2023 Vol. 50, No. 6
Article Contents

LI Man, XING Linxiao, WANG Guiling, ZHANG Wei, ZHAO Jiayi, JIN Menggui. 2023. Distribution characteristics of fluorine in deep geothermal water in Jizhong Depression and its risk assessment and development utilization suggestions[J]. Geology in China, 50(6): 1857-1870. doi: 10.12029/gc20220411005
Citation: LI Man, XING Linxiao, WANG Guiling, ZHANG Wei, ZHAO Jiayi, JIN Menggui. 2023. Distribution characteristics of fluorine in deep geothermal water in Jizhong Depression and its risk assessment and development utilization suggestions[J]. Geology in China, 50(6): 1857-1870. doi: 10.12029/gc20220411005

Distribution characteristics of fluorine in deep geothermal water in Jizhong Depression and its risk assessment and development utilization suggestions

    Fund Project: Supported by the project of China Geological Survey (No.DD20190555)
More Information
  • Author Bio: LI Man, female, born in 1985, assistant researcher, mainly engaged in the study of geothermal geology and hydrogeology; E-mail: liman@mail.cgs.gov.cn
  • Corresponding author: WANG Guiling, male, born in 1964, researcher, mainly engaged in geothermal geology; E-mail: guilingw@163.com 
  • This paper is the result of hydrogeological survey engineering.

    Objective

    The geothermal resources of Jizhong Depression are rich. The distribution characteristics and risk assessment of fluorine in geothermal waiter are of great significance to the development and utilization of geothermal resources.

    Methods

    This study takes the geothermal water in Jizhong Depression as the research object. The distribution characteristics and enrichment regularity of fluorine in geothermal fluid were studied by analyzing the hydrochemical data of geothermal fluid in sandstone and carbonate reservoirs, and the quality of geothermal fluid was evaluated, and furthermore some suggestions on the development and utilization of geothermal fluid were put forward.

    Results

    The results show that the geothermal fluids in the study area are mainly Na-Cl and Na-Cl-HCO3 type water, basically alkaline water, with high fluorine content. In particular, the concentration trend of fluorine ion content in the geothermal fluids of carbonate reservoir is 7.5-9.5 mg/L, and the highest is 13.9 mg/L. Weakly alkaline environment, water temperature and water-rock interaction are the main factors affecting fluoride ion enrichment in the study area. The F-concentration in sandstone geothermal reservoir has a significant negative correlation with Ca2+ and Mg2+ concentrations, while the correlation is not significant in carbonate geothermal reservoir. Fluorine enrichment is controlled by fluorite and other fluorine-bearing minerals. Fluorite saturation index of the geothermal fluids in sandstone reservoirs is all less than 0, while fluorite saturation index of the geothermal fluids in carbonate reservoirs with higher fluoride ion concentration is generally distributed around 0.

    Conclusions

    The high fluorine geothermal fluid in the study area cannot be directly used for drinking water, farmland irrigation and fisheries. It is of great importance to solve the problem of fluoride removal in geothermal tail water at the situation of conducting gradient utilization of geothermal resources in the study area.

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  • Chen Moxiang. 1988. Geothermics of North China[M]. Beijing: Science Press (in Chinese).

    Google Scholar

    Deng J, Lin W, Xing L, Chen L. 2022. The estimation of geothermal reservoir temperature based on integrated multicomponent geothermometry: A case study in the Jizhong depression, North China Plain[J]. Water, 14: 2489. doi: 10.3390/w14162489

    CrossRef Google Scholar

    Gao Z J, Zhu Z H, Liu X D. 2014. The formation and model of high fluoride groundwater and in-situ dispelling fluoride assumption in Gaomi City of Shandong Province[J]. Journal of Groundwater Science and Engineering, 2(2): 34-39. doi: 10.26599/JGSE.2014.9280016

    CrossRef Google Scholar

    Guo Q, Wang Y, Liu W. 2007. Major hydrogeochemical processes in the two reservoirs of the Yangbajing geothermal field, Tibet, China[J]. Journal of Volcanology and Geothermal Research, 166: 255-268. doi: 10.1016/j.jvolgeores.2007.08.004

    CrossRef Google Scholar

    He Jin, Zhang Fucun, Han Shuangbao, Li Xufeng, Yao Xiujü, Zhang Wei. 2010. The distribution and genetic types of high-fluoride groundwater in northern China[J]. Geology in China, 37(3): 621-626 (in Chinese with English abstract).

    Google Scholar

    Liu Chunhua, Wang Wei, Yang Lizhi, Zhu Henghua, Guo Yan, Ma Yuhong, Guo Jing, Liu Bohan. 2021. Driving mechanisms of fluorine enrichment characteristics in groundwater, Shandong Province[J]. Acta Geologica Sinica, 95(6): 1962-1972 (in Chinese with English abstract).

    Google Scholar

    Lu Mengsheng, Han Baoping, Wu Fan, Sun Dequ, Zhang Zhaomin. 2014. Characteristics and genesis of high-fluorine groundwater in southwestern Shandong Province[J]. Geology in China, 41(1): 294-302 (in Chinese with English abstract).

    Google Scholar

    Ma Feng, Wang Guiling, Zhang Wei, Zhu Xi, Zhang Hanxiong, Yue Gaofan. 2020. Structure of geothermal reservoirs and resource potential in the Rongcheng geothermal field in Xiong'an New Area[J]. Acta Geologica Sinica, 94(7): 1981-1990 (in Chinese with English abstract).

    Google Scholar

    Ou Hao, Lu Guoping, Hu Xiaonong, Wang Beibei. 2019. Fluoride enrichment in geothermal waters in Xinyi-Lianjiang region, Guangdong[J]. Environmental Chemistry, 38(5): 1128-1138 (in Chinese with English abstract).

    Google Scholar

    Ren Fuhong, Ceng Jianghui, Liu Wensheng, Zhang Cuiyun. 1996. Hydrogeochemical environment of high fluorine groundwater and the relation between the speciation of fluorine and the diseased ratio of endemic fluorosis: A case study of the North China Plain[J]. Acta Geoscientica Sinica, (1): 85-97 (in Chinese with English abstract).

    Google Scholar

    Shi Weidong, Guo Jianqiang, Zhang Senqi, Ye Chengming, Li Jian, Ma Xinhua. 2010. The distribution and geochemistry of geothermal groundwater bearing F and as in the guide basin[J]. Hydrogeology and Engineering Geology, 37(2): 36-41 (in Chinese with English abstract).

    Google Scholar

    Sun Hongli, Ma Feng; Liu Zhao, Liu Zhiming, Wang Guiling, Nan Dawa. 2015. The distribution and enrichment characteristics of fluoride in geothermal active area in Tibet[J]. China Environmental Science, 35(1): 251-259 (in Chinese with English abstract).

    Google Scholar

    Lin W J, Wang G L, Gan H N, Zhang S S, Zhao Z, Yue G F, Long X T. 2023. Heat source model for Enhanced Geothermal Systems (EGS) under different geological conditions in China[J]. Gondwana Research, 122: 243-259. doi: 10.1016/j.gr.2022.08.007

    CrossRef Google Scholar

    Wang Guiling, Lin Wenjing. 2020. Main hydro-geothermal systems and their genetic models in China[J]. Acta Geologica Sinica, 94(7): 1923-1937 (in Chinese with English abstract). doi: 10.3969/j.issn.0001-5717.2020.07.002

    CrossRef Google Scholar

    Wang Guiling, Zhang Wei, Liang Jiyun, Lin Wenjing, Liu Zhiming, Wang Wanli. 2017a. Evaluation of geothermal resources potential in China[J]. Acta Geoscientica Sinica, 38(4): 448-459 (in Chinese with English abstract).

    Google Scholar

    Wang Guiling, Zhang Wei, Lin Wenjing, Liu Feng, Zhu Xi, Liu Yanguang, Li Jun. 2017b. Research on formation mode and development potential of geothermal resources in Beijing-Tianjin-Hebei region[J]. Geology in China, 44(6): 1074-1085 (in Chinese with English abstract).

    Google Scholar

    Wang Ruizhi, Liu Jian, Wu Jinhui, Xia Lu, Cui Xiao, Zhang Qiangying. 2019. Preparation of magnetic nanocomposite and their removal properties of F and As in geothermal water[J]. The Journal of New Industrialization, 9(6): 82-85 (in Chinese with English abstract).

    Google Scholar

    Wang Xinwei, Guo Shiyan, Gao Nan'an, Liu Huiying, Wang Tinghao, Wei Guangren, Lei Haifei. 2023. Detection of carbonate geothermal reservoir in Niudong fault zone of Xiong'an New Area and its geothermal exploration significance[J]. Geological Bulletin of China, 42(1): 14-26 (in Chinese with English abstract).

    Google Scholar

    Wei Xiaoyang, Guo Qinghai, Yuan Jianfei, Ye Lu, Chang Juntan. 2009. Environmental migration and transformation of fluoride from high-temperature geothermal fluid: A case study at Yangbajing, Tibet, China[J]. Journal of East China Institute of Technology (Natural Science Edition), 32(1): 38-44 (in Chinese with English abstract).

    Google Scholar

    Wu Lihan. 2015. Characteristics and Genesis of High-Fluoride Groundwater in Hengshui City, the North China Plain China[D]. Beijing: China University of Geosciences (Beijing) (in Chinese with English abstract).

    Google Scholar

    Xing Lina, Guo Huaming, Wei Liang, Zhan Yanhong, Hou Chuntang, Li Ruimin, Wang Yi. 2012. Evolution feature and gensis of fluoride groundwater in shallow aquifer from North China Plain[J]. Journal of Earth Sciences and Environment, 34(4): 57-67 (in Chinese with English abstract).

    Google Scholar

    Yang Dongyi. 1986. Distribution of fluorine and geothermal fields[J]. Geotechnical Investigation Surveying, (6): 56 (in Chinese).

    Google Scholar

    Yu Bo, Ren Tong, Du Xinghong, Chu Zhiqing, Guo Meiyi. 2020. Study on the treatment process of fluorine-containing waste water[J]. China Resources Comprehensive Utilization, 38(11): 192-195 (in Chinese with English abstract).

    Google Scholar

    Yu Lan. 2007. A Study of the Occurrence and Origin of Fluoride in Thermal Groundwater in Some Areas of China[D]. Beijing: China University of Geosciences (Beijing) (in Chinese with English abstract).

    Google Scholar

    Yuan Ruoxi, Wang Guiling, Liu Feng, Zhang Wei, Cao Shengwei. 2021. Study on the indication of fluorine of the low-medium temperature convective geothermal system in Northeastern Hebei Province[J]. Geological Review, 67(1): 218-230 (in Chinese with English abstract).

    Google Scholar

    Zeng Jianhui. 1995. Numerical modelling of geochemical behavious of fluorine in the shallow groundwater system[J]. Acta Geologica Sinica, (3): 267-277 (in Chinese with English abstract).

    Google Scholar

    Zhang Dezhong, Liu Zhigang, Lu Hongliu. 2013. Geothermal of Hebei[M]. Beijing: Geological Publishing House (in Chinese).

    Google Scholar

    Zhang Lin, Sun Yongmei, Lin Chunzhu, Xie Zhenyuan, Wang Jun, Gao Weiqin. 1996. Utilization of geothermal water and environmental pollution of fluoride[J]. Agro-Enyironment and Development, 13(3): 40-42 (in Chinese with English abstract).

    Google Scholar

    Zhang Wei, Wang Guiling, Liu Feng, Xing Linxiao, Li Man. 2019. Characteristics of geothermal resources in sedimentary basins[J]. Geology in China, 46(2): 255-268 (in Chinese with English abstract).

    Google Scholar

    Zheng Guisen, Li Liangjing, Lü Jinbo. 2019. Research on method of processing tail water in geothermal exploration in Beijing[J]. Geological Bulletin of China, 38(2): 397-403 (in Chinese with English abstract).

    Google Scholar

    陈墨香. 1988. 华北地热[M]. 北京: 科学出版社.

    Google Scholar

    何锦, 张福存, 韩双宝, 李旭峰, 姚秀菊, 张徽. 2010. 中国北方高氟地下水分布特征和成因分析[J]. 中国地质, 37(3): 621-626.

    Google Scholar

    刘春华, 王威, 杨丽芝, 朱恒华, 郭艳, 马瑜宏, 郭晶, 刘柏含. 2021. 山东省地下水氟富集规律及其驱动机制[J]. 地质学报, 95(6): 1962-1972.

    Google Scholar

    鲁孟胜, 韩宝平, 武凡, 孙德全, 张兆民. 2014. 鲁西南地区高氟地下水特征及成因探讨[J]. 中国地质, 41(1): 294-302.

    Google Scholar

    马峰, 王贵玲, 张薇, 朱喜, 张汉雄, 岳高凡. 2020. 雄安新区容城地热田热储空间结构及资源潜力[J]. 地质学报, 94(7): 1981-1990.

    Google Scholar

    欧浩, 卢国平, 胡晓农, 王贝贝. 2019. 广东省信宜-廉江地区地热水中氟的富集过程[J]. 环境化学, 38(5): 1128-1138.

    Google Scholar

    任福弘, 曾溅辉, 刘文生, 张翠云. 1996. 高氟地下水的水文地球化学环境及氟的赋存形式与地氟病患病率的关系——以华北平原为例[J]. 地球学报, (1): 85-97.

    Google Scholar

    石维栋, 郭建强, 张森琦, 叶成明, 李健, 马新华. 2010. 贵德盆地高氟、高砷地下热水分布及水化学特征[J]. 水文地质工程地质, 37(2): 36-41.

    Google Scholar

    孙红丽, 马峰, 刘昭, 刘志明, 王贵玲, 男达瓦. 2015. 西藏高温地热显示区氟分布及富集特征[J]. 中国环境科学, 35(1): 251-259.

    Google Scholar

    王贵玲, 蔺文静. 2020. 我国主要水热型地热系统形成机制与成因模式[J]. 地质学报, 94(7): 1923-1937. doi: 10.3969/j.issn.0001-5717.2020.07.002

    CrossRef Google Scholar

    王贵玲, 张薇, 梁继运, 蔺文静, 刘志明, 王婉丽. 2017a. 中国地热资源潜力评价[J]. 地球学报, 38(4): 448-459.

    Google Scholar

    王贵玲, 张薇, 蔺文静, 刘峰, 朱喜, 刘彦广, 李郡. 2017b. 京津冀地区地热资源成藏模式与潜力研究[J]. 中国地质, 44(6): 1074-1085.

    Google Scholar

    王睿智, 刘建, 吴金辉, 夏露, 崔骁, 张强英. 2019. 磁性纳米复合物的制备及其在地热水中F和As的去除性能研究[J]. 新型工业化, 9(6): 82-85.

    Google Scholar

    汪新伟, 郭世炎, 高楠安, 刘慧盈, 王婷灏, 魏广仁, 雷海飞. 2023. 雄安新区牛东断裂带碳酸盐岩热储探测及其对地热勘探的启示[J]. 地质通报, 42(1): 14-26.

    Google Scholar

    魏晓阳, 郭清海, 袁建飞, 叶露, 常军坦. 2009. 高温地热流体来源氟在环境中的分布特征——以西藏羊八井热田为例[J]. 东华理工大学学报(自然科学版), 32(1): 38-44.

    Google Scholar

    乌丽罕. 2015. 衡水地区高氟地下水化学特征及其成因[D]. 北京: 中国地质大学(北京).

    Google Scholar

    邢丽娜, 郭华明, 魏亮, 詹燕红, 侯春堂, 李瑞敏, 王轶. 2012. 华北平原浅层含氟地下水演化特点及成因[J]. 地球科学与环境学报, 34(4): 57-67.

    Google Scholar

    杨东义. 1986. 氟与地热田的分布[J]. 工程勘察, (6): 56.

    Google Scholar

    杨明金, 杨帆, 王谋凤, 陈建明, 张少安. 2005. 地热水水质及其对农田和农作物影响研究[J]. 福建农业科技, (6): 65-67.

    Google Scholar

    于波, 任桐, 都兴红, 褚志强, 郭美祎. 2020. 含氟废水处理工艺研究[J]. 中国资源综合利用, 38(11): 192-195.

    Google Scholar

    虞岚. 2007. 我国部分地下热水中氟的分布与成因探讨[D]. 北京: 中国地质大学(北京).

    Google Scholar

    原若溪, 王贵玲, 刘峰, 张薇, 曹胜伟. 2021. 冀东北地区中低温对流型地热系统的氟指示意义研究[J]. 地质论评, 67(1): 218-230.

    Google Scholar

    曾溅辉. 1995. 浅层地下水系统氟地球化学行为的数值模拟[J]. 地质学报, (3): 267-277.

    Google Scholar

    张德忠, 刘志刚, 卢红柳. 2013. 河北地热[M]. 北京: 地质出版社.

    Google Scholar

    张林, 孙咏梅, 林春竹, 谢镇远, 王军, 高维勤. 1996. 地热水的开发利用与环境氟污染[J]. 农业环境与发展, 13(3): 40-42.

    Google Scholar

    张薇, 王贵玲, 刘峰, 邢林啸, 李曼. 2019. 中国沉积盆地型地热资源特征[J]. 中国地质, 46(2): 255-268.

    Google Scholar

    郑桂森, 李良景, 吕金波. 2019. 北京地热开采中的尾水氟处理方法[J]. 地质通报, 38(2): 397-403.

    Google Scholar

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