Application Technology and Economic Analysis of Low Carbon Cement Prepared by Titanium Gypsum

MENG Hua; QIN Chuan; LIANG Yuxiang; MENG Xianzhang; WANG Ye

doi:10.12476/kczhly.202211270749

2025 Vol. 46, No. 5

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Article navigation > Multipurpose Utilization of Mineral Resources > 2025 > 46(5): 190-195, 210

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MENG Hua, QIN Chuan, LIANG Yuxiang, MENG Xianzhang, WANG Ye. Application Technology and Economic Analysis of Low Carbon Cement Prepared by Titanium Gypsum[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(5): 190-195, 210. doi: 10.12476/kczhly.202211270749

Citation:

MENG Hua, QIN Chuan, LIANG Yuxiang, MENG Xianzhang, WANG Ye. Application Technology and Economic Analysis of Low Carbon Cement Prepared by Titanium Gypsum[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(5): 190-195, 210. doi: 10.12476/kczhly.202211270749

Application Technology and Economic Analysis of Low Carbon Cement Prepared by Titanium Gypsum

1.
Chongqing Chemical Industry Vocational College, Chongqing 400020, China
2.
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan 610065, China
3.
‌Pangang Metallurgical Materials Co., Ltd., Panzhihua, Sichuan 617000, China

More Information

Corresponding author: WANG Ye, wangye@scu.edu.cn

Received Date: 27 November 2022

Publish Date: 25 October 2025

Abstract

Abstract

To deal with global climate change, people have to strike a balance between "cement" and "CO₂ reduction". A new method was proposed to produce super sulfate cement (SSC) by pressing and filtering the titanium gypsum raw material with 50% water content in Panxi Area, and fully mixed it with other solid wastes such as titanium extraction tailings, steel slag, furnace slag and fly ash. This gelling properties of Fe and Millpebs ball mill technology were used to combine with other wastes innovatively. The low-carbon preparation process with "One Mill" process and hydration mechanism of SSC were clarified by physical and mechanical analysis, and the CO₂ emission reduction effect was also calculated. The goals of heighten the ratio of titanium gypsum (content > 10%) in the SSC and reduction the cost were not only achieved, the performance of SSC were in line with national standard (32.5). It will make a contribution to realize the carbon peak and carbon neutralization.
- titanium gypsum /
- super sulfate cement (SSC) /
- hydration mechanism /
- CO₂ emission

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References

[1]	孟华, 赵婧亦, 聂朝阳, 等. 硫磺流化法还原钛白石膏工艺模拟研究[J]. 无机盐工业, 2021, 53(9):61-66.MENG H, ZHAO J Y, NIE C Y, et al. Study on simulation process of reducing titanium dioxide gypsum by sulfur fluidization[J]. Inorganic Chemicals Industry, 2021, 53(9):61-66. Google Scholar MENG H, ZHAO J Y, NIE C Y, et al. Study on simulation process of reducing titanium dioxide gypsum by sulfur fluidization[J]. Inorganic Chemicals Industry, 2021, 53(9):61-66. Google Scholar
[2]	ZHANG C Y, YU B, CHEN J M, et al. Green Transition Pathways for Cement Industry in China[J]. Resources Conservation and Recycling, 2021, 166(1):105355. Google Scholar
[3]	许长红, 刘数华. 一种超低水化热水泥—超硫酸盐水泥[J]. 混凝土世界, 2017(10):38-42.XU C H, LIU S H. A kind of ultra-low hydration thermal cement - super sulfate cement[J]. China Concrete, 2017(10):38-42. Google Scholar XU C H, LIU S H. A kind of ultra-low hydration thermal cement - super sulfate cement[J]. China Concrete, 2017(10):38-42. Google Scholar
[4]	付一江. 工业副产石膏—钛石膏的现状及综合利用前景[J]. 钢铁钒钛, 2019, 40(6):63-66+100.FU Y J. Situation and comprehensive utilization prospect of titanium gyps[J]. Iron Steel Vanadium Titanium, 2019, 40(6):63-66+100 Google Scholar FU Y J. Situation and comprehensive utilization prospect of titanium gyps[J]. Iron Steel Vanadium Titanium, 2019, 40(6):63-66+100 Google Scholar
[5]	靳必强, 张婷婷, 朱静平, 等. 钛石膏的开发利用研究进展[J]. 矿产综合利用, 2020(3):28-32.JIN B Q, ZHANG T T, ZHU J P, et al. The development and research progress of titanium gypsum exploitation and utilization[J]. Multipurpose Utilization of Mineral Resources, 2020(3):28-32. Google Scholar JIN B Q, ZHANG T T, ZHU J P, et al. The development and research progress of titanium gypsum exploitation and utilization[J]. Multipurpose Utilization of Mineral Resources, 2020(3):28-32. Google Scholar
[6]	刘洪, 郝朝阳, 朱静平. 钛白石膏的开发利用进展[J]. 矿产综合利用, 2011(1):36-38.LIU H, HE C Y, ZHU J P. Progress in exploitation and utilization of titanium gypsum[J]. Multipurpose Utilization of Mineral Resources, 2011(1):36-38. doi: 10.3969/j.issn.1000-6532.2011.01.010 CrossRef Google Scholar LIU H, HE C Y, ZHU J P. Progress in exploitation and utilization of titanium gypsum[J]. Multipurpose Utilization of Mineral Resources, 2011(1):36-38. doi: 10.3969/j.issn.1000-6532.2011.01.010 CrossRef Google Scholar
[7]	隋肃, 高子栋, 李国忠. 钛石膏的改性处理和力学性能研究[J]. 硅酸盐通报, 2010, 29(1):89-93.SUI S, GAO Z D, LI G Z. Study on modification and mechanical property of titanium gypsum[J]. Bulletin of the Chinese Ceramic Society, 2010, 29(1):89-93. Google Scholar SUI S, GAO Z D, LI G Z. Study on modification and mechanical property of titanium gypsum[J]. Bulletin of the Chinese Ceramic Society, 2010, 29(1):89-93. Google Scholar
[8]	刘数华, 王露, 余保英. 超硫酸盐水泥的水化机理及工程应用综述[J]. 混凝土世界, 2018, 10:46-51.LIU S H, WANG L, YU B Y. Review on hydration mechanism and engineering application of supersulfate cement[J]. China Concrete, 2018, 10:46-51. Google Scholar LIU S H, WANG L, YU B Y. Review on hydration mechanism and engineering application of supersulfate cement[J]. China Concrete, 2018, 10:46-51. Google Scholar
[9]	LI J, WANG W, XU D, et al. Preparation of sulfoaluminate cementitious material using harmful titanium gypsum: material properties and heavy metal immobilization characteristics[J]. Waste disposal and sustainable energy (English), 2020, 2(2):11. Google Scholar
[10]	PENG X, ZHENG J, LIU Q, et al. Efficient removal of iron from red gypsum via synergistic regulation of gypsum phase transformation and iron speciation[J]. Science of The Total Environment, 2021:148319. Google Scholar
[11]	ZHA F, QIAO B, Kang B, et al. Engineering properties of expansive soil stabilized by physically amended titanium gypsum[J]. Construction and Building Materials, 2021, 303(12):124456. Google Scholar
[12]	范剑明, 李娜, 冯鑫国. 粉煤灰/矿渣复合基沙土固化剂的制备及固化性能研究[J]. 矿产综合利用, 2019(6):105-109.FAN J M, LI N, FENG X G. Study on preparation and curing performance of fly ash/slag-based soil stabilizer[J]. Multipurpose Utilization of Mineral Resources, 2019(6):105-109. doi: 10.3969/j.issn.1000-6532.2019.06.023 CrossRef Google Scholar FAN J M, LI N, FENG X G. Study on preparation and curing performance of fly ash/slag-based soil stabilizer[J]. Multipurpose Utilization of Mineral Resources, 2019(6):105-109. doi: 10.3969/j.issn.1000-6532.2019.06.023 CrossRef Google Scholar
[13]	程旭. 一种新型异形介质对磨矿效果的影响研究[D].沈阳:东北大学, 2014.CHENG X. Study on the influence of a influence of a new special-shaped medium on grinding effect [D]. Shenyang: Northeastern University, 2014. Google Scholar CHENG X. Study on the influence of a influence of a new special-shaped medium on grinding effect [D]. Shenyang: Northeastern University, 2014. Google Scholar
[14]	林宗寿. 矿渣基生态水泥[C]. 1版,北京:中国建材工业出版社, 2018.LIN Z S. Slag based ecological cement [C]. The first edition,Beijing:China Building Materials Industry Press, 2018. Google Scholar LIN Z S. Slag based ecological cement [C]. The first edition,Beijing:China Building Materials Industry Press, 2018. Google Scholar
[15]	胡敏, 彭丽, 郭娜, 等. 磷石膏-炭化污泥胶凝材料力学性能试验研究[J]. 矿产综合利用, 2020(4):196-201.HU M, PENG L, GUO N, et al. Study on mechanical properties of phosphogypsum-carbonized sludge composite cementitious materials[J]. Multipurpose Utilization of Mineral Resources, 2020(4):196-201. Google Scholar HU M, PENG L, GUO N, et al. Study on mechanical properties of phosphogypsum-carbonized sludge composite cementitious materials[J]. Multipurpose Utilization of Mineral Resources, 2020(4):196-201. Google Scholar
[16]	李军卫, 刘长明, 单雪峰. 水泥改良铁尾矿砂路基填料的力学特性研究[J]. 矿产综合利用, 2021(3):193-199.LI J W, LIU C M, SHAN X F. Research on mechanical properties of cement-improved iron tailings sand roadbed filler[J]. Multipurpose Utilization of Mineral Resources, 2021(3):193-199. Google Scholar LI J W, LIU C M, SHAN X F. Research on mechanical properties of cement-improved iron tailings sand roadbed filler[J]. Multipurpose Utilization of Mineral Resources, 2021(3):193-199. Google Scholar
[17]	张振芳, 陈秀法, 李仰春, 等. “双碳”目标下镍资源的综合利用发展趋势[J]. 矿产综合利用, 2022(2):31-39.ZHANG Z F, CHEN X F, LI Y C, et al. Multipurpose utilization trend of nickel mineral resources under the goal of carbon peaking and carbon neutrality[J]. Multipurpose Utilization of Mineral Resources, 2022(2):31-39. Google Scholar ZHANG Z F, CHEN X F, LI Y C, et al. Multipurpose utilization trend of nickel mineral resources under the goal of carbon peaking and carbon neutrality[J]. Multipurpose Utilization of Mineral Resources, 2022(2):31-39. Google Scholar
[18]	贺晋瑜, 何捷, 王郁涛, 等. 中国水泥行业二氧化碳排放达峰路径研究[J]. 环境科学研究, 2022(2):347-355.HE J Y, HE J, WANG Y T, et al. Study on the path of carbon dioxide emission peak in China's cement industry[J]. Research of Environmental Sciences, 2022(2):347-355. Google Scholar HE J Y, HE J, WANG Y T, et al. Study on the path of carbon dioxide emission peak in China's cement industry[J]. Research of Environmental Sciences, 2022(2):347-355. Google Scholar
[19]	于胜民, 马翠梅, 王田, 等. 对"降低中国化石燃料燃烧和水泥生产过程碳排放估算"一文主要结论的初步分析[J]. 中国能源, 2015, 37(9):27-31.YU S M, MA C M, WANG T, et al. A preliminary analysis of the main conclusions of the paper "reducing carbon emissions from fossil fuel combustion and cement production in China"[J]. China Energy, 2015, 37(9):27-31. Google Scholar YU S M, MA C M, WANG T, et al. A preliminary analysis of the main conclusions of the paper "reducing carbon emissions from fossil fuel combustion and cement production in China"[J]. China Energy, 2015, 37(9):27-31. Google Scholar
[20]	陈杰, 肖建襄, 邓亮. 降低吨熟料综合电耗的措施[J]. 中国水泥, 2016(10):102-103.CHEN J, XIAO J X, DENG L. Measures to reduce the comprehensive power consumption of tons of clinker[J]. China Concrete, 2016(10):102-103. doi: 10.3969/j.issn.1671-8321.2016.10.027 CrossRef Google Scholar CHEN J, XIAO J X, DENG L. Measures to reduce the comprehensive power consumption of tons of clinker[J]. China Concrete, 2016(10):102-103. doi: 10.3969/j.issn.1671-8321.2016.10.027 CrossRef Google Scholar