2024 Vol. 43, No. 8
Article Contents

WU Zhenzhu, ZHANG Wanyi, WANG Fengxiang, HUANG Kuan, SHI Chunyuan. 2024. The development of overseas exploration of white hydrogen and implications for China. Geological Bulletin of China, 43(8): 1395-1405. doi: 10.12097/gbc.2024.02.013
Citation: WU Zhenzhu, ZHANG Wanyi, WANG Fengxiang, HUANG Kuan, SHI Chunyuan. 2024. The development of overseas exploration of white hydrogen and implications for China. Geological Bulletin of China, 43(8): 1395-1405. doi: 10.12097/gbc.2024.02.013

The development of overseas exploration of white hydrogen and implications for China

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  • Hydrogen energy is considered to be the cleanest energy and will play an increasingly important role in the future energy field. At present, it is only regarded as a secondary energy and does not have the characteristics of large scale and stability. Besides, most hydrogen energies are produced from fossil energies, which emit a lot of greenhouse gases. Because the environment problems caused by excessive dependence on fossil energies, it has become much important to study geological hydrogen (known as “white or native hydrogen”). With the deepening of research, hundreds of white hydrogen discoveries with high content have been reported worldwide, especially, the discovery in the Lorrain Basin, France. It is estimated that the resource is about ranging 6 million to 250 million tons. White hydrogen has regarded as the key energy to combat the climate crisis. Based on the previous studies, the hydrogen color spectrum is introduced. Compared with hydrogen produced by other routes, white hydrogen has three natural advantages of zero carbon, very low production cost and renewable. According to the progress of international exploration for white hydrogen, it is concluded that the Earth has a complete hydrogen production mechanism. Relevant studies have shown that white hydrogen with high content is widely distributed in rifts, plate subduction zones, and Precambrian crystalline basement. Both the resource and application prospects of white hydrogen are broad and the United States and Europe and other countries are stepping up the layout of white hydrogen exploration. According to the previous research, China also has the geological conditions for the white hydrogen. However, compared with other countries, the research work on white hydrogen needs to be improved. Based on this, three suggestions are put forward for white hydrogen work in China, which are launching white hydrogen investigation pilot projects in Songliao Basin and Qaidam Basin, strengthening comprehensive research and theoretical technology research and development of white hydrogen and also building a high−quality white hydrogen talent team.

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  • [1] Angino E E, Coveney R M J, Goebel E D, et al. 1984. Hydrogen and nitrogen—Origin, distribution, and abundance, a followup[J]. Oil & Gas Journal, 82(49): 142−146.

    Google Scholar

    [2] Arcos J M M, Santos D M F. 2023. The hydrogen color spectrum: Techno−economic analysis of the available technologies for hydrogen production[J]. Gases, 3(1): 25−46. doi: 10.3390/gases3010002

    CrossRef Google Scholar

    [3] Ascent Funds. 2020. Ascent hydrogen fund and helios aragon sign agreement to develop gold hydrogen in the northern Province of Aragon, Spain [EB/OL]. (2020-12-15) [2024-02-18]. https://ascent-funds.com/2020/12/15/ascent-hydrogen-fund-signs-new-deal-with-spains-helios-aragon-to-explore-and-produce-gold-hydrogen/.

    Google Scholar

    [4] Bakx K. A new gold rush? 2024. The search for the natural hydrogen motherlode is coming to Canada [EB/OL]. (2024-01-26) [2024- 02-18]. https://www.cbc.ca/news/canada/bakx-white-hydrogen-natural-mali-1.7094645.

    Google Scholar

    [5] Bartlett J, Krupnick A. 2020. Decarbonized hydrogen in the US power and industrial sectors: Identifying and incentivizing opportunities to lower emissions[R]. Resources for the Future, 20−25.

    Google Scholar

    [6] Bauer C, Treyer K, Antonini C, et al. 2022. On the climate impacts of blue hydrogen production[J]. Sustainable Energy & Fuels, 6(1): 66−75.

    Google Scholar

    [7] Brandon N, Armstrong F, Chan S H, et al. 2021. The role of hydrogen and ammonia in meeting the net zero challenge[J]. Climate Change: Science and Solutions, Briefing, 4: 1−13.

    Google Scholar

    [8] Briere D, Jerzykiewicz T. 2016. On generating a geological model for hydrogen gas in the southern Taoudeni Megabasin (Bourakebougou area, Mali) [C]//International Conference and Exhibition, Barcelona, Spain, 3−6 April 2016. Society of Exploration Geophysicists and American Association of Petroleum Geologists: 342−342.

    Google Scholar

    [9] Bulletin R. 2023. The hydrogen economy: Opportunities and risks in the energy transition [EB/OL]. (2023-04)[2024-02-18]. https://commercial. allianz.com/news-and-insights/reports/hydrogen-energy.html.

    Google Scholar

    [10] Collins L. 2023a. ‘Energy of the future’ | French president promises ‘massive funding’ for natural hydrogen. [EB/OL].(2023-12-13) [2024-02-18]. https://www.hydrogeninsight.com/production/energy-of-the-future-french-president-promises-massive-funding-for-natural-hydrogen/2-1-1570543.

    Google Scholar

    [11] Collins L. 2023b. Natural hydrogen found? | State-owned oil company analysing five sites across South Korea [EB/OL]. (2023-03-31) [2024-02-18]. https://www.hydrogeninsight.com/production/natural-hydrogen- found-state-owned-oil-company-analysing-five-sites-across-south-korea/2-1-1429573.

    Google Scholar

    [12] Dove N. 2023. How a white hydrogen discovery could help global emissions efforts[EB/OL]. (2023-10-31) [2024-02-18]. https://global news.ca/news/10061237/white-hydrogen-discovery-what-is-it/.

    Google Scholar

    [13] Dou L R, Liu H Q, Li B, et al. 2024. Global natural hydrogen exploration and developmentsituation and prospects in China[J]. Lithologic Reservoirs, 36(2): 1−14 (in Chinese with English abstract).

    Google Scholar

    [14] Dubessy J, Pagel M, Beny J M, et al. 1988. Radiolysis evidenced by H2−O2 and H2−bearing fluid inclusions in three uranium deposits[J]. Geochimica et Cosmochimica Acta, 52(5): 1155−1167. doi: 10.1016/0016-7037(88)90269-4

    CrossRef Google Scholar

    [15] Dutta S. 2018. Hydrogen as sustainable and green energy resource [EB/OL]. (2018-07-17) [2024-02-18]. Kirk−Othmer Encyclopedia of Chemical Technology. https://doi.org/10.1002/0471238961.082504180 2091212.a01.pub3.

    Google Scholar

    [16] Ellis G S. 2023. Geologic hydrogen: An overlooked potential primary clean−energy resource[R]. Invited Presentation to the Geological Society of Washington DC.

    Google Scholar

    [17] Enery. gov. 2023. Workshop with Oman’s Ministry of Energy and Minerals Explores Potential for Producing Hydrogen from Oman’s Unique Geology [EB/OL]. (2023-09-29) [2024-02-18]. https://www. energy.gov/articles/department-energy-convenes-first-ever-bilateral-engagement-geologic-hydrogen.

    Google Scholar

    [18] Evans M. 2023. HyTerra, a first mover in natural hydrogen production [EB/OL]. (2023-09-29) [2024-02-18]. https://www.proactiveinvestors. co.uk/companies/news/1037927/hyterra-a-first-mover-in-natural-hydrogen-production-1037927.html.

    Google Scholar

    [19] Goebel E D, Coveney Jr R M, Angino E E, et al. 1983. Naturally occurring hydrogen gas from a borehole on the western flank of Nemaha anticline in Kansas[J]. AAPG Bulletin, 67(8): 1324−1324.

    Google Scholar

    [20] Guélard J, Beaumont V, Rouchon V, et al. 2017. Natural H2 in Kansas: Deep or shallow origin?[J]. Geochemistry, Geophysics, Geosystems, 18(5): 1841−1865.

    Google Scholar

    [21] Han S, Tang Z, Wang C, et al. 2022. Hydrogen−rich gas discovery in continental scientific drilling project of Songliao Basin, Northeast China: New insights into deep Earth exploration[J]. Science Bulletin, 67(10): 1003−1006. doi: 10.1016/j.scib.2022.02.008

    CrossRef Google Scholar

    [22] Hand E. 2023a. Hidden hydrogen: Does Earth hold vast stores of a renewable, carbon-free? [EB/OL]. (2023-02-16)[2024-02-18]. https:// www.science.org/content/article/hidden-hydrogen-earth-may-hold-vast-stores-renewable carbon-free-fuel.

    Google Scholar

    [23] Hand E. 2023b. Geological hydrogen wins first major funding[J]. Science (New York, NY), 381(6662): 1036−1037.

    Google Scholar

    [24] Hao Y, Pang Z, Tian J, et al. 2020. Origin and evolution of hydrogen−rich gas discharges from a hot spring in the eastern coastal area of China[J]. Chemical Geology, 538: 119477. doi: 10.1016/j.chemgeo.2020.119477

    CrossRef Google Scholar

    [25] Howarth R W, Jacobson M Z. 2021. How green is blue hydrogen?[J]. Energy Science & Engineering, 9(10): 1676−1687.

    Google Scholar

    [26] Ji M, Wang J. 2021. Review and comparison of various hydrogen production methods based on costs and life cycle impact assessment indicators[J]. International Journal of Hydrogen Energy, 46(78): 38612−38635. doi: 10.1016/j.ijhydene.2021.09.142

    CrossRef Google Scholar

    [27] Jin Z J, Yang L, Zeng J H et al. 2002. Deep fluid activities and their effects on generation of hydrocarbon in Dongying depression[J]. Petroleum Exploration and Development, 36(2): 1−14.

    Google Scholar

    [28] Jovan D J, Dolanc G. 2020. Can green hydrogen production be economically viable under current market conditions[J]. Energies, 13(24): 6599. doi: 10.3390/en13246599

    CrossRef Google Scholar

    [29] Kazi M K, Eljack F, El−Halwagi M M, et al. 2021. Green hydrogen for industrial sector decarbonization: Costs and impacts on hydrogen economy in qatar[J]. Computers & Chemical Engineering, 145: 107144.

    Google Scholar

    [30] Kuehn M. 2023. Transitioning from a Grey to Clean Hydrogen Economy: Considerations for Scaling Production and Making Use of Existing Transport Infrastructure[C]//Abu Dhabi International Petroleum Exhibition and Conference. SPE, D031S106R007.

    Google Scholar

    [31] Li X M, Liu Y H, Wen J P. 2002. Geochemical characteristics and geological significance of natural gas in Well Wulong 1, Chuxiong Basin[J]. Natural Gas Industry, 22(5): 16−19 (in Chinese with English abstract).

    Google Scholar

    [32] Liang Y B. 2022. A comparative study on energy strategies of the US, Japan and Germany[J]. Frontiers, 13: 45−55.

    Google Scholar

    [33] Lollar B S, Onstott T C, Lacrampe−Couloume G, et al. 2014. The contribution of the Precambrian continental lithosphere to global H2 production[J]. Nature, 516(7531): 379−382. doi: 10.1038/nature14017

    CrossRef Google Scholar

    [34] Marty B, Gunnlaugsson E, Jambon A, et al. 1991. Gas geochemistry of geothermal fluids, the Hengill area, southwest rift zone of Iceland[J]. Chemical geology, 91(3): 207−225. doi: 10.1016/0009-2541(91)90001-8

    CrossRef Google Scholar

    [35] Maiga O, Deville E, Laval J, et al. 2023. Characterization of the spontaneously recharging natural hydrogen reservoirs of Bourakebougou in Mali[J]. Scientific Reports, 13(1): 11876. doi: 10.1038/s41598-023-38977-y

    CrossRef Google Scholar

    [36] Mendrela P, Stanek W, Simla T. 2024. Sustainability assessment of hydrogen production based on nuclear energy[J]. International Journal of Hydrogen Energy, 49: 729−744. doi: 10.1016/j.ijhydene.2023.07.156

    CrossRef Google Scholar

    [37] Messad P. 2023. Excitement event about natural hydrogen as huge reserves found in France [EB/OL]. (2023-07-05)[2024-02-18]. https://www.euractiv.com/section/energy-environment/news/ excitement-grows-about-natural-hydrogen-as-huge-reserves-found-in-france/.

    Google Scholar

    [38] Milani D, Kiani A, McNaughton R. 2020. Renewable−powered hydrogen economy from Australia's perspective[J]. International Journal of Hydrogen Energy, 45(46): 24125−24145. doi: 10.1016/j.ijhydene.2020.06.041

    CrossRef Google Scholar

    [39] Moon B, Lee W, Lee Y. 2021. The present condition and outlook of hydrogen industry in Alberta, Canada[J]. Journal of the Korean Institute of Gas, 25(1): 1−6.

    Google Scholar

    [40] Moore B J, Sigler S. 1987. Analyses of natural gases, 1917−85[R]. US Department of the Interior, Bureau of Mines.

    Google Scholar

    [41] Morrill P L, Kuenen J G, Johnson O J, et al. 2013. Geochemistry and geobiology of a present−day serpentinization site in California: The Cedars[J]. Geochimica et Cosmochimica Acta, 109: 222−240. doi: 10.1016/j.gca.2013.01.043

    CrossRef Google Scholar

    [42] Newcombe R B. 1935. Natural gas fields of Michigan[J]. AAPG Special Volumes, 7: 787−812.

    Google Scholar

    [43] Nitz B. 2023. The history and promise of geological hydrogen for fuel [EB/OL]. (2023-03-06)[2014-02-18]. https://www.greenprophet.com/ 2023/03/geological-hydrogen-for-fuel/.

    Google Scholar

    [44] Osselin F, Soulaine C, Fauguerolles C, et al. 2022. Orange hydrogen is the new green[J]. Nature Geoscience, 15(10): 765−769. doi: 10.1038/s41561-022-01043-9

    CrossRef Google Scholar

    [45] Paddison L. 2023. They went hunting for fossil fuels. What they found could help save the world [EB/OL]. https://edition.cnn.com/2023/ 10/29/climate/white-hydrogen-fossil-fuels-climate/index.html.

    Google Scholar

    [46] Parkes R. 2023. Massive underground reservoir of natural hydrogen in Spain 'could deliver the cheapest H2 in the world' [EB/OL]. (2023- 04-06) [2024-02-18]. https://www.hydrogeninsight.com/innovation/ massive-underground-reservoir-of-natural-hydrogen-in-spain-could-deliver-the-cheapest-h2-in-the-world/2-1-1431515.

    Google Scholar

    [47] Peacock B. 2023. NASA pictures hydrogen-emitting ‘fairy circles’ in WA [EB/OL]. (2023-09-12)[2024-02-18]. https://www.pv-magazine-australia.com/2023/09/12/nasa-finds-hydrogen-emitting-fairy-circles-in-wa/.

    Google Scholar

    [48] Potter J, Rankin A H, Treloar P J. 2004. Abiogenic Fischer–Tropsch synthesis of hydrocarbons in alkaline igneous rocks; fluid inclusion, textural and isotopic evidence from the Lovozero complex, NW Russia[J]. Lithos, 75(3/4): 311−330. doi: 10.1016/j.lithos.2004.03.003

    CrossRef Google Scholar

    [49] Qin C, Yu Q, Liu W et al. 2017. Reservoir Characteristics of Organic−rich Mudstone of Niutitang Formation in Northern Guizhou[J]. Journal of Southwest Petroleum University(Science & Technology Edition, 39(4): 13−24 (in Chinese with English abstract).

    Google Scholar

    [50] Ren X, Dong L, Xu D, et al. 2020. Challenges towards hydrogen economy in China[J]. International Journal of Hydrogen Energy, 45(59): 34326−34345. doi: 10.1016/j.ijhydene.2020.01.163

    CrossRef Google Scholar

    [51] Salvi S, Williams−Jones A E. 1997. Fischer−Tropsch synthesis of hydrocarbons during sub−solidus alteration of the Strange Lake peralkaline granite, Quebec/Labrador, Canada[J]. Geochimica et Cosmochimica Acta, 61(1): 83−99. doi: 10.1016/S0016-7037(96)00313-4

    CrossRef Google Scholar

    [52] Savchenko V P. 1958. The formation of free hydrogen in the Earth’s crust as determined by the reducing action of the products of radioactive transformations of isotopes[J]. Geochemistry Int., 1: 16−25.

    Google Scholar

    [53] Scita R, Raimondi P P, Noussan M. 2020. Green hydrogen: the holy grail of decarbonisation? An analysis of the technical and geopolitical implications of the future hydrogen economy[R]. http://dx.doi.org/ 10.2139/ssrn.3709789.

    Google Scholar

    [54] Shuai Y H, Zhang S C, Su A G, et al. 2010. Geochemical evidence for strong ongoing methanogenesis in Sanhu region of Qaidam Basin[J]. Science in China Series D: Earth Sciences, 53(1): 84−90. doi: 10.1007/s11430-009-0081-4

    CrossRef Google Scholar

    [55] Stangarone T. 2021. South Korean efforts to transition to a hydrogen economy[J]. Clean technologies and environmental policy, 23: 509−516. doi: 10.1007/s10098-020-01936-6

    CrossRef Google Scholar

    [56] Symonds R B, Poreda R J, Evans W C, et al. 2003. Mantle and crustal sources of carbon, nitrogen, and noble gases in Cascade−Range and Aleutian−Arc volcanic gases[R]. US Geological Survey.

    Google Scholar

    [57] Tian Q N, Zhang W, Wang H H, et al. 2022. Non−negligible new energy in the energy transition context: Natural hydrogen[J]. Geological Survey of China, 9(1): 1−15 (in Chinese with English abstract).

    Google Scholar

    [58] Trencher G, Edianto A. 2021. Drivers and barriers to the adoption of fuel cell passenger vehicles and buses in Germany[J]. Energies, 14(4): 833. doi: 10.3390/en14040833

    CrossRef Google Scholar

    [59] Tu X Q, Zeng R. 2024. New Trends, Impact and response strategies of clean energy subsidy policies in the United States: Analysis based on the US inflation reduction act[J]. Zhejiang Academic Journal, (1): 137−143 (in Chinese with English abstract).

    Google Scholar

    [60] Vacquand C. 2011. Genèse et mobilité de l’hydrogène dans les roches sédimentaires: Source d’énergie naturelle ou vecteur énergétique stockable[D]. PhD Thesis Defended in IFP Energies nouvelles and Institut de Physique du Globe de Paris.

    Google Scholar

    [61] Wan Y M. 2020. Global exploration, application and prospect of natural hydrogen[J]. Energy of China, 42(9): 33−37 (in Chinese with English abstract).

    Google Scholar

    [62] Ward L K. 1933. Inflammable gases occluded in the pre−Palaeozoic rocks of South Australia[J]. Transactions and Proceedings of the Royal Society of South Australia, 57: 42−47.

    Google Scholar

    [63] Wei Q Z, Zhu R K, Yang Z et al. 2024. Geological characteristics, formation distribution and resource prospects of natural hydrogen reservoir[J]. Natural Gas Geoscience, 35(6): 1113−1122 (in Chinese with English abstract).

    Google Scholar

    [64] Woolnough W G. 1934. Natural gas in Australia and new guinea[J]. AAPG Bulletin, 18(2): 226−242.

    Google Scholar

    [65] Worman S L, Pratson L F, Karson J A, et al. 2016. Global rate and distribution of H2 gas produced by serpentinization within oceanic lithosphere[J]. Geophysical Research Letters, 43(12): 6435−6443. doi: 10.1002/2016GL069066

    CrossRef Google Scholar

    [66] Yu C. 2012. Analysis of reservoir-forming conditions of shale gas in Lower Silurian of southeast Sichuan area[D]. Master's thesis of Southwest Petroleum University.

    Google Scholar

    [67] Yu M, Wang K, Vredenburg H. 2021. Insights into low−carbon hydrogen production methods: Green, blue and aqua hydrogen[J]. International Journal of Hydrogen Energy, 46(41): 21261−21273. doi: 10.1016/j.ijhydene.2021.04.016

    CrossRef Google Scholar

    [68] Zgonnik V. 2020. The occurrence and geoscience of natural hydrogen: A comprehensive review[J]. Earth−Science Reviews, 203: 103140. doi: 10.1016/j.earscirev.2020.103140

    CrossRef Google Scholar

    [69] 45−8 Energy. 2023. Hydrogen, the emergence of a clean energy [EB/OL]. (2023−09−12) [2024−02−18]. https://458energy.com/hydrogen/.

    Google Scholar

    [70] 窦立荣, 刘化清, 李博, 等. 2024. 全球天然氢气勘探开发利用进展及中国的勘探前景[J]. 岩性油气藏, 36(2): 1−14. doi: 10.12108/yxyqc.20240201

    CrossRef Google Scholar

    [71] 金之钧, 杨雷, 曾溅辉, 等. 2002. 东营凹陷深部流体活动及其生烃效应初探[J]. 石油勘探与开发, 29(2): 42−44.

    Google Scholar

    [72] 李秀梅, 刘映辉, 温景萍. 2002. 楚雄盆地乌龙 1 井天然气的地球化学特征和地质意义[J]. 天然气工业, 22(5): 16−19. doi: 10.3321/j.issn:1000-0976.2002.05.004

    CrossRef Google Scholar

    [73] 梁亚滨. 2022. 美、日、德能源战略比较与借鉴意义[J]. 学术前沿, (13): 45−55.

    Google Scholar

    [74] 秦川, 余谦, 刘伟, 等. 2017. 黔北地区牛蹄塘组富有机质泥岩储层特 征[J]. 西南石油大学学报(自然科学版), 39(4): 13−24.

    Google Scholar

    [75] 田黔宁, 张炜, 王海华, 等. 2022. 能源转型背景下不可忽视的新能源: 天然氢[J]. 中国地质调查, 9(1): 1−15.

    Google Scholar

    [76] 屠新泉, 曾瑞. 2024. 美国清洁能源补贴政策新动向、影响及应对策 略——基于美国《通胀削减法案》的分析[J]. 浙江学刊, (1): 137−143.

    Google Scholar

    [77] 万燕鸣. 2020. 全球天然氢的勘探、应用与发展[J]. 中国能源, 42(9): 33−37. doi: 10.3969/j.issn.1003-2355.2020.09.007

    CrossRef Google Scholar

    [78] 魏琪钊, 朱如凯, 杨智, 等. 2024. 天然氢气藏地质特征、形成分布与资源前景[J]. 天然气地球科学, 35(6): 1113−1122. doi: 10.11764/j.issn.1672-1926.2023.09.006

    CrossRef Google Scholar

    [79] 余川. 2012. 川东南地区下志留统页岩气成藏条件及资源潜力分 析[D].西南石油大学硕士学位论文.

    Google Scholar

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