar
[69]	王翠芝, 肖荣阁, 刘敬党. 辽宁翁泉沟橄榄玄武岩的地质地球化学特征及其形成环境[J]. 地球学报, 2008, 29(5): 542-552. doi: 10.3321/j.issn:1006-3021.2008.05.002 CrossRef Google Scholar Wang C Z, Xiao R G, Liu J D. Geological and geochemical characteristics and formation environment of the Wengquangou olivine basalt in Liaoning Province[J]. Acta Geoscientica Sinica, 2008, 29(5): 542-552. doi: 10.3321/j.issn:1006-3021.2008.05.002 CrossRef Google Scholar
[70]	谢宏远, 冯本智, 邹日, 等. 辽宁杨木杆硼矿床地质地球化学特征[J]. 矿床地质, 1998, 17(4): 355-362. doi: 10.3969/j.issn.0258-7106.1998.04.008 CrossRef Google Scholar Xie H Y, Feng B Z, Zou R, et al. Geological and geochemical characteristics of the Yangmugan boron deposit, Liaoning Province[J]. Mineral Deposits, 1998, 17(4): 355-362. doi: 10.3969/j.issn.0258-7106.1998.04.008 CrossRef Google Scholar
[71]	赵岩, 张朋, 毕中伟, 等. 沉积建造在辽东半岛古元古代杨木杆硼矿富集成矿过程中的重要作用[J]. 地球科学与环境学报, 2022, 44(2): 207-219. Google Scholar Zhao Y, Zhang P, Bi Z W, et al. Key role of sedimentary formation played in the mineralization process of the Paleoproterozoic Yangmugan boron deposit in Liaodong Peninsula, NE China[J]. Journal of Earth Sciences and Environment, 2022, 44(2): 207-219. Google Scholar
[72]	叶丽娜. 吉林东部前寒武纪热水沉积成矿作用研究[D]. 长春: 吉林大学, 2021: 1-220. Google Scholar Ye L N. Research of Precambrian sedimentary exhalative metallogenesis in eastern Jilin Province[D]. Changchun: Jilin University, 2021: 1-220. Google Scholar
[73]	张天旭. 吉林省集安市高台沟硼矿床地质特征及成因探讨[D]. 长春: 吉林大学, 2020: 11-24. Google Scholar Zhang T X. The geological features and genesis discussion of Gaotaigou boron deposit in Ji'an City, Jilin Province[D]. Changchun: Jilin University, 2020: 11-24. Google Scholar
[74]	Lu X P, Wu F Y, Guo J H, et al. Zircon U-Pb geochronological constraints on the Paleoproterozoic crustal evolution of the eastern block in the North China Craton[J]. Precambrian Research, 2006, 146(3/4): 138-164. Google Scholar
[75]	张艳飞, 刘敬党, 肖荣阁, 等. 辽宁后仙峪硼矿区古元古代电气石岩: 锆石特征及SHRIMP定年[J]. 地球科学——中国地质大学学报, 2010, 35(6): 985-999. Google Scholar Zhang Y F, Liu J D, Xiao R G, et al. The hyalotourmalites of Houxianyu borate deposit in eastern Liaoning: Zircon features and SHRIMP dating[J]. Earth Science-Journal of China University of Geosciences, 2010, 35(6): 985-999. Google Scholar
[76]	付燕刚, 胡古月, 李延河, 等. 辽宁后仙峪硼矿区混合岩的LA-MC-ICP-MS锆石U-Pb年龄: 对硼矿成矿演化的制约[J]. 地质论评, 2018, 64(2): 405-417. Google Scholar Fu Y G, Hu G Y, Li Y H, et al. LA-MC-ICP-MS U-Pb zircon ages of Paleoproterozoic migmatitized granites from the Houxianyu borate deposit, eastern Liaoning: Constraints on the evolution of the borate deposits[J]. Geological Review, 2018, 64(2): 405-417. Google Scholar
[77]	Hu G Y, Li Y H, Fan C F, et al. In situ LA-MC-ICP-MS boron isotope and zircon U-Pb age determinations of Paleoproterozoic borate deposits in Liaoning Province, northeastern China[J]. Ore Geology Reviews, 2015, 65: 1127-1141. doi: 10.1016/j.oregeorev.2014.09.005 CrossRef Google Scholar
[78]	路孝平, 吴福元, 张艳斌, 等. 吉林南部通化地区古元古代辽吉花岗岩的侵位年代与形成构造背景[J]. 岩石学报, 2004, 20(3): 381-392. Google Scholar Lu X P, Wu F Y, Zhang Y B, et al. Emplacement age and tectonic setting of the Paleoproterozoic Liaoji granites in Tonghua area, southern Jilin Province[J]. Acta Petrologica Sinica, 2004, 20(3): 381-392. Google Scholar
[79]	赵岩, 李生辉, 杨中柱, 等. 辽东翁泉沟硼矿区二长花岗岩脉锆石U-Pb年龄及对成矿时代的制约[J]. 地质与资源, 2022, 31(3): 342-350. Google Scholar Zhao Y, Li S H, Yang Z Z, et al. Zircon U-Pb dating of monzogranite dikes in Wengquangou boron orefield, eastern Liaoning: Constraints on metallogenic age[J]. Geology and Resources, 2022, 31(3): 342-350. Google Scholar
[80]	蒋少涌. 硼同位素及其地质应用研究[J]. 高校地质学报, 2000, 6(1): 1-16. doi: 10.3969/j.issn.1006-7493.2000.01.001 CrossRef Google Scholar Jiang S Y. Boron isotope and its geological applications[J]. Geological Journal of China Universities, 2000, 6(1): 1-16. doi: 10.3969/j.issn.1006-7493.2000.01.001 CrossRef Google Scholar
[81]	张生, 陈根文, Seward T M, 等. 硼在共存水蒸气-富硼熔体之间分配的实验研究及其地质意义[J]. 地球化学, 2014, 43(6): 583-591. Google Scholar Zhang S, Chen G W, Seward T M, et al. Experimental study on boron distribution between coexisting water vapor and boron-rich melt and its geological implications[J]. Geochimica, 2014, 43(6): 583-591. Google Scholar
[82]	郑绵平, 陈文西, 齐文. 青藏高原火山-沉积硼矿找矿的新发现与远景分析[J]. 地球学报, 2016, 37(4): 407-418. Google Scholar Zheng M P, Chen W X, Qi W. New findings and perspective analysis of prospecting for volcanic sedimentary boron deposits in the Tibetan Plateau[J]. Acta Geoscientica Sinica, 2016, 37(4): 407-418. Google Scholar
[83]	Chaussidon M, Albarède F. Secular boron isotope variations in the continental crust: An ion microprobe study[J]. Earth and Planetary Science Letters, 1992, 108(4): 229-241. doi: 10.1016/0012-821X(92)90025-Q CrossRef Google Scholar
[84]	Chaussidon M, Marty B. Primitive boron isotope composition of the mantle[J]. Science, 1995, 269(5222): 383-386. doi: 10.1126/science.269.5222.383 CrossRef Google Scholar
[85]	Swihart G H, Moore P B, Callis E L. Boron isotopic composition of marine and nonmarine evaporite borates[J]. Geochimica et Cosmochimica Acta, 1986, 50(6): 1297-1301. doi: 10.1016/0016-7037(86)90413-8 CrossRef Google Scholar
[86]	Azmy K, Lavoie D, Wang Z R. Magnesium-isotope and REE compositions of Lower Ordovician carbonates from eastern Laurentia: Implications for the origin of dolomites and limestones[J]. Chemical Geology, 2013, 356: 64-75. doi: 10.1016/j.chemgeo.2013.07.015 CrossRef Google Scholar
[87]	Galy A, Bar-Matthews M, Halicz L, et al. Mg isotopic composition of carbonate: Insight from speleothem formation[J]. Earth and Planetary Science Letters, 2002, 201(1): 105-115. doi: 10.1016/S0012-821X(02)00675-1 CrossRef Google Scholar
[88]	Geske A, Goldstein R H, Mavromatis V, et al. The magnesium isotope (δ²⁶Mg) signature of dolomites[J]. Geochimica et Cosmochimica Acta, 2015, 149: 131-151. doi: 10.1016/j.gca.2014.11.003 CrossRef Google Scholar
[89]	Geske A, Lokier S, Dietzel M, et al. Magnesium isotope composition of sabkha porewater and related (sub-) recent stoichiometric dolomites, Abu Dhabi (UAE)[J]. Chemical Geology, 2015, 393-394: 112-124. doi: 10.1016/j.chemgeo.2014.11.020 CrossRef Google Scholar
[90]	Geske A, Zorlu J, Richter D K, et al. Impact of diagenesis and low grade metamorphosis on isotope (δ²⁶Mg, δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr) and elemental (Ca, Mg, Mn, Fe and Sr) signatures of Triassic sabkha dolomites[J]. Chemical Geology, 2012, 332-333: 45-64. doi: 10.1016/j.chemgeo.2012.09.014 CrossRef Google Scholar
[91]	Immenhauser A, Buhl D, Richter D, et al. Magnesium-isotope fractionation during low-Mg calcite precipitation in a limestone cave: Field study and experiments[J]. Geochimica et Cosmochimica Acta, 2010, 74(15): 4346-4364. doi: 10.1016/j.gca.2010.05.006 CrossRef Google Scholar
[92]	Jacobson AD, Zhang Z F, Lundstrom C, et al. Behavior of Mg isotopes during dedolomitization in the Madison Aquifer, South Dakota[J]. Earth and Planetary Science Letters, 2010, 297(3/4): 446-452. Google Scholar
[93]	Lavoie D, Jackson S, Girard I. Magnesium isotopes in high-temperature saddle dolomite cements in the Lower Paleozoic of Canada[J]. Sedimentary Geology, 2014, 305: 58-68. doi: 10.1016/j.sedgeo.2014.03.002 CrossRef Google Scholar
[94]	Shirokova L S, Mavromatis V, Bundeleva I A, et al. Using Mg isotopes to trace cyanobacterially mediated magnesium carbonate precipitation in alkaline lakes[J]. Aquatic Geochemistry, 2013, 19(1): 1-24. doi: 10.1007/s10498-012-9174-3 CrossRef Google Scholar
[95]	孙剑, 房楠, 李世珍, 等. 白云鄂博矿床成因的Mg同位素制约[J]. 岩石学报, 2012, 28(9): 2890-2902. Google Scholar Sun J, Fang N, Li SZ, et al. Magnesium isotopic constraints on the genesis of Bayan Obo ore deposit[J]. Acta Petrologica Sinica, 2012, 28(9): 2890-2902. Google Scholar
[96]	胡古月, 范昌福, 李延河, 等. 辽东砖庙矿区硼矿床的海相蒸发成因——来自硼、硫、碳同位素的证据[J]. 地球学报, 2014, 35(4): 445-453. Google Scholar Hu G Y, Fan C F, Li Y H, et al. Marine evaporative genesis of Mg-borate deposits in the Zhuanmiao ore district, eastern Liaoning Province: Evidence from B, S, C isotope[J]. Acta Geoscientica Sinica, 2014, 35(4): 445-453. Google Scholar
[97]	Wang Z Q, Chen B, Yan X L. Geochemistry and boron isotopic compositions of tourmaline from the Paleoproterozoic amphibolites, NE China: Implications for the origin of borate deposit[J]. Precambrian Research, 2019, 326: 258-271. doi: 10.1016/j.precamres.2018.01.006 CrossRef Google Scholar
[98]	Yan X L, Chen B. Chemical and boron isotopic compositions of tourmaline from the Paleoproterozoic Houxianyu borate deposit, NE China: Implications for the origin of borate deposit[J]. Journal of Asian Earth Sciences, 2014, 94: 252-266. doi: 10.1016/j.jseaes.2014.05.021 CrossRef Google Scholar
[99]	Dong A G, Zhu X K, Li Z H, et al. A multi-isotope approach towards constraining the origin of large-scale Paleoproterozoic B-(Fe) mineralization in NE China[J]. Precambrian Research, 2017, 292: 115-129. doi: 10.1016/j.precamres.2017.01.030 CrossRef Google Scholar
[100]	Dong A G, Zhu X K, Li S Z, et al. Genesis of a giant Paleoproterozoic strata-bound magnesite deposit: Constraints from Mg isotopes[J]. Precambrian Research, 2016, 281, 673-683. doi: 10.1016/j.precamres.2016.06.020 CrossRef Google Scholar
[101]	冯本智, 卢静文, 邹日, 等. 中国辽吉地区早元古代大型-超大型硼矿床的形成条件[J]. 长春科技大学学报, 1998, 28(1): 1-15. Google Scholar Feng B Z, Lu J W, Zou R, et al. Ore-forming conditions for the Early Proterozoic large-super large boron deposits in Liaoning and Jilin provinces, China[J]. Journal of Changchun University of Science and Technology, 1998, 28(1): 1-15. Google Scholar
[102]	刘玉山. 遂安石的合成及其成因[J]. 岩矿测试, 1982, 1(4): 30-36, 80. Google Scholar Liu Y S. Synthesis of Suanite and its origin[J]. Acta Petrologica Mineralogica et Analytica, 1982, 1(4): 30-36, 80. Google Scholar
[103]	黄作良, 王璞, 冯本智. 辽吉硼矿床矿物学[M]. 北京: 地质出版社, 1999: 1-145. Google Scholar Huang Z L, Wang P, Feng B Z. Mineralogy of boron deposits in Liaoning and Jilin[M]. Beijing: Geological Publishing House, 1999: 1-145. (in Chinese) Google Scholar
[104]	王猛, 张旭, 武奕立, 等. 物化探综合找矿方法在辽宁宽甸硼矿勘查中的应用[J]. 矿产与地质, 2022, 36(1): 154-158. Google Scholar Wang M, Zhang X, Wu Y L, et al. Application of geophysical and geochemical exploration methods in the prospecting of boron deposit in Kuandian County of Liaoning[J]. Mineral Resources and Geology, 2022, 36(1): 154-158. Google Scholar
[105]	侯跃武, 王生志. 高精度磁法在找硼矿上的尝试——以牛皮闸硼矿为例[J]. 化工矿产地质, 2005, 27(3): 185-188. doi: 10.3969/j.issn.1006-5296.2005.03.010 CrossRef Google Scholar Hou Y W, Wang S Z. Attempt of boron prospecting with high precision magnetic method: Take the example of Niupizha boron deposit[J]. Geology of Chemical Minerals, 2005, 27(3): 185-188. doi: 10.3969/j.issn.1006-5296.2005.03.010 CrossRef Google Scholar