| Citation: | CHU Haiyan, GAO Yeling, ZHANG Wei, WANG Wei, XU Duanping. Adsorption of Heavy Metals Lead and Cadmium in Soil by Modified Lignite[J]. Multipurpose Utilization of Mineral Resources, 2025, 46(5): 176-181, 189. doi: 10.12476/kczhly.202211210732 |
In this paper, the adsorption and resolution mechanism of heavy metals Pb2+ and Cd2+ by modified lignite were studied. Methods: Four single-factor gradient variables (pH value, amount of lignite, adsorption time, adsorption temperature) were designed to carry out the adsorption contrast test before and after the sulfonation. The desorption effects of modified lignite on Pb2+ and Cd2+ in soil were measured at different pH value gradients. The results showed that the specific surface area of lignite increased from 165 m2/g to 784 m2/g, and the adsorption rate of Pb2+ and Cd2+ on modified lignite was positively correlated with pH value of solution, addition of lignite, adsorption time and adsorption temperature The adsorption equilibrium was reached at 120 min when the dosage of modified lignite was 6%, and the desorption of Pb2+ and Cd2+ was the lowest when pH value was 11, and the adsorption has high stability. Conclusions: the adsorption efficiency of modified lignite on heavy metals Pb2+ and Cd2+ in soil is higher than that before modification, and it can be used as an additive material for the treatment of heavy metal pollution in soil.
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Microstructure of lignite before and after sulfonation(SEM)
FTIR of lignite before and after sulfonation
Effect of solution pH value on adsorption of Pb2+ and Cd2+ by lignite and modified lignite
Effect of lignite and modified lignite dosage on adsorption of Pb2+ and Cd2+
Effect of adsorption time on adsorption of Pb2+ and Cd2+ by lignite and modified lignite
Effect of temperature on adsorption of Pb2+ and Cd2+ by lignite and modified lignite
Effect of solution pH value on adsorption of heavy metals Pb2+ and Cd2+ by modified lignite