Institute of Multipurpose Utilization of Mineral Resources, Chinese Academy of Geological SciencesHost
2025 Vol. 46, No. 5
Article Contents

YUAN Zhuang, CHEN Wen, LIU Xiaoyin, WANG Xiang, SONG Xin, WANG Wei. Boron Recovery and Utilization of Boron Bearing Tailings from Wengquanggou, Fengcheng[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(5): 119-125. doi: 10.12476/kczhly.202305100246
Citation: YUAN Zhuang, CHEN Wen, LIU Xiaoyin, WANG Xiang, SONG Xin, WANG Wei. Boron Recovery and Utilization of Boron Bearing Tailings from Wengquanggou, Fengcheng[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(5): 119-125. doi: 10.12476/kczhly.202305100246

Boron Recovery and Utilization of Boron Bearing Tailings from Wengquanggou, Fengcheng

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  • With the increasing attention on boron resources at home and abroad, the safety supply of boron resources is particularly important in order to prevent the risk of "choking" of boron resources. As the main boron production base in China, Wengquangou, Fengcheng, Liaoning Province, has seen a gradual reduction of boron content in raw ore in recent years, while the stock of tailings is increasing. In order to realize the "boron removal reduction" of tailings, a systematic study was carried out on refractory micro-fine boron bearing tailings from Wengquangou, Fengcheng. The raw ore B2O3 contains 5.86%, and exists in the form of bormagnesite (low activity). In order to produce boron chemical materials, the grade of B2O3 in the fine grain (-0.038 mm) is 10.37%, and distribution rate is 75.72%. The states of boron are controlled by physical separation and preenrichment or roasting. A boron concentrate with a B2O3 grade of 12.56% and a recovery of 64.53% was obtained by physical separation and preenrichment test. At the roasting temperature of 650 ℃ and time of 45 min, the leaching rate of the calcination ore reached 91.56%. In the calcination process, the boronite (Mg2[B2O4(OH)](OH)) becomes suanite (Mg2B2O5) due to dehydroxylation, and the boron concentrate has a very fine particle size, which greatly reduces the roasting and leaching time. Therefore, high quality boron chemical materials can be obtained through the process of physical separation and roasting activation.

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  • [1] 聂宾汗,陈甲斌,余良晖.国内外硼资源供需形势分析[J/OL].自然资源情报:1-7[2023-04-04].NIE B H, CHEN J B, YU L H. Analysis of supply and demand of boron resources at home and abroad[J/OL].Natural Resources Information:1-7[2023-04-04].

    Google Scholar

    NIE B H, CHEN J B, YU L H. Analysis of supply and demand of boron resources at home and abroad[J/OL].Natural Resources Information:1-7[2023-04-04].

    Google Scholar

    [2] 张福祥,赵莎,刘卓,等. 全球硼矿资源现状与利用趋势[J]. 矿产保护与利用, 2019, 39(6):142-151.ZHANG F X, ZHAO S, LIU Z, et al. Status quo and utilization trend of global boron ore resources[J]. Mineral Conservation and Utilization, 2019, 39(6):142-151.

    Google Scholar

    ZHANG F X, ZHAO S, LIU Z, et al. Status quo and utilization trend of global boron ore resources[J]. Mineral Conservation and Utilization, 2019, 39(6):142-151.

    Google Scholar

    [3] 张生辉,王振涛,李永胜,等. 中国关键矿产清单、应用与全球格局[J]. 矿产保护与利用, 2022, 42(5):138-168.ZHANG S H, WANG Z T, LI Y S, et al. List of key minerals in China, application and global pattern[J]. Mineral Conservation and Utilization, 2022, 42(5):138-168.

    Google Scholar

    ZHANG S H, WANG Z T, LI Y S, et al. List of key minerals in China, application and global pattern[J]. Mineral Conservation and Utilization, 2022, 42(5):138-168.

    Google Scholar

    [4] U.S. Geological Survey, Mineral Commodity Summaries[R]. 2010-2019.

    Google Scholar

    [5] 中华人民共和国自然资源部. 中国矿产资源报告(2019)[M].北京, 地质出版社, 2019:3.Ministry of Natural Resources of the People's Republic of China. China Mineral Resources Report (2019).[M]. Beijing, Geological Publishing House, 2019:3.

    Google Scholar

    Ministry of Natural Resources of the People's Republic of China. China Mineral Resources Report (2019).[M]. Beijing, Geological Publishing House, 2019:3.

    Google Scholar

    [6] 王庚亮. 中国硼资源进口依赖性分析[J]. 化工矿产地质, 2016(S1):116-121.WANG G L. Analysis of import dependence of boron resources in China[J]. Chemical Mineral Geology, 2016(S1):116-121. doi: 10.3969/j.issn.1006-5296.2016.z1.025

    CrossRef Google Scholar

    WANG G L. Analysis of import dependence of boron resources in China[J]. Chemical Mineral Geology, 2016(S1):116-121. doi: 10.3969/j.issn.1006-5296.2016.z1.025

    CrossRef Google Scholar

    [7] 焦森,郑厚义,屈云燕,等. 全球硼矿资源供需形势分析[J]. 国土资源情报, 2020(10):85-89.JIAO S, ZHENG H Y, QU Y Y, et al. Analysis of global supply and demand situation of boron ore resources[J]. Land and Resources Information, 2020(10):85-89.

    Google Scholar

    JIAO S, ZHENG H Y, QU Y Y, et al. Analysis of global supply and demand situation of boron ore resources[J]. Land and Resources Information, 2020(10):85-89.

    Google Scholar

    [8] 付喜林. 含硼尾矿物提取硼砂的工艺研究[D].北京:北京工业大学,2017.FU X L. Research on the extraction process of borax from boron tail minerals[D].Beijing:Beijing University of Technology,2017.

    Google Scholar

    FU X L. Research on the extraction process of borax from boron tail minerals[D].Beijing:Beijing University of Technology,2017.

    Google Scholar

    [9] 张晟南,胡海林. 大幅提升战略性矿产资源安全保障能力[N]. 辽宁日报,2022-10-30(01).ZHANG S N, HU H L. Greatly improve the security guarantee capability of strategic mineral resources[N]. Liaoning Daily,2022-10-30(01).

    Google Scholar

    ZHANG S N, HU H L. Greatly improve the security guarantee capability of strategic mineral resources[N]. Liaoning Daily,2022-10-30(01).

    Google Scholar

    [10] 唐镇宇. 宽甸含硼尾矿活性研究[D].长沙:长沙理工大学,2017.TANG Z Y. Study on the activity of boron bearing tailings in Kuandian [D]. Changsha:Changsha University of Science and Technology,2017.

    Google Scholar

    TANG Z Y. Study on the activity of boron bearing tailings in Kuandian [D]. Changsha:Changsha University of Science and Technology,2017.

    Google Scholar

    [11] 付喜林,杨晓军,符寒光. 改善含硼尾矿活性的研究[J]. 上海化工, 2016, 41(9):16-19.FU X L, YANG X J, FU H G. Study on improving the activity of boron containing tailings[J]. Shanghai Chemical Industry, 2016, 41(9):16-19. doi: 10.3969/j.issn.1004-017X.2016.09.009

    CrossRef Google Scholar

    FU X L, YANG X J, FU H G. Study on improving the activity of boron containing tailings[J]. Shanghai Chemical Industry, 2016, 41(9):16-19. doi: 10.3969/j.issn.1004-017X.2016.09.009

    CrossRef Google Scholar

    [12] 邹诚茜. 低品位含硼尾矿制备硼砂研究[D].长沙:长沙理工大学,2018.ZOU C Q. Study on preparation of Borax from low grade Boron Tailings [D]. Changsha:Changsha University of Science and Technology,2018.

    Google Scholar

    ZOU C Q. Study on preparation of Borax from low grade Boron Tailings [D]. Changsha:Changsha University of Science and Technology,2018.

    Google Scholar

    [13] 付喜林,杨晓军,符寒光,等. 浮选法富集低品位含硼尾矿研究[J]. 矿产综合利用, 2018(1):101-105.FU X L, YANG X J, FU H G, et al. Study on enrichment of low grade boron tailings by flotation[J]. Comprehensive Utilization of Mineral Resources, 2018(1):101-105. doi: 10.3969/j.issn.1000-6532.2018.01.022

    CrossRef Google Scholar

    FU X L, YANG X J, FU H G, et al. Study on enrichment of low grade boron tailings by flotation[J]. Comprehensive Utilization of Mineral Resources, 2018(1):101-105. doi: 10.3969/j.issn.1000-6532.2018.01.022

    CrossRef Google Scholar

    [14] 中国科学院贵阳地球化学研究所. 地质地球化学.[M]重庆:科学技术文献出版社重庆分社, 1975:2.Guiyang Institute of Geochemistry, Chinese Academy of Sciences. Geogeochemistry[M]. Chongqing:Chongqing Branch, Scientific and Technical Literature Press, 1975:2.

    Google Scholar

    Guiyang Institute of Geochemistry, Chinese Academy of Sciences. Geogeochemistry[M]. Chongqing:Chongqing Branch, Scientific and Technical Literature Press, 1975:2.

    Google Scholar

    [15] 葛小冬,高会颖. 摇床分选过程中颗粒受力与运动分析[J]. 煤炭加工与综合利用, 2022(10):1-8.GE X D, GAO H Y. Analysis on force and movement of particles in Separation process of Shaker[J]. Coal Processing and Comprehensive Utilization, 2022(10):1-8.

    Google Scholar

    GE X D, GAO H Y. Analysis on force and movement of particles in Separation process of Shaker[J]. Coal Processing and Comprehensive Utilization, 2022(10):1-8.

    Google Scholar

    [16] XIN ZHANG, GUANGHUI LI, JINXIANG YOU, et al. Extraction of Boron from Ludwigite Ore: Mechanism of Soda-Ash Roasting of Lizardite and Szaibelyite[J]. Minerals, 2019,9(9).

    Google Scholar

    [17] QIN S Y, YIN B W, ZHANG Y F, et al. Leaching kinetics of szaibelyite ore in NaOH solution[J]. Hydrometallurgy, 2015, 157:333-339. doi: 10.1016/j.hydromet.2015.09.014

    CrossRef Google Scholar

    [18] 丁信珍. 硼精矿活化焙烧与加压碳化过程机理研究与工艺优化[D].天津:天津科技大学,2017.DING X Z. Research on mechanism and process optimization of boron concentrate activation roasting and pressurized carbonization[D]. Tianjin:Tianjin University of Science and Technology,2017.

    Google Scholar

    DING X Z. Research on mechanism and process optimization of boron concentrate activation roasting and pressurized carbonization[D]. Tianjin:Tianjin University of Science and Technology,2017.

    Google Scholar

    [19] 都兴红,刘慧,牛亚慧,等.含镍蛇纹石中氧化镍的碳热还原过程[C]. 2012年全国冶金物理化学学术会议:2012.DU X H, LIU H, NIU Y H, et al. Carbon-thermal reduction process of nickel oxide in nickel-containing serpentine[C]. 2012 National Conference on Metallurgical Physical Chemistry:2012.

    Google Scholar

    DU X H, LIU H, NIU Y H, et al. Carbon-thermal reduction process of nickel oxide in nickel-containing serpentine[C]. 2012 National Conference on Metallurgical Physical Chemistry:2012.

    Google Scholar

    [20] HU B S, XIONG, F W. The Influence of Serpentine Kind and Size on Sintering Process. Sinter. Pelletizing 2010, 35, 23-26.

    Google Scholar

    [21] 李晓军,张润平,谢兵. 钒渣钙化焙烧参数对钒浸出率的影响[J]. 过程工程学报, 2012, 12(1):54-58.LI X J, ZHANG R P, XIE B. Effect of calcination Parameters on leaching rate of Vanadium Slag[J]. Journal of Process Engineering, 2012, 12(1):54-58.

    Google Scholar

    LI X J, ZHANG R P, XIE B. Effect of calcination Parameters on leaching rate of Vanadium Slag[J]. Journal of Process Engineering, 2012, 12(1):54-58.

    Google Scholar

    [22] 郎建峰,曹文华. 高炉铁硼分离富硼渣活性的研究[J]. 无机盐工业, 1994(4):4-6.LANG J F, CAO W H. Study on separation activity of boron rich slag from iron and boron in blast furnace[J]. Inorganic Chemicals Industry, 1994(4):4-6.

    Google Scholar

    LANG J F, CAO W H. Study on separation activity of boron rich slag from iron and boron in blast furnace[J]. Inorganic Chemicals Industry, 1994(4):4-6.

    Google Scholar

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