2021 Vol. 48, No. 5
Article Contents

WU Jixiu, WANG Wen, HUANG Zengbao, WANG Xiaosai, XUE Qianbing, SU Xin. 2021. Zircon U-Pb age, Hf isotope composition, and magma source of Mo-bearing granite porphyry in the Wenquan Mo deposit from West Qinling[J]. Geology in China, 48(5): 1596-1608. doi: 10.12029/gc20210520
Citation: WU Jixiu, WANG Wen, HUANG Zengbao, WANG Xiaosai, XUE Qianbing, SU Xin. 2021. Zircon U-Pb age, Hf isotope composition, and magma source of Mo-bearing granite porphyry in the Wenquan Mo deposit from West Qinling[J]. Geology in China, 48(5): 1596-1608. doi: 10.12029/gc20210520

Zircon U-Pb age, Hf isotope composition, and magma source of Mo-bearing granite porphyry in the Wenquan Mo deposit from West Qinling

    Fund Project: Supported by the project of China Geological Survey (No. DD20190072)
More Information
  • Author Bio: WU Jixiu, male, born in 1984, doctor candidate, engineer, engaged in reginal geological survey; E-mail: 272139943@qq.com
  • The Wenquan Mo ore deposit, the only one porphyry-type Mo deposit in the West Qinling, is located on the northern margin of the West Qinling orogenic belt. The ore bodies are mainly distributed within the granite porphyry and the contact zone between the granite porphyry and its surrounding rocks. The zircon U-Pb dating and Hf isotope studying of the ore deposit have great significance to define the forming age of the granite porphyry, reveal the evolution of the magma, and furthermore to clarify genesis of the ore deposit. The zircon LA-ICP MS U-Pb dating method was used to constrain the forming age of Mo-bearing granite porphyry in the Wenquan mine. Zircons from the granite porphyry have clear zonal texture and large value of Th/U ratio (0.41~0.88). The LA-ICPMS U-Pb dating of zircons from the Mo-bearing granite porphyry and its intruding porphyritic monzogranite yield ages of 212.43~213.4Ma and 219.9Ma respectively, indicating Late Triassic magmatic product. The hafnium isotope of the granite porphyry has a negative value between-1.89 and-1.63, with an average value of-1.59. On the εHf(t)-t diagram, the sampling points are plotted below the chondrite and the deficit mantle line, which indicates a unitary magmatic source. This source is the partially melting product of the modified earth crust. The age of the second stage (TDM2) model ranges from 1291 to 1408 Ma, which indicates that the magma was probably derived from the partiall melting of Mesoproterozoic earth crust.

  • 加载中
  • Cao Xiaofeng, Lǜ Xinbiao, Chen Chao, LiuShentai, Zhang Ping, Su Yuyun, Mei Wei, Zhang Bin. 2011. LA-ICP-MS U-Pb zircon geochronology, geochemistry and kinetics of the Wenquan ore-bearing granites from West Qinling, China[J]. Ore Geology Reviews, 43(1): 120-131. doi: 10.1016/j.oregeorev.2010.03.004

    CrossRef Google Scholar

    Chen Nengsong, Xia Xiaoping, Li Xiaoyan, Sun Min, Xu Ping, Liu Xiaoming, Wang Xinyu, Wang Qinyan. 2007. Timing of magmatism of the gneissic-granite plutons along North Qaidam margin and implications for precambrian crustal accretions: Zircon U-Pb Dating and Hf isotope evidences[J]. Acta Petrologica Sinica, 23 (2): 501-512(in Chinese with English abstract).

    Google Scholar

    Feng Chengyou, Li Dongsheng, Wu Zhengshou, Li Hongjun, Zhang Zhanyu, Zhang Aikui, Shu Xiaofeng, Su Shengshun. 2010. Major types, time-space distribution and metallogeneses of polymetallic deposits in the Qimantage Metal orogenic Belt, Eastern Kunlun Area[J]. Northwest Geoscience, 43(4): 10-17(in Chinese with English abstract).

    Google Scholar

    Feng Chengyou, Wang Song, Li Guochen, Ma Shengchao, Li Dongsheng. 2012. Middle to Late Triassic granitoids in the Qimantage area, Qinghai Province, China: Chronology, geochemistry and metallogenic significances. [J]. Acta Petrologica Sinica, 28(2): 665-678 (in Chinese with English abstract).

    Google Scholar

    Gansu Bureau of Geological and Mineral. 1989. Regional Geological Records of Gansu Province[M]. Beijing: Geological Publishing House (in Chinese).

    Google Scholar

    Gansu Bureau of Geology and Mineral Exploration. 1989. Geology of Gansu Province[M]. Beijing: Geological Publishing House, (in Chinese).

    Google Scholar

    Griffina W L, Belousova E A, Shee S R, Pearson N J, O'Reilly S Y. 2004. Archean crustal evolution in the northern Yilgarn Craton: U-Pb and Hf-isotope evidence from detrital zircons[J]. Precambrian Research, 131(3/4): 231-282.

    Google Scholar

    Han Haitao, Liu Jishun, Dong Xin, Zhou Yuguo, Shi Jianjun. 2008. Geochemical Characteristics of the Wen Quan Porphyry Molybdenum Deposit in West Qinling Area[J]. Geophysical and Geochemical Exploration, 32(2): 139-143 (in Chinese with English abstract).

    Google Scholar

    Han Haitao. 2009. Geological-Geochemical Characters and Metallogenic Prediction of Wen Quan Molybdenum Deposit in the West Qinling area[D]. Changsha: Central South University, 1-116 (in Chinese with English abstract).

    Google Scholar

    Hu Haizhu, Li Nuo, Deng Xiaohua, Chen Yanjiang, LI Yi. 2013. Indosinian Mo mineralization in Qinling area and prospecting potential[J]. Geology in China, 40(2): 549-564(in Chinese with English abstract).

    Google Scholar

    Huang Dianhao. 2015. Discussion with Prof. Mao Jingwen on types, ore-forming material source of some deposits and geological significance of rhenium content in Molybdenite[J]. Geological Rewiew, 61(5): 991-1000 (in Chinese with English abstract).

    Google Scholar

    Jin Weijun, Zhang Qi, He Dengfa, Jia Xiuqin. 2005. Shrimp Dating of Ddakites in Western Qinling and their Implications[J]. Acta Petrologica Sinica, 21 (3): 959-966(in Chinese with English abstract).

    Google Scholar

    Li Yongjun, Li Ying, Liu Zhiwu, Li Zhucang, Li Jinbao. 2003. Lithogeochemical features and magma mixing information of Wenquan Granite in Western Qinling Area[J]. Acta Geologica Gansu, 12(1): 31-35 (in Chinese with English abstract).

    Google Scholar

    Li Yongjun. 2005. Colleeting and Integariton of the Geological Information of Granitoids[D]. Xi'an: Chang'an University, 1-163 (in Chinese with English abstract).

    Google Scholar

    Liang Yazhong. 2008. Gelogical characteristics of Wenquan molybdenum of deposit in Wushan County of Province[J]. Gansu Geology, 17(2)40-49 (in Chinese with English abstract).

    Google Scholar

    Liu Yanliang, Gao Ya, Luo Weibin, Ji Wenzhong. 2018. Metallogenic regularity and prospect prediction of metallic deposits in Wenquan-Zhongchuan area of Western Qinling[J]. Geological Survey of China, 5 (4): 40-49 (in Chinese with English abstract).

    Google Scholar

    Liu Yongsheng, Hu Zhaochu, Gao Shan, Detlef Günther, Xu Juan, GaoChanggui, Chen Haihong. 2008. In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard[J]. Chemical Geology, 257(1/2): 34-43.

    Google Scholar

    Ludwig K R. 2003. ISOPLOT3.00: A Geochronological Toolkit for Microsoft Excel[M]. California, Berkeley: Berkeley Geochronol Center Special Publication., 4: 1-71.

    Google Scholar

    Ming Li, Haihong Chen, Lian Zhou, Lu Yang. 2012. Improved in situ Hf isotope ratio analysis of zircon using newly designed X skimmer cone and jet sample cone in combination with the addition of nitrogen bylaser ablation multiple collector ICP-MS[J]. Journal of Analytical Atomic Spectrometry, 27(9): 1391-1399. doi: 10.1039/c2ja30078h

    CrossRef Google Scholar

    Ou Yang, Yufei, Liu Jishun, Han Haitao, Liu Weiming, Wu Zicheng. 2009. Characteristics of ore minerals and modes of occurrence of molybdenumin Wenquan Molybdenum deposit in the West Qinling Area[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 28(4): 336-342 (in Chinese with English abstract).

    Google Scholar

    Pei Xianzhi, Ding Saping, Li Yong. 2004. Report of l: 250000 Tianshui Geological Map (in Chinese)[R]. Xi, an: Geological Survey Department of Chang, an University (in Chinese).

    Google Scholar

    Qingtao Zeng, M Cc Uaig T C, Hart C, Jourdan F, Muhling J, Bagas, L. 2012. Structural and geochronological studies on the Liba goldfield of the West Qinling Orogen, Central China[J]. Mineralium Deposita, 47(7): 799-819. doi: 10.1007/s00126-011-0398-8

    CrossRef Google Scholar

    Qiu Kunfeng, Li Nan, Taylor R D, Song Yaohui, Song Kairui, Han Wangzhen, Zhang Dongxu. 2014. Timing and duration of metallogeny of the Wenquan deposit in the West Qinling, and its constrain on a proposed classification for porphyry molybdenum deposits[J]. Acta Petrologica Sinica, 30(9): 2631-2643(in Chinese with English abstract).

    Google Scholar

    Rapp R P, Watson E B. 1995. Dehydration melting of metabasalt at 8-32 kbar: Implications for continental growth and crust-mantlerecycling[J]. J. Petrol., 36: 891-931. doi: 10.1093/petrology/36.4.891

    CrossRef Google Scholar

    Ren Hongxin. 2009. Geological characteristics and genesis of Molybdenum Deposits in Wushan County of Gansu[J] Gansu Metallurgy, 31(6): 58-61. (in Chinese with English abstract)

    Google Scholar

    Shang Liping, Liu Lihui, Lü Caiping, Tang Lin. 2015. Geochemical characteristics of intrusive rock in the Western Qinling[J]. Gansu Metallurgy, 37(6): 92-96 (in Chinese with English abstract).

    Google Scholar

    Song Shigang, Ding Zhenju, Yao Shuzhen, Zhou Zonggui, Zhang Shixin, Du Andao. 2008. Re-Os isotopic dating of molybdenite and its implication for molybdenum mineralization of Wenquan porphyry, Wushan, Gansu Province[J]. Northwester Geoloy, 41(1): 67-72 (in Chinese with English abstract).

    Google Scholar

    Vervoort J D, Blichert-Toft J. 1999. Evolution of the depleted mantle: Hf isotope evidence from juvenile rocks through time[J]. Geochemica et Cosmochemica Acta, 63: 533-566. doi: 10.1016/S0016-7037(98)00274-9

    CrossRef Google Scholar

    Wang Fei. 2011. Geological and Geochemical Characteristics and Geodynamic Setting of Mineralization of the Wenquan Molybdenum ore deposit in the west Qinling[D]. Xi'an: Northwestern University(in Chinese with English abstract).

    Google Scholar

    Wu Yuanbao, Zheng Yongfei. 2004. Zircon minerageny and its restrictions on U-Pb age interpretation[J]. Chinese Science Bulletin, 49(16): 1589-1604 (in Chinese). doi: 10.1360/csb2004-49-16-1589

    CrossRef Google Scholar

    Xu Xueyi, Chen Junlu, Gao Ting, Li Ping, Li Ting. 2014. Granitoid magmatism and tectonic evolution in northern edge of theWestern Qinling terrane, NW China[J]. Acta Petrologica Sinica, 30(2): 371-389 (in Chinese with English abstract).

    Google Scholar

    Xu Xueyi, He Shiping, Wang Hongliang, Chen Juanlu, Zhang Erpeng, Feng Yimin. 2008. Geology of Northwest China-Qinling, Qilian and Tianshan Area[M]. Beijing: Science Press, 131-133(in Chinese).

    Google Scholar

    Xu Xueyi, Li Ting, Chen Junlu. 2011. The granitoid magmatism and mineralization in west section of the Western Qin ling, NW China[J]. Northwest Geoscience, 45(4): 76-83 (in Chinese).

    Google Scholar

    Yin Yong, Yin Xianming. 2009. Porphyry Cu-Mo-Au mineralization related to adakite and Himalayan type granite in the northern margin of West Qinling[J]. Acta Petrologica Sinica, 25(5): 1239-1252 (in Chinese with English abstract).

    Google Scholar

    Zhang Chengli, Wang Tao, Wang Xiaoxia. 2008. Origin and tectonic setting of the early Mesozoic granitoids in Qinling Orogenic belt. Geological Journal of China Universities, 14(3): 304-316 (in Chinese with English abstract).

    Google Scholar

    Zhang Guowei, Guo Anlin, Yao Anping. 2004. Western Qinling-Songpan continental tectonic in China's continental tectonics[J]. Earth Science Frontiers, 11(3): 23-33 (in Chinese with English abstract).

    Google Scholar

    Zhang Hongfei, Jin lanlan, Zhang Li, Zhou Lian, Hu Shenhong, Zhang Benren. 2005. Geochemistry of granitoids and limitation of Pb-Sr-Nd isotope composition on basement properties and tectonic properties in the West Qinling[J]. Chinese Science (Series D), 35(10): 914-926 (in Chinese with English abstract).

    Google Scholar

    Zhou Junlie, Han Haitao. 2010. Mineralization characteristics and alteration zoning of Wenquan molybdenum deposit in West Qinling[J]. Global Geology, 29(2): 248-255 (in Chinese with English abstract).

    Google Scholar

    Zhu L M, Zhang G W, Ding Z, Guo B, Wang F, Lee B. 2011. Zircon U-Pb ages and geochemistry of the Wenquan Mo-bearing granitioids in Western Qinling, China: Constraints on the geodynamic setting for the newly discovered Wenquan Mo deposit[J]. Ore Geology Review, 39: 46-62. doi: 10.1016/j.oregeorev.2010.10.001

    CrossRef Google Scholar

    Zhu Laimin, Ding Zhenju, Yao Shuzhen, Zhang Guowei, Song Shigan, Qu Wenjun, Guo Bo, Li Beng. 2009. Ore-forming event and geodynamic setting of molybdenum deposit at Wenquan in Gansu Province, Western Qinling[J]. Chinese Sci. Bull., 54, 2337-2347 (in Chinese with English abstract). doi: 10.1360/csb2009-54-16-2337

    CrossRef Google Scholar

    陈能松, 夏小平, 李晓彦, 孙敏, 徐平, 柳小明, 王新宇, 王勤燕. 2007. 柴北缘花岗片麻岩的岩浆作用计时和前寒武纪地壳增长的锆石U-Pb年龄和Hf同位素证据[J]. 岩石学报, 23(2): 501-512.

    Google Scholar

    丰成友, 李东生, 吴正寿, 李军红, 张占玉, 张爱奎, 舒晓峰, 苏生顺. 2010. 东昆仑祁漫塔格成矿带矿床类型、时空分布及多金属成矿作用[J]. 西北地质, 43(4): 10-17. doi: 10.3969/j.issn.1009-6248.2010.04.002

    CrossRef Google Scholar

    丰成友, 王松, 李国臣, 马圣钞, 李东生. 2012. 青海祁漫塔格中晚三叠世花岗岩: 年代学、地球化学及成矿意义[J]. 岩石学报, 28(2): 665-678.

    Google Scholar

    冯益民, 曹宣铎, 张二朋, 胡云绪, 潘晓萍, 杨军录, 贾群子, 李文明. 2003. 西秦岭造山带的演化、构造格局和性质[J]. 西北地质, 36(1): 1-10. doi: 10.3969/j.issn.1009-6248.2003.01.001

    CrossRef Google Scholar

    甘肃省地质矿产局. 1989. 甘肃省区域地质志[M]. 北京: 地质出版社.

    Google Scholar

    韩海涛, 刘继顺, 董新, 周余国, 史建军. 2008. 西秦岭温泉斑岩型钼矿花岗岩类地球化学特征[J]. 物探与化探, 32(2): 139-143.

    Google Scholar

    韩海涛. 2009. 西秦岭温泉钼矿床地质化学特征及成矿预测[D]. 长沙: 中南大学, 1-116.

    Google Scholar

    胡海珠, 李诺, 邓小华, 陈衍景, 李毅. 2013. 秦岭地区印支期钼矿化特征及找矿前景[J]. 中国地质, 40(2): 549-564. doi: 10.3969/j.issn.1000-3657.2013.02.019

    CrossRef Google Scholar

    黄典豪. 2015. 就若干矿床的类型、成矿物质来源及辉钼矿含铼量的地质意义等与毛景文研究员商榷[J]. 地质评论, 61(5): 991-1000.

    Google Scholar

    金维浚, 张旗, 何登发, 贾秀琴. 2005. 西秦岭埃达克岩的SHRIMP定年及其构造意义[J]. 岩石学报, 21(3): 959-966.

    Google Scholar

    李永军, 李英, 刘志武, 李注苍, 李金宝. 2003. 西秦岭温泉花岗岩岩石化学特征及岩浆混合信息[J]. 甘肃地质学报, 12(1): 31-35.

    Google Scholar

    李永军. 2005. 花岗岩类地质信息的采集与集成[D]. 西安: 长安大学, 1-163.

    Google Scholar

    梁亚忠. 2008. 甘肃武山温泉钼矿床地质特征[J]. 甘肃地质. 17(2): 40-49.

    Google Scholar

    刘彦良, 高雅, 罗维斌, 季文中. 2018. 西秦岭温泉-中川一带金属矿床的成矿规律及找矿预测[J]. 中国地质调查, 5(4): 40-49.

    Google Scholar

    马玉明, 汪建彪. 2009. 温泉钼矿床地质特征及成因浅析[J]. 甘肃冶金, 31(5): 81-85.

    Google Scholar

    欧阳玉飞, 刘继顺, 韩海涛, 刘卫明, 吴自成. 2009. 西秦岭温泉钼矿床矿石矿物特征及钼的赋存状态[J]. 矿物岩石地球化学通报, 28(4): 336-342.

    Google Scholar

    裴先治, 丁仨平, 李勇. 2004. 1:250000天水市幅区域地质调查报告[R]. 西安: 长安大学地质调查研究院.

    Google Scholar

    邱坤峰, 宋开瑞, 宋耀辉. 2015. 西秦岭温泉斑岩钼矿床岩浆-热液演化[J]. 岩石学报, 31(11): 3391-3404.

    Google Scholar

    邱昆峰, 李楠, Taylor R D, 宋耀辉, 宋开瑞, 韩旺珍, 张东旭. 2014. 西秦岭温泉钼矿床成矿作用时限及其对斑岩型钼矿床系统分类制约[J]. 岩石学报, 30(9): 2631-2643.

    Google Scholar

    任新红. 2009. 甘肃武山温泉钼矿床地质特征及成因[J]. 甘肃冶金, 31(6): 58-61.

    Google Scholar

    尚丽萍, 刘莉晖, 吕彩萍, 汤琳. 2015. 西秦岭侵入岩地球化学特征[J]. 甘肃冶金. 37(6): 92-96.

    Google Scholar

    宋史刚, 丁振举, 姚书振, 周宗桂, 张世新, 杜安道. 2008. 甘肃武山温泉辉钼矿Re-Os同位素定年及其成矿意义[J]. 西北地质, 41(1)67-72.

    Google Scholar

    王飞. 2011. 西秦岭温泉钼矿床地质-地球化学特征与成矿动力学背景[D]. 西安: 西北大学.

    Google Scholar

    吴元保, 郑永飞. 2004. 锆石成因矿物学研究及其对U-Pb年龄解释的制约[J]. 科学通报, 49(16): 1589-1604.

    Google Scholar

    徐学义, 何世平, 王洪亮, 陈隽璐, 张二朋, 冯益民. 2008. 中国西北部地质概论——秦岭、祁连、天山地区[M]. 北京: 科学出版社, 131-133.

    Google Scholar

    徐学义, 李婷, 陈隽璐, 等. 2011. 西秦岭西段花岗岩浆作用与成矿[J]. 西北地质, 45(4): 76-83.

    Google Scholar

    徐学义, 陈隽璐, 高婷, 李平, 李婷. 2014. 西秦岭北缘花岗质岩浆作用及构造演化[J]. 岩石学报, 30(2): 371-389.

    Google Scholar

    殷勇, 殷先明. 2009, 西秦岭北缘与埃达克岩和喜马拉雅型花岗岩有关的斑岩型铜-钼-金成矿作用[J]. 岩石学报, 25(5): 1239-1252.

    Google Scholar

    张成立, 王涛, 王晓霞. 2008. 秦岭造山带早中生代花岗岩成因及其构造环境[J]. 高校地质学报, 14(3): 304-316.

    Google Scholar

    张国伟, 郭安林, 姚安平. 2004. 中国大陆构造中的西秦岭-松潘大陆构造结[J]. 地学前缘, 11(3): 23-33.

    Google Scholar

    张宏飞, 靳兰兰, 张利, 周炼, 胡圣虹, 张本仁. 2005. 西秦岭花岗岩类地球化学和Pb-Sr-Nd同位素组成对基底性质及其构造属性的限制[J]. 中国科学(D辑), 35(10): 914-926.

    Google Scholar

    张瑞雪, 司雪峰, 姚强. 2018. 西秦岭地区钨钼成矿特征及找矿预测[J]. 甘肃科技, 34(5): 22-24, 104.

    Google Scholar

    周俊烈, 韩海涛. 2010. 西秦岭温泉钼矿床矿化特征与蚀变分带[J]. 世界地质, 29(2): 248-255.

    Google Scholar

    朱赖民, 丁振举, 姚书振, 张国伟, 宋史刚, 屈文俊, 郭波, 李犇. 2009. 西秦岭甘肃温泉钼矿床成矿地质事件及其成矿构造背景[J]. 科学通报, 54: 2337-2347.

    Google Scholar

  • 加载中
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Figures(4)

Tables(3)

Article Metrics

Article views(2383) PDF downloads(130) Cited by(0)

Access History

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint