| Citation: | YING Hongwei, LI Yubiao, CHEN Kun, MA Qiang. Influencing Mechanisms of Unavoidable Ions Ca2+、Mg2+ on the Viscosity of Kaolin[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(5): 164-169. doi: 10.12476/kczhly.202211290755 |
Viscosity is an important factor affecting the high-value application of kaolin. In order to figure out how unavoidable ions influence the viscosity of kaolin, the slurry was investigated through a viscomete runder different concentrations of Ca2+ and Mg2+ ions. The interaction potential energy between kaolinite particles was calculated and analyzed based on the zeta potential and DLVO theory. The results showed that Ca2+ and Mg2+ increased the viscosity of kaolin slurry, with the enhancement due to Ca2+ being stronger than that of Mg2+. In addition, based on the zeta potential measurements, Ca2+ and Mg2+ increased the surface potential of kaolin slurry, but reduced the repulsive force between kaolinite particles, thereby promoting the flocculation of kaolinite particles and improving the viscosity of slurry. Moreover, DLVO theoretical calculation showed that an increase of Ca2+、Mg2+ concentration reduced the potential interaction barriers between the basal faces, as well as between the edge faces and basal faces of kaolinite particles.
| [1] | 国土资源部信息中心. 世界矿产资源年评[M]. 武汉:中国地质大学出版社, 2016.Information Center of Ministry of Land and Resources. Annual review of world mineral resources[M]. Wuhan: China University of Geosciences Press, 2016. Information Center of Ministry of Land and Resources. Annual review of world mineral resources[M]. Wuhan: China University of Geosciences Press, 2016. |
| [2] | 胡超,包惠明,迟恩涛,等. 高岭土矿粉沥青混合料抗腐性能试验与机理研究[J]. 矿产综合利用, 2020(5):161-168.HU C,BAO H M,CHI E T,et al. Test and mechanism study on corrosion resistance of kaolin tailings asphalt mixture[J]. Multipurpose Utilization of Mineral Resources, 2020(5):161-168. doi: 10.3969/j.issn.1000-6532.2020.05.026 HU C,BAO H M,CHI E T,et al. Test and mechanism study on corrosion resistance of kaolin tailings asphalt mixture[J]. Multipurpose Utilization of Mineral Resources, 2020(5):161-168. doi: 10.3969/j.issn.1000-6532.2020.05.026 |
| [3] | 郭春雷,马莹,赵拓,等. 南方某高岭土除铁增白实验[J]. 矿产综合利用, 2022(4):183-187.GUO C L,MA Y,ZHAO T,et al. Study on the factors influencing on potassium feldspar - phosphogypsum - activated carbon potassium extraction process[J]. Multipurpose Utilization of Mineral Resources, 2022(4):183-187. doi: 10.3969/j.issn.1000-6532.2022.04.031 GUO C L,MA Y,ZHAO T,et al. Study on the factors influencing on potassium feldspar - phosphogypsum - activated carbon potassium extraction process[J]. Multipurpose Utilization of Mineral Resources, 2022(4):183-187. doi: 10.3969/j.issn.1000-6532.2022.04.031 |
| [4] | 刘纯波. 湖南高岭土的资源类型及低质高岭土的开发利用研究[D]. 长沙:中南大学, 2004.LIU C B. Study on kaolin types and utilization of low-quality kaolin in Hunan[D]. Changsha: Central South University, 2004. LIU C B. Study on kaolin types and utilization of low-quality kaolin in Hunan[D]. Changsha: Central South University, 2004. |
| [5] | 谢玮. 沉淀碳酸钙(PCC)的植物胶交联表面改性及其作为造纸填料的性能研究[D].哈尔滨:东北林业大学,2017.XIE W. Surface modification of precipitated calcium carbonate (PCC) by plant gum crosslinking and Its application as papermaking filler[D]. Harbin: Northeast Forestry University,2017. XIE W. Surface modification of precipitated calcium carbonate (PCC) by plant gum crosslinking and Its application as papermaking filler[D]. Harbin: Northeast Forestry University,2017. |
| [6] | 代滇, 代雷孟, 李坤, 等. 茂名高岭土漂白酸性废水的循环回用试验研究[J]. 中国非金属矿工业导刊, 2021(6):50-52.DAI D, DAI L M, LI K, et al. Experimental study on recycling of Maoming kaolin bleaching acidic wastewater[J]. China Non-metallic Mining Industry, 2021(6):50-52. doi: 10.3969/j.issn.1007-9386.2021.06.015 DAI D, DAI L M, LI K, et al. Experimental study on recycling of Maoming kaolin bleaching acidic wastewater[J]. China Non-metallic Mining Industry, 2021(6):50-52. doi: 10.3969/j.issn.1007-9386.2021.06.015 |
| [7] | 王运新. 洗涤对高岭土粘浓度的影响[J]. 非金属矿, 2003(05):41-42.WANG Y X. Effect of washing on the viscosity concentration of kaolin[J]. Nonmetallic Mines, 2003(05):41-42. doi: 10.3969/j.issn.1000-8098.2003.05.016 WANG Y X. Effect of washing on the viscosity concentration of kaolin[J]. Nonmetallic Mines, 2003(05):41-42. doi: 10.3969/j.issn.1000-8098.2003.05.016 |
| [8] | 戴兆广, 朱永杰, 莫长录. 北海高岭土黏度特性的分析[J]. 中国非金属矿工业导刊, 2007(3):32-34.DAI Z G, ZHU Y J, MO C L. Analysis of viscosity characteristics of Beihai kaolin[J]. China Non-metallic Mining Industry, 2007(3):32-34. doi: 10.3969/j.issn.1007-9386.2007.03.009 DAI Z G, ZHU Y J, MO C L. Analysis of viscosity characteristics of Beihai kaolin[J]. China Non-metallic Mining Industry, 2007(3):32-34. doi: 10.3969/j.issn.1007-9386.2007.03.009 |
| [9] | 张志军, 李亚南, 佟震阳, 等. 高岭石对金属阳离子的吸附特性研究[J]. 矿业科学学报, 2017(3):7.ZHANG Z J, LI Y N, TONG Z Y, et al. Adsorption characteristics of metal ions on kaolinite[J]. Journal of Mining Science and Technology, 2017(3):7. ZHANG Z J, LI Y N, TONG Z Y, et al. Adsorption characteristics of metal ions on kaolinite[J]. Journal of Mining Science and Technology, 2017(3):7. |
| [10] | 刘令云. 煤泥水中高岭石颗粒表面水化作用机理研究[D]. 淮南:安徽理工大学, 2013.LIU L Y. Study on the hydration of coal-measured kaolinite surfaces in aqueous solutions[D]. Huainan: Anhui University of Science and Technology, 2013. LIU L Y. Study on the hydration of coal-measured kaolinite surfaces in aqueous solutions[D]. Huainan: Anhui University of Science and Technology, 2013. |
| [11] | WIELAND E. SUP A. SUP. Dissolution kinetics of kaolinite in acidic aqueous solutions at 25 ℃[J]. Geochim. Cosmochim. Acta, 1992(9):3339-3355. |
| [12] | HUERTAS F J, CHOU L, WOLLAST R. Mechanism of kaolinite dissolution at room temperature and pressure: Part 1. Surface speciation[J]. Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society, 1998(3):417-431. |
| [13] | CHOROVER J, SPOSITO G. Surface charge characteristics of kaolinitic tropical soils[J]. Geochimica et Cosmochimica Acta, 1995(5):875-884. |
| [14] | OLSEN C S. The surface chemistry of soils [M]. The Surface Chemistry of Soils, 1984. |
| [15] | 邱冠周, 胡岳华, 王淀佐. 颗粒间相互作用与细粒浮选[M]. 长沙:中南工业大学出版社, 1993.QIU G Z, HU Y H, WANG D Z. Interactions between particles and flotation of fine particles[M]. Changsha:Central South University of Technology Press, 1993. QIU G Z, HU Y H, WANG D Z. Interactions between particles and flotation of fine particles[M]. Changsha:Central South University of Technology Press, 1993. |
| [16] | 骆兆军, 胡岳华. 铝土矿反浮选体系分散与凝聚理论[J]. 中国有色金属学报, 2001(4):680-683.LUO Z J, HU Y H. Mechanism of dispersion and aggregationin reverse flotation for bauxite[J]. Transactions of Nonferrous Metals Society of China, 2001(4):680-683. LUO Z J, HU Y H. Mechanism of dispersion and aggregationin reverse flotation for bauxite[J]. Transactions of Nonferrous Metals Society of China, 2001(4):680-683. |
| [17] | 陈宝,束庆霏,邓荣升. 考虑板状颗粒间相互作用的黏土强度时效性的微观解释[J]. 岩土工程学报, 2021, 43(3):271-280.CHEN B, SHU Q F, DENG R S. Microscopic Interpretation of the time effect of clay strength considering the interaction between plate-like particles[J]. Chinese Journal of Geotechnical Engineering, 2021, 43(3):271-280. doi: 10.11779/CJGE202102007 CHEN B, SHU Q F, DENG R S. Microscopic Interpretation of the time effect of clay strength considering the interaction between plate-like particles[J]. Chinese Journal of Geotechnical Engineering, 2021, 43(3):271-280. doi: 10.11779/CJGE202102007 |
| [18] | 康馨,苏晨曦,陈仁朋,等. 不同水化环境下高岭土微观结构各向异性研究[J]. 湖南大学学报(自然科学版), 2023(1):1-10.KANG X, SU C X, CHEN R P, et al. Study on the anisotropy of kaolin microstructure in different hydration environments[J]. Journal of Hunan University (Natural Science Edition), 2023(1):1-10. KANG X, SU C X, CHEN R P, et al. Study on the anisotropy of kaolin microstructure in different hydration environments[J]. Journal of Hunan University (Natural Science Edition), 2023(1):1-10. |
| [19] | 夏曌.盐环境下高岭土物理力学特性的多尺度研究[D]. 长沙:湖南大学,2020XIA Z. Multi-scale study on physical and mechanical properties of kaolin in salt environment [D]. Changsha: Hunan University, 2020. XIA Z. Multi-scale study on physical and mechanical properties of kaolin in salt environment [D]. Changsha: Hunan University, 2020. |
| [20] | 吴伦.基于原子力显微镜的煤粒表面水化膜和颗粒间相互作用力研究[D]. 徐州:中国矿业大学,2015.WU L. Study on hydration film on coal particle surface and interaction between coal particles based on atomic force microscope[D]. Xuzhou: China Mining University, 2015. WU L. Study on hydration film on coal particle surface and interaction between coal particles based on atomic force microscope[D]. Xuzhou: China Mining University, 2015. |
| [21] | VITALE, E. , DENEELE, D.,RUSSO, G., et al.Short-term effects on physical properties of lime treated kaolin[J]. Applied Clay Science, 2016, 132:223-231 |
XRD patterns of kaolin sample
Effects of Ca2+and Mg2+on(a) viscosity and (b) Zeta potentials of kaolin
Effects of Ca2+and Mg2+concentration on potential energy of kaolinite (a), (b) edge to face; (c), (d) face to face
SEM of kaolin