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2023 Vol. 50, No. 1
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YANG Yuzhen, GAO Baolong, HUANG Yi, XIAO Dechang, CHEN Fei, LUO Heng, LI Lifen, WU Gang. 2023. The adsorption characteristics of Pb2+ and Cd2+ by straw based biochars generated at medium-high pyrolysis temperatures[J]. Geology in China, 50(1): 52-60. doi: 10.12029/gc20220509001
Citation: YANG Yuzhen, GAO Baolong, HUANG Yi, XIAO Dechang, CHEN Fei, LUO Heng, LI Lifen, WU Gang. 2023. The adsorption characteristics of Pb2+ and Cd2+ by straw based biochars generated at medium-high pyrolysis temperatures[J]. Geology in China, 50(1): 52-60. doi: 10.12029/gc20220509001
shu

The adsorption characteristics of Pb2+ and Cd2+ by straw based biochars generated at medium-high pyrolysis temperatures

  • 1.

    Central South Geological Survey Institute, China Metallurgical Geology Bureau, Wuhan 430080, Hubei, China

  • 2.

    Institute of Mineral Resources Research, China Metallurgical Geology Bureau, Beijing 101300, China

    • Fund Project: Supported by Natural Resources Science and Technology project of Hubei Province (No.ZRZY2020KJ05)
More Information
  • Author Bio: YANG Yuzhen, male, born in 1986, bachelor, senior engineer, engaged in mineral and environmental geochemical survey; E-mail: 527657213@qq.com
  • Corresponding author: GAO Baolong, male, born in 1979, doctor, professor level senior engineer, engaged in mineral exploration and applied geophysics; E-mail: 45371309@qq.com 
Received Date:  09 May 2022
Revised Date:  20 August 2022
Publish Date:  25 February 2023
    Abstract

  • This paper is the result of environmental geological survey engineering.

     Objective

    Effect of pyrolysis temperature and raw materials on adsorption of heavy metals by straw-based biochar.

     Methods

    Corn straw and rice straw were used as raw materials to prepare straw based biochars (i.e. S450, S600, Y450, Y600) under anoxic conditions at 450℃ and 600℃. And the differences in their surface characteristics and their adsorption capacity for Pb2+ and Cd2+ in solutions were studied.

     Results

    The results showed that the pyrolysis temperature had a significant effect on the physicochemical properties of different biochars. With the increase of pyrolysis temperature, the C contents of biochars increased, but N, H, O contents decreased. Besides, their specific surface area, total pore volume and average pore diameter all showed a decreased tendency. As the result of the increase of pyrolysis temperature, the adsorption capacity and rate of Pb2+ and Cd2+ increased. Meanwhile, the adsorption capacity of Pb2+ and Cd2+ of corn straw biochar was significantly higher than that of rice straw biochar. The adsorption of Pb2+ and Cd2+ by the four biochars was dominated by chemical precipitation.

     Conclusions

    The adsorption of Pb2+ and Cd2+ was mainly multilayer and monolayer adsorption, respectively. Straw based biochars with higher pyrolysis temperature had higher adsorption capacity for Pb2+ and Cd2+. This study is useful for straw resource utilization and heavy metal pollution remediation.
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