Citation: | WU Zhenzhu, ZHANG Wanyi, WANG Fengxiang, HUANG Kuan, SHI Chunyuan. 2024. The development of overseas exploration of white hydrogen and implications for China. Geological Bulletin of China, 43(8): 1395-1405. doi: 10.12097/gbc.2024.02.013 |
Hydrogen energy is considered to be the cleanest energy and will play an increasingly important role in the future energy field. At present, it is only regarded as a secondary energy and does not have the characteristics of large scale and stability. Besides, most hydrogen energies are produced from fossil energies, which emit a lot of greenhouse gases. Because the environment problems caused by excessive dependence on fossil energies, it has become much important to study geological hydrogen (known as “white or native hydrogen”). With the deepening of research, hundreds of white hydrogen discoveries with high content have been reported worldwide, especially, the discovery in the Lorrain Basin, France. It is estimated that the resource is about ranging 6 million to 250 million tons. White hydrogen has regarded as the key energy to combat the climate crisis. Based on the previous studies, the hydrogen color spectrum is introduced. Compared with hydrogen produced by other routes, white hydrogen has three natural advantages of zero carbon, very low production cost and renewable. According to the progress of international exploration for white hydrogen, it is concluded that the Earth has a complete hydrogen production mechanism. Relevant studies have shown that white hydrogen with high content is widely distributed in rifts, plate subduction zones, and Precambrian crystalline basement. Both the resource and application prospects of white hydrogen are broad and the United States and Europe and other countries are stepping up the layout of white hydrogen exploration. According to the previous research, China also has the geological conditions for the white hydrogen. However, compared with other countries, the research work on white hydrogen needs to be improved. Based on this, three suggestions are put forward for white hydrogen work in China, which are launching white hydrogen investigation pilot projects in Songliao Basin and Qaidam Basin, strengthening comprehensive research and theoretical technology research and development of white hydrogen and also building a high−quality white hydrogen talent team.
[1] | Angino E E, Coveney R M J, Goebel E D, et al. 1984. Hydrogen and nitrogen—Origin, distribution, and abundance, a followup[J]. Oil & Gas Journal, 82(49): 142−146. |
[2] | Arcos J M M, Santos D M F. 2023. The hydrogen color spectrum: Techno−economic analysis of the available technologies for hydrogen production[J]. Gases, 3(1): 25−46. doi: 10.3390/gases3010002 |
[3] | Ascent Funds. 2020. Ascent hydrogen fund and helios aragon sign agreement to develop gold hydrogen in the northern Province of Aragon, Spain [EB/OL]. (2020-12-15) [2024-02-18]. https://ascent-funds.com/2020/12/15/ascent-hydrogen-fund-signs-new-deal-with-spains-helios-aragon-to-explore-and-produce-gold-hydrogen/. |
[4] | Bakx K. A new gold rush? 2024. The search for the natural hydrogen motherlode is coming to Canada [EB/OL]. (2024-01-26) [2024- 02-18]. https://www.cbc.ca/news/canada/bakx-white-hydrogen-natural-mali-1.7094645. |
[5] | Bartlett J, Krupnick A. 2020. Decarbonized hydrogen in the US power and industrial sectors: Identifying and incentivizing opportunities to lower emissions[R]. Resources for the Future, 20−25. |
[6] | Bauer C, Treyer K, Antonini C, et al. 2022. On the climate impacts of blue hydrogen production[J]. Sustainable Energy & Fuels, 6(1): 66−75. |
[7] | Brandon N, Armstrong F, Chan S H, et al. 2021. The role of hydrogen and ammonia in meeting the net zero challenge[J]. Climate Change: Science and Solutions, Briefing, 4: 1−13. |
[8] | Briere D, Jerzykiewicz T. 2016. On generating a geological model for hydrogen gas in the southern Taoudeni Megabasin (Bourakebougou area, Mali) [C]//International Conference and Exhibition, Barcelona, Spain, 3−6 April 2016. Society of Exploration Geophysicists and American Association of Petroleum Geologists: 342−342. |
[9] | Bulletin R. 2023. The hydrogen economy: Opportunities and risks in the energy transition [EB/OL]. (2023-04)[2024-02-18]. https://commercial. allianz.com/news-and-insights/reports/hydrogen-energy.html. |
[10] | Collins L. 2023a. ‘Energy of the future’ | French president promises ‘massive funding’ for natural hydrogen. [EB/OL].(2023-12-13) [2024-02-18]. https://www.hydrogeninsight.com/production/energy-of-the-future-french-president-promises-massive-funding-for-natural-hydrogen/2-1-1570543. |
[11] | Collins L. 2023b. Natural hydrogen found? | State-owned oil company analysing five sites across South Korea [EB/OL]. (2023-03-31) [2024-02-18]. https://www.hydrogeninsight.com/production/natural-hydrogen- found-state-owned-oil-company-analysing-five-sites-across-south-korea/2-1-1429573. |
[12] | Dove N. 2023. How a white hydrogen discovery could help global emissions efforts[EB/OL]. (2023-10-31) [2024-02-18]. https://global news.ca/news/10061237/white-hydrogen-discovery-what-is-it/. |
[13] | Dou L R, Liu H Q, Li B, et al. 2024. Global natural hydrogen exploration and developmentsituation and prospects in China[J]. Lithologic Reservoirs, 36(2): 1−14 (in Chinese with English abstract). |
[14] | Dubessy J, Pagel M, Beny J M, et al. 1988. Radiolysis evidenced by H2−O2 and H2−bearing fluid inclusions in three uranium deposits[J]. Geochimica et Cosmochimica Acta, 52(5): 1155−1167. doi: 10.1016/0016-7037(88)90269-4 |
[15] | Dutta S. 2018. Hydrogen as sustainable and green energy resource [EB/OL]. (2018-07-17) [2024-02-18]. Kirk−Othmer Encyclopedia of Chemical Technology. https://doi.org/10.1002/0471238961.082504180 2091212.a01.pub3. |
[16] | Ellis G S. 2023. Geologic hydrogen: An overlooked potential primary clean−energy resource[R]. Invited Presentation to the Geological Society of Washington DC. |
[17] | Enery. gov. 2023. Workshop with Oman’s Ministry of Energy and Minerals Explores Potential for Producing Hydrogen from Oman’s Unique Geology [EB/OL]. (2023-09-29) [2024-02-18]. https://www. energy.gov/articles/department-energy-convenes-first-ever-bilateral-engagement-geologic-hydrogen. |
[18] | Evans M. 2023. HyTerra, a first mover in natural hydrogen production [EB/OL]. (2023-09-29) [2024-02-18]. https://www.proactiveinvestors. co.uk/companies/news/1037927/hyterra-a-first-mover-in-natural-hydrogen-production-1037927.html. |
[19] | Goebel E D, Coveney Jr R M, Angino E E, et al. 1983. Naturally occurring hydrogen gas from a borehole on the western flank of Nemaha anticline in Kansas[J]. AAPG Bulletin, 67(8): 1324−1324. |
[20] | Guélard J, Beaumont V, Rouchon V, et al. 2017. Natural H2 in Kansas: Deep or shallow origin?[J]. Geochemistry, Geophysics, Geosystems, 18(5): 1841−1865. |
[21] | Han S, Tang Z, Wang C, et al. 2022. Hydrogen−rich gas discovery in continental scientific drilling project of Songliao Basin, Northeast China: New insights into deep Earth exploration[J]. Science Bulletin, 67(10): 1003−1006. doi: 10.1016/j.scib.2022.02.008 |
[22] | Hand E. 2023a. Hidden hydrogen: Does Earth hold vast stores of a renewable, carbon-free? [EB/OL]. (2023-02-16)[2024-02-18]. https:// www.science.org/content/article/hidden-hydrogen-earth-may-hold-vast-stores-renewable carbon-free-fuel. |
[23] | Hand E. 2023b. Geological hydrogen wins first major funding[J]. Science (New York, NY), 381(6662): 1036−1037. |
[24] | Hao Y, Pang Z, Tian J, et al. 2020. Origin and evolution of hydrogen−rich gas discharges from a hot spring in the eastern coastal area of China[J]. Chemical Geology, 538: 119477. doi: 10.1016/j.chemgeo.2020.119477 |
[25] | Howarth R W, Jacobson M Z. 2021. How green is blue hydrogen?[J]. Energy Science & Engineering, 9(10): 1676−1687. |
[26] | Ji M, Wang J. 2021. Review and comparison of various hydrogen production methods based on costs and life cycle impact assessment indicators[J]. International Journal of Hydrogen Energy, 46(78): 38612−38635. doi: 10.1016/j.ijhydene.2021.09.142 |
[27] | Jin Z J, Yang L, Zeng J H et al. 2002. Deep fluid activities and their effects on generation of hydrocarbon in Dongying depression[J]. Petroleum Exploration and Development, 36(2): 1−14. |
[28] | Jovan D J, Dolanc G. 2020. Can green hydrogen production be economically viable under current market conditions[J]. Energies, 13(24): 6599. doi: 10.3390/en13246599 |
[29] | Kazi M K, Eljack F, El−Halwagi M M, et al. 2021. Green hydrogen for industrial sector decarbonization: Costs and impacts on hydrogen economy in qatar[J]. Computers & Chemical Engineering, 145: 107144. |
[30] | Kuehn M. 2023. Transitioning from a Grey to Clean Hydrogen Economy: Considerations for Scaling Production and Making Use of Existing Transport Infrastructure[C]//Abu Dhabi International Petroleum Exhibition and Conference. SPE, D031S106R007. |
[31] | Li X M, Liu Y H, Wen J P. 2002. Geochemical characteristics and geological significance of natural gas in Well Wulong 1, Chuxiong Basin[J]. Natural Gas Industry, 22(5): 16−19 (in Chinese with English abstract). |
[32] | Liang Y B. 2022. A comparative study on energy strategies of the US, Japan and Germany[J]. Frontiers, 13: 45−55. |
[33] | Lollar B S, Onstott T C, Lacrampe−Couloume G, et al. 2014. The contribution of the Precambrian continental lithosphere to global H2 production[J]. Nature, 516(7531): 379−382. doi: 10.1038/nature14017 |
[34] | Marty B, Gunnlaugsson E, Jambon A, et al. 1991. Gas geochemistry of geothermal fluids, the Hengill area, southwest rift zone of Iceland[J]. Chemical geology, 91(3): 207−225. doi: 10.1016/0009-2541(91)90001-8 |
[35] | Maiga O, Deville E, Laval J, et al. 2023. Characterization of the spontaneously recharging natural hydrogen reservoirs of Bourakebougou in Mali[J]. Scientific Reports, 13(1): 11876. doi: 10.1038/s41598-023-38977-y |
[36] | Mendrela P, Stanek W, Simla T. 2024. Sustainability assessment of hydrogen production based on nuclear energy[J]. International Journal of Hydrogen Energy, 49: 729−744. doi: 10.1016/j.ijhydene.2023.07.156 |
[37] | Messad P. 2023. Excitement event about natural hydrogen as huge reserves found in France [EB/OL]. (2023-07-05)[2024-02-18]. https://www.euractiv.com/section/energy-environment/news/ excitement-grows-about-natural-hydrogen-as-huge-reserves-found-in-france/. |
[38] | Milani D, Kiani A, McNaughton R. 2020. Renewable−powered hydrogen economy from Australia's perspective[J]. International Journal of Hydrogen Energy, 45(46): 24125−24145. doi: 10.1016/j.ijhydene.2020.06.041 |
[39] | Moon B, Lee W, Lee Y. 2021. The present condition and outlook of hydrogen industry in Alberta, Canada[J]. Journal of the Korean Institute of Gas, 25(1): 1−6. |
[40] | Moore B J, Sigler S. 1987. Analyses of natural gases, 1917−85[R]. US Department of the Interior, Bureau of Mines. |
[41] | Morrill P L, Kuenen J G, Johnson O J, et al. 2013. Geochemistry and geobiology of a present−day serpentinization site in California: The Cedars[J]. Geochimica et Cosmochimica Acta, 109: 222−240. doi: 10.1016/j.gca.2013.01.043 |
[42] | Newcombe R B. 1935. Natural gas fields of Michigan[J]. AAPG Special Volumes, 7: 787−812. |
[43] | Nitz B. 2023. The history and promise of geological hydrogen for fuel [EB/OL]. (2023-03-06)[2014-02-18]. https://www.greenprophet.com/ 2023/03/geological-hydrogen-for-fuel/. |
[44] | Osselin F, Soulaine C, Fauguerolles C, et al. 2022. Orange hydrogen is the new green[J]. Nature Geoscience, 15(10): 765−769. doi: 10.1038/s41561-022-01043-9 |
[45] | Paddison L. 2023. They went hunting for fossil fuels. What they found could help save the world [EB/OL]. https://edition.cnn.com/2023/ 10/29/climate/white-hydrogen-fossil-fuels-climate/index.html. |
[46] | Parkes R. 2023. Massive underground reservoir of natural hydrogen in Spain 'could deliver the cheapest H2 in the world' [EB/OL]. (2023- 04-06) [2024-02-18]. https://www.hydrogeninsight.com/innovation/ massive-underground-reservoir-of-natural-hydrogen-in-spain-could-deliver-the-cheapest-h2-in-the-world/2-1-1431515. |
[47] | Peacock B. 2023. NASA pictures hydrogen-emitting ‘fairy circles’ in WA [EB/OL]. (2023-09-12)[2024-02-18]. https://www.pv-magazine-australia.com/2023/09/12/nasa-finds-hydrogen-emitting-fairy-circles-in-wa/. |
[48] | Potter J, Rankin A H, Treloar P J. 2004. Abiogenic Fischer–Tropsch synthesis of hydrocarbons in alkaline igneous rocks; fluid inclusion, textural and isotopic evidence from the Lovozero complex, NW Russia[J]. Lithos, 75(3/4): 311−330. doi: 10.1016/j.lithos.2004.03.003 |
[49] | Qin C, Yu Q, Liu W et al. 2017. Reservoir Characteristics of Organic−rich Mudstone of Niutitang Formation in Northern Guizhou[J]. Journal of Southwest Petroleum University(Science & Technology Edition, 39(4): 13−24 (in Chinese with English abstract). |
[50] | Ren X, Dong L, Xu D, et al. 2020. Challenges towards hydrogen economy in China[J]. International Journal of Hydrogen Energy, 45(59): 34326−34345. doi: 10.1016/j.ijhydene.2020.01.163 |
[51] | Salvi S, Williams−Jones A E. 1997. Fischer−Tropsch synthesis of hydrocarbons during sub−solidus alteration of the Strange Lake peralkaline granite, Quebec/Labrador, Canada[J]. Geochimica et Cosmochimica Acta, 61(1): 83−99. doi: 10.1016/S0016-7037(96)00313-4 |
[52] | Savchenko V P. 1958. The formation of free hydrogen in the Earth’s crust as determined by the reducing action of the products of radioactive transformations of isotopes[J]. Geochemistry Int., 1: 16−25. |
[53] | Scita R, Raimondi P P, Noussan M. 2020. Green hydrogen: the holy grail of decarbonisation? An analysis of the technical and geopolitical implications of the future hydrogen economy[R]. http://dx.doi.org/ 10.2139/ssrn.3709789. |
[54] | Shuai Y H, Zhang S C, Su A G, et al. 2010. Geochemical evidence for strong ongoing methanogenesis in Sanhu region of Qaidam Basin[J]. Science in China Series D: Earth Sciences, 53(1): 84−90. doi: 10.1007/s11430-009-0081-4 |
[55] | Stangarone T. 2021. South Korean efforts to transition to a hydrogen economy[J]. Clean technologies and environmental policy, 23: 509−516. doi: 10.1007/s10098-020-01936-6 |
[56] | Symonds R B, Poreda R J, Evans W C, et al. 2003. Mantle and crustal sources of carbon, nitrogen, and noble gases in Cascade−Range and Aleutian−Arc volcanic gases[R]. US Geological Survey. |
[57] | Tian Q N, Zhang W, Wang H H, et al. 2022. Non−negligible new energy in the energy transition context: Natural hydrogen[J]. Geological Survey of China, 9(1): 1−15 (in Chinese with English abstract). |
[58] | Trencher G, Edianto A. 2021. Drivers and barriers to the adoption of fuel cell passenger vehicles and buses in Germany[J]. Energies, 14(4): 833. doi: 10.3390/en14040833 |
[59] | Tu X Q, Zeng R. 2024. New Trends, Impact and response strategies of clean energy subsidy policies in the United States: Analysis based on the US inflation reduction act[J]. Zhejiang Academic Journal, (1): 137−143 (in Chinese with English abstract). |
[60] | Vacquand C. 2011. Genèse et mobilité de l’hydrogène dans les roches sédimentaires: Source d’énergie naturelle ou vecteur énergétique stockable[D]. PhD Thesis Defended in IFP Energies nouvelles and Institut de Physique du Globe de Paris. |
[61] | Wan Y M. 2020. Global exploration, application and prospect of natural hydrogen[J]. Energy of China, 42(9): 33−37 (in Chinese with English abstract). |
[62] | Ward L K. 1933. Inflammable gases occluded in the pre−Palaeozoic rocks of South Australia[J]. Transactions and Proceedings of the Royal Society of South Australia, 57: 42−47. |
[63] | Wei Q Z, Zhu R K, Yang Z et al. 2024. Geological characteristics, formation distribution and resource prospects of natural hydrogen reservoir[J]. Natural Gas Geoscience, 35(6): 1113−1122 (in Chinese with English abstract). |
[64] | Woolnough W G. 1934. Natural gas in Australia and new guinea[J]. AAPG Bulletin, 18(2): 226−242. |
[65] | Worman S L, Pratson L F, Karson J A, et al. 2016. Global rate and distribution of H2 gas produced by serpentinization within oceanic lithosphere[J]. Geophysical Research Letters, 43(12): 6435−6443. doi: 10.1002/2016GL069066 |
[66] | Yu C. 2012. Analysis of reservoir-forming conditions of shale gas in Lower Silurian of southeast Sichuan area[D]. Master's thesis of Southwest Petroleum University. |
[67] | Yu M, Wang K, Vredenburg H. 2021. Insights into low−carbon hydrogen production methods: Green, blue and aqua hydrogen[J]. International Journal of Hydrogen Energy, 46(41): 21261−21273. doi: 10.1016/j.ijhydene.2021.04.016 |
[68] | Zgonnik V. 2020. The occurrence and geoscience of natural hydrogen: A comprehensive review[J]. Earth−Science Reviews, 203: 103140. doi: 10.1016/j.earscirev.2020.103140 |
[69] | 45−8 Energy. 2023. Hydrogen, the emergence of a clean energy [EB/OL]. (2023−09−12) [2024−02−18]. https://458energy.com/hydrogen/. |
[70] | 窦立荣, 刘化清, 李博, 等. 2024. 全球天然氢气勘探开发利用进展及中国的勘探前景[J]. 岩性油气藏, 36(2): 1−14. doi: 10.12108/yxyqc.20240201 |
[71] | 金之钧, 杨雷, 曾溅辉, 等. 2002. 东营凹陷深部流体活动及其生烃效应初探[J]. 石油勘探与开发, 29(2): 42−44. |
[72] | 李秀梅, 刘映辉, 温景萍. 2002. 楚雄盆地乌龙 1 井天然气的地球化学特征和地质意义[J]. 天然气工业, 22(5): 16−19. doi: 10.3321/j.issn:1000-0976.2002.05.004 |
[73] | 梁亚滨. 2022. 美、日、德能源战略比较与借鉴意义[J]. 学术前沿, (13): 45−55. |
[74] | 秦川, 余谦, 刘伟, 等. 2017. 黔北地区牛蹄塘组富有机质泥岩储层特 征[J]. 西南石油大学学报(自然科学版), 39(4): 13−24. |
[75] | 田黔宁, 张炜, 王海华, 等. 2022. 能源转型背景下不可忽视的新能源: 天然氢[J]. 中国地质调查, 9(1): 1−15. |
[76] | 屠新泉, 曾瑞. 2024. 美国清洁能源补贴政策新动向、影响及应对策 略——基于美国《通胀削减法案》的分析[J]. 浙江学刊, (1): 137−143. |
[77] | 万燕鸣. 2020. 全球天然氢的勘探、应用与发展[J]. 中国能源, 42(9): 33−37. doi: 10.3969/j.issn.1003-2355.2020.09.007 |
[78] | 魏琪钊, 朱如凯, 杨智, 等. 2024. 天然氢气藏地质特征、形成分布与资源前景[J]. 天然气地球科学, 35(6): 1113−1122. doi: 10.11764/j.issn.1672-1926.2023.09.006 |
[79] | 余川. 2012. 川东南地区下志留统页岩气成藏条件及资源潜力分 析[D].西南石油大学硕士学位论文. |
Earth’s hydrogen factories