Formation and evolution of the Yuncheng Salt Lake and sources of the saline ions

Yuncheng Salt Lake, located within the core area of the Fenwei Graben System in the south-central part of the North China Craton, is the earliest known salt lake in China and worldwide. The formation and evolution of the Yuncheng Salt Lake are closely related to the Cenozoic tectonic domains of the coastal Pacific in eastern China and the Qinghai-Xizang Plateau in western China. However, there are many debates regarding the spatiotemporal processes and key timing associated with these two domains in the Yuncheng Salt Lake. Additionally, the salt lake is rich in sodium, magnesium, chloride, and sulfate ions; however the sources of these saline ions remain unclear.

This study investigated the major changes in the Cenozoic tectonic geomorphology of the Yuncheng Basin and its surrounding areas, focusing on the evolution of the Cenozoic river-lake system to establish the formation and evolution stages of the Yuncheng Salt Lake. This study combined the tectonic background and geochemical element analysis of typical strata in the adjacent Zhongtiao Mountains to identify the main sources of saline ions in the Yuncheng Salt Lake.

At the boundary between the Paleogene and Neogene, there was a widespread angular unconformity across the central and eastern parts of the North China Craton. This unconformity affected the Weihe Basin in the Fenwei Graben System to the west, and not the northeastern edge of the Qinghai-Xizang Plateau, which connects to the western North China Craton. This indicates that the tectonic forces during this period originated mainly from the coastal Pacific tectonic domain of the eastern North China Craton. In the mid-Miocene, a widespread unconformity along the northeastern edge of the Qinghai-Xizang Plateau connect to the western North China Craton. The northeastward uplift and expansion of the Qinghai-Xizang Plateau affected caused the Ordos Basin to rotate counterclockwise, initiating the formation of the Shanxi Graben System within the Fenwei Graben System. The Cenozoic evolution of the Yuncheng Salt Lake is the result of the interaction between the two major tectonic domains of eastern and western China. Before the mid-Miocene, the coastal Pacific tectonic domain predominantly controlled the region. Subsequently, the long-distance effects of northeastward uplift and expansion of the Qinghai-Xizang Plateau began to influence the Yuncheng Salt Lake. The Jixian System Longjiayuan Formation in the Zhongtiao Mountain area is composed of marine carbonate deposits that is the primary source of magnesium ions for the salt lake, with an average magnesium oxide content of 20.92%. The Paleogene Pinglu Group, an arid lake basin deposit rich in gypsum layers, provids sodium, chloride, and sulfate ions to the salt lake, with an average sodium oxide content of up to 2.6%.

This study suggested that approximatedly 700000 years ago, during the transition between the early and middle Pleistocene, the Yellow River flowed eastward into the sea through the Sanmenxia Gorge, leading to the disappearance of the Sanmen paleolake and the initial formation of the Yuncheng Salt Lake. Approximately 70000 years ago, during the mid-late Pleistocene, the Fen River changed its course and left the Yuncheng Basin, transforming the salt lake from an open to a closed system, ultimately forming the Yuncheng Salt Lake. Subsequently, under the continuous influence of the fault at the northern edge of the Zhongtiao Mountains, a large sedimentary depression formed, accumulating a large amount of saline minerals. Natural salt lake is formed over long periods of precipitation and evaporation. Currently, the saline ions of the Yuncheng Salt Lake mainly originate from adjacent sedimentary strata in the Zhongtiao Mountains and deep mineralization layers. The major fault controlling the salt lake provides the upward migration and injection of saline substances from deep mineralization layers into the salt lake. The marine high-magnesium dolomite of the Longjiayuan Formation of the Mesoproterozoic Jixian System in the Zhongtiao Mountains is a major source of magnesium ions for the salt lake.

The research findings provide fundamental geological evidence for the implementation of an ecological protection strategy to restore the lake by reducing salt levels in Yuncheng Salt Lake.