Citation: | SHI Lei, ZONG Wen-ming, SUN Qiu-shi, GAO Xiao-yong, LI Yong-fei, SUN Shou-liang, ZHANG Tao. THE SOURCE ROCKS OF MESOPROTEROZOIC TIELING FORMATION IN LINGYUAN-NINGCHENG BASIN: Biomarker Characteristics and Implication[J]. Geology and Resources, 2023, 32(5): 547-554. doi: 10.13686/j.cnki.dzyzy.2023.05.004 |
Based on gas chromatography and gas chromatography-mass spectrometry, the paper studies the characteristics of biomarker compounds in the source rocks of Tieling Formation in Lingyuan-ningcheng Basin, and analyzes the organic source, sedimentary environment and thermal evolution degree of organic matter, as well as geochemical implication. The saturated hydrocarbon gas chromatography of source rocks is front-peak type unimodal distribution dominated, with the main peak carbon mostly nC18, indicating that the organic matter is mainly derived from lower organism. The Pr/Ph ratio mainly ranges from 0.16 to 0.73, with obviously more phytane, indicating a strongly reducing sedimentary environment. The source rocks of Tieling Formation are characterized by abundant long-side chain tricyclic terpane, high content of gamacerane and dominant distribution of C27 sterane, with Ga/C30H of 0.10-0.31, averagely 0.19, reflecting the source rocks were formed in slight saline water-brackish water environment. The Ts/Tm ratio of 0.54-1.19 (averagely 0.88) shows the thermal evolution degree of source rocks is relatively high. The ratio of sterane/hopane contents is mainly in the range of 0.24-0.59, averagely 0.42, reflecting the lower organism of algae contributes little to organic matter, while the microorganisms such as bacteria contribute a lot. The sterane in the source rocks are L-shape with dominant C27 sterane, indicating the hydrocarbon generating parent material is of lower aquatic biological organism origin.
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Geological and structural map of Lingyuan-Ningcheng Basin
Lithological column of Tieling Formation in LLD2 well
Saturated hydrocarbon gas chromatogram of the source rocks in Tieling Formation
The Ph/nC18-Pr/nC17 diagram of source rocks in Tieling Formation
The Pr/Ph distribution histogram of source rocks in Tieling Formation
Terpanes series distribution of the source rocks in Tieling Formation
Steranes series distribution of the source rocks in Tieling Formation
The triangular diagram for C27-C28-C29ααα(R) sterane distribution of the source rocks in Tieling Formation
Sterane/hopane distribution histogram of the source rocks in Tieling Formation