Citation: | ZHANG Xiongmao, CHEN Bing, YANG Rong, CHEN Jun, CHENG Jiaxiao, JIANG Hongjun, LI Peng, YE Xingchao, KANG Qingqing. 2023. The source of uranium minerals in Huayangchuan area of North Qinling. Geological Bulletin of China, 42(2-3): 420-430. doi: 10.12097/j.issn.1671-2552.2023.2-3.019 |
The Huayangchuan uranium deposit is located at the sandwiched part of the Laoniushan and the Huashan pluton.The ore body is strictly controlled by the NW-SE-trending Huayangchuan brittle-ductile shear zone.The ore-bearing rocks are mainly quartz carbonatite, followed by pegmatite.There have been no more credible research results on the material source of Huayangchuan uranium deposit.This study systematically collected airborne, geological, drilling, and metallurgical data, and used surface radioactive geophysical prospecting, geology, zircon U-Pb dating and other methods to calculate the radioactive energy spectrum characteristics and age characteristics of each plastid body (unit), study the structure distribution law of rock mass and dyke rock and the migration law of radioactive elements, and reveal the source of ore-forming materials of Huayangchuan uranium deposit.The characteristics of the surface gamma spectrum show that the content of the Wengyu granite of the Huashan pluton is 4.82×10-6~6.46×10-6, the thorium content is 23.03×10-6~31.08×10-6, and the Th/U ratios are 5.29~6.00.The uranium content of the main rock units of the Niushan pluton is 9.27×10-6~11.18×10-6, the thorium content is 24.39×10-6~27.72×10-6, the Th/U ratios are 2.64~3.55, both of which have the characteristics of high uranium and thorium.Geochemical characteristics of the Huashan pluton and the Laoniushan pluton are similar to adakitic rocks, which are the same source and rich uranium bodies of different stages.However, the Wengyu granite of the Huashan pluton has obvious uranium source characteristics.Radioactive aerial geophysical characteristics show that the ductile shear zone in Huayangchuan mining area has the characteristics of uranium migration and enrichment.Based on the geochronological background research, the diagenetic age of the Wengyu granite of the Huashan pluton is the same as that of the ore-bearing quartz carbonate in the Huayangchuan mining area, both formed in 235~200 Ma.The bottom of the multi-stage sub-brittle-ductile shear zone which is formed from the first land-making event (ca.1800 Ma) to the Indosinian period is directly connected to the Huashan pluton, which provides favorable conditions for the migration of activated uranium.Combined the above research, the author believes that after the uranium element in the Wengyu granite of the Huashan Pluton is activated and migrated, it provides a large amount of uranium source for the Huayangchuan uranium deposit.
[1] | Hu J, Jiang S Y, Zhao H X, et al. Geochemistry and petrogenesis of the Huashan granites and their implications for the Mesozoic tectonic settings in the Xiaoqinling gold mineralization belt, NW China[J]. Journal of Asian Earth Sciences, 2012, 56: 276-289. doi: 10.1016/j.jseaes.2012.05.016 |
[2] | Yang C S, Zhao L D, Zheng H, et al. The multiple granitic magmatism in the giant Huayangchuan uranium polymetallic ore district: Implications for tectonic evolution of the southern margin of North China Craton in the Qinling Orogen[J]. Ore Geology Reviews, 2019, 112: 1-21. |
[3] | Yang C S, Chen H Y, Zhao L D, et al. Multiphase magmatic overprinting in the Late Jurassic Laoniushan pluton at the SW margin of the North China Craton: Geochronological and petrogenetic constraints[J]. Geological Journal, 2020, 55(10): 1-17. |
[4] | Zheng H, Chen H Y, Li D F, et al. Timing of carbonatite-hosted U-polymetallic mineralization in the supergiant Huayangchuan deposit, Qinling Orogen: Constraints from titanite U-Pb and molybdenite Re-Os dating[J]. Geoscience Frontiers, 2020, 3: 1-12. |
[5] | 高成, 康清清, 张熊猫, 等. 华阳川碳酸岩的岩石学特征及铀矿赋存状态[J]. 陕西地质, 2015, 33(2): 10-13. doi: 10.3969/j.issn.1001-6996.2015.02.002 |
[6] | 高成, 康清清, 江宏君, 等. 秦岭造山带发现新型铀多金属矿: 华阳川与伟晶岩脉和碳酸岩脉有关的超大型铀-铌-铅-稀土矿床[J]. 地球化学, 2017, 46(5): 446-455. doi: 10.3969/j.issn.0379-1726.2017.05.004 |
[7] | 高龙刚, 陈佑绎, 毕献武, 等. 陝西华阳川铀铌矿床中铀矿物的年代学与矿物化学研究及其对铀成矿的启示[J]. 地质学报, 2019, 93(9): 2273-2291. doi: 10.3969/j.issn.0001-5717.2019.09.012 |
[8] | 郭威, 周鼎武, 任军锋, 等. 陕西小秦岭华阳川韧性剪切带的特征及其区域构造意义[J]. 地质通报, 2008, 27(6): 823-828. doi: 10.3969/j.issn.1671-2552.2008.06.010 |
[9] | 郭波, 朱赖民, 李犇, 等. 华北陆块南缘华山和合峪花岗岩岩体锆石U-Pb年龄、Hf同位素组成与成岩动力学过程[J]. 岩石学报, 2009, 25(2): 265-281. |
[10] | 何升, 李子颖, 惠小朝, 等. 陕西华阳川铀多金属矿床黑云母40Ar/39Ar年龄及其地质意义[J]. 铀矿地质, 2016, 32(3): 159-164. doi: 10.3969/j.issn.1000-0658.2016.03.005 |
[11] | 黄卉, 潘家永, 洪斌跃, 等. 陕西华阳川铀-多金属矿床晶质铀矿电子探针U-Th-Pb化学定年及其地质意义[J]. 矿床地质, 2020, 39(2): 351-368. |
[12] | 惠小朝, 李子颖, 冯张生, 等. 陕西华阳川铀多金属矿床铀赋存状态研究[J]. 矿物学报, 2014, 34(4): 573-580. |
[13] | 惠小朝, 何升. 华阳川铀多金属矿床碳酸岩脉矿化特征[J]. 铀矿地质, 2016, 32(3): 94-98. |
[14] | 江宏君, 高成, 康清清, 等. 小秦岭华阳川铀铌铅矿床蚀变矿化期次研究[J]. 大地构造与成矿学, 2020, 44(3): 404-421. |
[15] | 康清清, 江宏君, 李鹏, 等. 陕西华阳川铀铌铅矿床矿石矿物学特征[J]. 东华理工大学学报(自然科学版), 2018, 41(2): 111-123. |
[16] | 康清清, 张熊猫, 孟华. 小秦岭西段稀土矿特征及找矿远景浅析[J]. 西北地质, 2020, 53(1): 107-121. |
[17] | 李普涛, 辜平阳, 李永军, 等. 小秦岭华阳川地区吕梁期和燕山期铀成矿作用: 来自含铀伟晶岩年代学的启示[J]. 地球科学与环境学报, 2022, 44(2): 191-206. |
[18] | 齐秋菊, 王晓霞, 柯昌辉, 等. 华北地块南缘老牛山杂岩体时代、成因及地质意义——锆石年龄、Hf同位素和地球化学新证据[J]. 岩石学报, 2012, 28(1): 279-301. |
[19] | 邱家骧, 李昌年, 喻学惠, 等. 秦巴碱性岩[M]. 北京: 地质出版社, 1993. |
[20] | 王林军, 许成, 吴敏, 等. 华阳川碳酸岩流体包裹体研究[J]. 矿物学报, 2011, 31(3): 372-379. |
[21] | 王瑞廷, 秦西社, 袁海潮, 等. 小秦岭金钼多金属矿集区西部区域地质地球化学特征、成矿模式与找矿方向[J]. 地质通报, 2021, 40(4): 531-544. |
[22] | 王文广, 王驹. 连山关铀矿床特殊的工业铀矿物组合及其特征和意义[J]. 铀矿地质, 1991, (4): 196-205. |
[23] | 武翠莲, 刘志超, 马嘉, 等. 华阳川多金属矿床中铀的赋存状态研究[J]. 铀矿冶, 2015, 34(1): 30-34. |
[24] | 辛存林, 马维云, 安国堡, 等. 甘肃龙首山207铀矿床成矿地质特征及其成矿机制探讨[J]. 地质学报, 2013, 87(4): 577-590. |
[25] | 喻学惠. 陕西华阳川碳酸岩地质学和岩石学特征及其成因初探[J]. 地球科学, 1992, 17(2): 151-158. |
[26] | 张国伟, 张宗清, 董云鹏. 秦岭造山带主要构造岩石地层单元的构造性质及其大地构造意义[J]. 岩石学报, 1995, 11(2): 101-114. |
[27] | 张金带, 李子颖, 蔡煜琦, 等. 全国铀矿资源潜力评价工作进展与主要成果[J]. 铀矿地质, 2012, 28(6): 321-326. |
[28] | 张兴康, 叶会寿, 李正远, 等. 小秦岭华山复式岩基大夫峪岩体锆石U-Pb年龄、Hf同位素和地球化学特征[J]. 矿床地质, 2015, 34(2): 235-260. |
[29] | 郑惠, 陈华勇. 华阳川铀多金属矿床烧绿石特征研究[C]//翟裕生等编. 第九届全国成矿理论与找矿方法学术讨论会论文摘要集. 南京: 中国矿物岩石地球化学学会矿床地球化学专业委员会, 2019: 204. |
[30] | 朱赖民, 张国伟, 郭波, 等. 东秦岭金堆城大型斑岩钼矿床LA-ICP-MS锆石U-Pb定年及成矿动力学背景[J]. 地质学报, 2008, 82(2): 204-220. |
Simplified regional tectonic-magma map of the Lesser Qinling area
Simplified geological map of the study area
Distribution characteristics of strata and rock mass in Huayangchuan area
Zircon U-Pb ages concordia diagrams from the Pluton
Comparison of U, Th and Th/U in the surface sections of the main rock units of the Huashan and Laoniushan plutons